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Miyazaki Yuzo

Institute of Low Temperature Science Water and Material CyclesAssistant Professor

Researcher basic information

■ Degree
  • Ph,D, (Sci.), The University of Tokyo
  • Ms. (Sci.), The University of Tokyo
■ URL
researchmap URLホームページURL■ Various IDs
Researcher number
  • 60376655
J-Global ID■ Research Keywords and Fields
Research Keyword
  • Biogeochemistry
  • Marine atmospheric chemistry
  • Atmospheric chemistry
  • Interaction between atmosphere and biosphere
  • Organic aerosol
Research Field
  • Natural Science, Atmospheric and hydrospheric sciences
  • Environmental Science/Agriculture Science, Environmental dynamic analysis
■ Educational Organization

Career

■ Career
Career
  • 2003 - 2007
    The University of Tokyo, Research Center for Advanced Science and Technology
  • 2007
    Institute of Low Temperature Science
  • 2003
    The University of Tokyo, Research Center for Advanced Science and Technology
  • 2003
    Postdoctoral Fellowships of Japan Society for the Promotion of Science
Educational Background
  • The University of Tokyo, 理学系研究科, 地球惑星科学専攻, Japan
Committee Memberships
  • 2022 - Present
    日本気象学会, SOLA編集委員会 運営委員, Society
  • 2018 - Present
    SOLAS, National Representative of Japan, Society
  • 2018 - Present
    日本学術会議 環境学委員会・地球惑星科学委員会合同 FE・WCRP合同分科会, SOLAS小委員会委員(第24期:副委員長,第25期:委員長), Society
  • 2018 - Present
    日本学術会議 環境学委員会・地球惑星科学委員会合同 FE・WCRP合同分科会, IGAC小委員会委員, Society
  • Oct. 2014 - Present
    Scientific Reports (Nature Publishing Group), Editorial Board Member, Society
  • Jul. 2021 - Jun. 2025
    日本大気化学会, 運営委員, Society
  • Apr. 2020 - Mar. 2024
    日本地球惑星科学連合, 代議員, Society
  • 2016 - 2022
    日本気象学会, SOLA編集委員, Society
  • 2015 - 2017
    日本学術会議, 環境学委員会・地球惑星科学委員会合同IGBP・WCRP・DIVERSITAS合同分科会IGAC小委員会委員, Others

Research activity information

■ Awards
  • 2017, 日本地球惑星科学連合 (JpGU), 第2回地球惑星科学振興西田賞
    「大気有機エアロゾルの起源に関する観測的研究」
    宮﨑 雄三
  • 2016, 日本気象学会, 2016年度 正野賞
    宮﨑 雄三
  • 2011, 日本大気化学会 第7回(2011年度)奨励賞
    Japan
  • 2009, 日本気象学会 2009年度 山本・正野論文賞
    Japan
■ Papers
■ Other Activities and Achievements
■ Books and other publications
  • 低温科学便覧 (北海道大学低温科学研究所編)
    宮﨑 雄三, 第10章 有機エアロゾル
    丸善出版, 2015, [Contributor]
■ Syllabus
  • 対流圏化学特論, 2024年, 修士課程, 環境科学
  • 大気海洋化学基礎論, 2024年, 修士課程, 環境科学院
  • 生物地球化学基礎論, 2024年, 修士課程, 環境科学院
  • 環境と人間, 2024年, 学士課程, 全学教育
■ Affiliated academic society
  • American Geophysical Union
  • 日本エアロゾル学会
  • 日本気象学会
  • 日本地球惑星科学連合
  • 日本大気化学会
■ Research Themes
  • 陸域で生成される超難分解な燃焼起源有機物の海洋への移行および埋没過程の定量評価
    科学研究費助成事業
    01 Apr. 2025 - 31 Mar. 2029
    山下 洋平; 宮崎 雄三; 入野 智久; 野牧 秀隆
    日本学術振興会, 基盤研究(A), 北海道大学, 25H01176
  • 北極海洋上で生成する大気有機エアロゾル量・組成変動を制御する海洋微生物因子の解明
    科学研究費助成事業
    Apr. 2026 - Mar. 2029
    宮崎 雄三; 持田 陸宏; 山下 洋平; 深井 悠里
    日本学術振興会, 基盤研究(B), 北海道大学, 26K03054
  • Exploring new indicators representing the hygroscopicity of atmospheric organic aerosol
    Grants-in-Aid for Scientific Research
    01 Apr. 2023 - 31 Mar. 2027
    持田 陸宏; 佐藤 圭; 石塚 紳之介; 木村 勇気; 松井 仁志; 宮崎 雄三; 大畑 祥
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (A), Nagoya University, 23H00515
  • 海洋に存在する熱成有機物のミッシングソースの解明
    科学研究費助成事業
    01 Apr. 2022 - 31 Mar. 2026
    山下 洋平; 宮崎 雄三; 入野 智久
    日本学術振興会, 基盤研究(B), 北海道大学, 22H03714
  • 亜寒帯海域での大気有機態窒素エアロゾル生成量・組成変動を支配する微生物要因の解明
    日本学術振興会 科学研究費助成事業 基盤研究(B)
    Apr. 2023 - Mar. 2026
    宮﨑 雄三, 鈴木 光次, 山下 洋平
    Principal investigator
  • Association analysis between short/long-range diffusion of non-tuberculosis mycobacterium bioaerosols and its infectious disease
    Grants-in-Aid for Scientific Research
    01 Apr. 2020 - 31 Mar. 2024
    能田 淳; 露口 一成; 御手洗 聡; 森本 耕三; 宮崎 雄三; 牧 輝弥
    本研究は、地域ごとの大気環境中のPM2.5の化学的特性及び肺非結核抗酸菌症(肺NTM症)の90%を占めるMAC菌の特異性を把握することと、これら大気環境中の化学成分とMAC菌との相互作用を検証することを目的としている。大気を介したMAC菌感染症の越境の可能性を検証するため、地上付近数十メートルでの測定を全国5拠点(北海道札幌市、東京都清瀬市、石川県珠洲市、大阪府堺市、福岡県福岡市)にて進めている。頻度としては、季節変動の把握を目的として、年4回のサンプリングを季節ごとで進めている。さらに、高高度での拡散条件の把握を行うために、ヘリコプター、航空機などの活用で、隣国などから越境することの可能性も視野に入れつつ観測を進めている。高高度測定については、大阪府、石川県付近など限られた地点での測定ではあるが、地上でのデータとの比較を目指して、できるだけ同時期に測定することを目指す。これらの測定結果で得られたデータを基に、大気中のバイオエアロゾルの挙動を擬似的に検証できる擬似大気チャンバーを用いて、大気中細菌などのバイオエアロゾル活性保持メカニズムの把握、検証を行う。これらの知識構築にて、肺NTM症などの感染が起こりやすい状況をより明確化し、感染症に対応できる生活環境の整備、又は状況の把握か取り組む予防的な対応にて疾病問題の低減化を目ざす。環境因子と関連した感染症対策は知識が不十分であるため、本研究には大きな意義がありこれらの対応を進めていくことは感染症対策として健康維持に向けた重要な取り組みである。
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), Rakuno Gakuen University, 20H04326
  • Exploratory research on new source of atmospheric reactive nitrogen focusing on marine nitrogen-fixing organisms
    Grants-in-Aid for Scientific Research
    Jul. 2021 - Mar. 2023
    宮﨑 雄三, 鈴木 光次
    本研究は、海水中で微生物が窒素分子を(栄養塩として利用可能な)反応性窒素へと変換するプロセスである窒素固定に着目し、海洋表層の窒素固定生物が大気反応性窒素の有意な放出源となり得るかを明らかにすることを目的としている。今年度は、人工海水(培地)を用いた窒素固定生物の培養-大気捕集システムの構築と実験条件の最適化を行った。人工海水での窒素固定生物の培養と大気捕集が可能な測定システムを恒温槽内に製作し、大気の吸引による培養容器(水槽)内の圧力変化が細胞増殖に与える影響や容器への負荷を調べた。培養容器約30Lの材質は、光合成のための光を照射するため透明かつ強度が大きく、測定への有機物の干渉がないアクリル製を予備実験により選定した。
    この実験システムを使用し、窒素固定生物の中でトリコデスミウムを用いた室内培養-大気捕集実験を約2カ月間行った。恒温槽内に設置した人工海水中でトリコデスミウムを培養し、インパクタを用いて24時間毎の大気捕集を行った。インパクタにより粒子相と気相(酸性、アルカリ性)の反応性窒素(アンモニア/アンモニウム塩、有機態窒素、硝酸/硝酸塩等)成分を捕集・測定した。人工海水試料は24時間毎に採取し、溶存態窒素や溶存有機炭素濃度、及びクロロフィルa濃度を計算するための細胞内蛍光強度など微生物指標を測定した。約2か月間の培養期間において、トリコデスミウムの増殖期、減衰期を捉えることに成功し、特にアンモニアの大気放出が衰退期において顕著であることが観測された。同時測定したバクテリアの数も減衰期に増加していたことから、トリコデスミウム増殖に伴う滲出物である溶存窒素、溶存態有機炭素の分解が進み、揮発性の高いアンモニア/アンモニウム塩として大気中へ放出が増大したことが示唆された。同様の大気濃度増大は塩基性の有機態窒素(気相)でも観測された。
    Japan Society for the Promotion of Science, Grant-in-Aid for Challenging Research (Exploratory), Hokkaido University, 21K19835
  • Deepening the quantitative understanding of the hygroscopicity of atmospheric organic aerosol: Its relationship to chemical structures and sources
    Grants-in-Aid for Scientific Research
    01 Apr. 2019 - 31 Mar. 2022
    Mochida Michihiro
    In this study, the relationships of the hygroscopicity of organic components in atmospheric aerosol samples with the chemical structures and sources were investigated. For urban aerosols, the mass spectral analysis of the extracts from aerosol samples showed the contributions of organics associated with their sources and chemical structure. Further, the relationships of the hygroscopicity of humic-like substances with the oxygen-to-carbon ratios and sources were obtained. For forest aerosols, the atmospheric concentrations of organic fractions were determined based on mass spectral analysis. Based on the hygroscopic growth measurements for particles such as those composed of the mixtures of humic-like substances and ammonium sulfate, results for the assessment of the additivity of hygroscopicity were also obtained.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), Nagoya University, 19H04253
  • 海洋大気の有機態窒素エアロゾル:生成量を制御する海洋微生物活動の支配要因は何か?
    日本学術振興会 科学研究費助成事業 基盤研究(B)
    Apr. 2019 - Mar. 2022
    宮﨑 雄三, 鈴木 光次, 山下 洋平
    Principal investigator, Competitive research funding
  • Origin of organic nitrogen aerosol revealed by advanced analysis of nitrogen isotope ratio
    Grants-in-Aid for Scientific Research
    09 Nov. 2018 - 31 Mar. 2021
    宮崎 雄三; XU YU
    本年度は昨年度から引き続き大気エアロゾル中のアミノ酸について、実大気中での代表的な反応過程であるオゾン酸化反応を受けた際の同位体分別効果を調べ、起源トレーサーとしての有用性を検証した。同位体比既知の遊離態アミノ酸標準物質、タンパク質のモデル物質としてのウシ血清アルブミンを添加した石英繊維フィルター、および森林観測サイトで採取した大気エアロゾルフィルター試料(TSP)をそれぞれ大気オゾンに曝露した。これにより、オゾン曝露の前後でアミノ酸の窒素、炭素の安定同位体比が有意に変化するかどうか、すなわちエアロゾル中のアミノ酸がオゾンに伴う反応を受けることによる同位体分別効果の影響を調べた。測定には前年度に確立した、石英繊維フィルターからの溶媒抽出、加水分解や誘導体化等のプロセスの後、ガスクロマトグラフ-質量分析計およびガスクロマトグラフ-同位体比質量分析計に導入し、化合物の質量および安定同位体比を測定する手法を用いた。
    その結果、主要な化合物を含め、ほとんどのアミノ酸化合物の窒素・炭素の安定同位体比について、オゾン曝露の前後で有意な変化は見られず、オゾンに関連する反応による同位体分別は起きていないことが確認できた。植生内で同位体分別が起きないとされる特定のアミノ酸化合物についての過去の文献と本研究による実験結果から、大気でのオゾン酸化反応を経ても、特にグリシンの安定同位体比などが大気中の生物起源トレーサーとして有用であることが初めて示唆された。
    Japan Society for the Promotion of Science, Grant-in-Aid for JSPS Fellows, Hokkaido University, 18F18398
  • 植生由来テルペン類から生成する有機態窒素エアロゾルの起源と生成メカニズムの解明
    科研費補助金 基盤研究(B)
    Apr. 2016 - Mar. 2019
    宮崎 雄三, 佐藤 圭, 持田 陸宏
    Principal investigator, Competitive research funding
  • Analysis of BVOV emission of white birch and grazing traits by insect herbivore under elevated ozone
    Grants-in-Aid for Scientific Research
    01 Apr. 2016 - 31 Mar. 2018
    Koike Takayoshi
    Ground-level Ozone (O3) decreased defense leaf capacity because of suppression of photosynthesis. We found severe grazing damages of leaf beetle on a crown of White birch at elevated O3. Contrary to this, choice and non-choice style of feeding experiments showed that leaves exposed to elevated O3 were preferred by leaf beetles because of lower defensive chemicals production. To clarify this phenomenon, we suggested possibility of BVOC (Biogenic Volatile Organic Compounds) as signal chemicals for insects to locate their host plants. BVOCs were roughly sorted into two groups: one was monoterpene (MT), the other was sesquiterpene (SQT). MT and SQT had no significant difference in the basic-emission rate regardless of O3 exposure. Therefore, BVOC emission in itself did not work as a factor of changing grazing activity of leaf beetles although the brand ratio of BVOC should be considered. At high O3, we should study BVOC dynamics through reaction with O3 after emitted in the atmosphere.
    Japan Society for the Promotion of Science, Grant-in-Aid for Challenging Exploratory Research, Hokkaido University, 16K14932
  • Effect of vertical mixing within the atmospheric boundary layer measured by the marvelous method on clouds, air quality and radiation
    Grants-in-Aid for Scientific Research
    01 Apr. 2014 - 31 Mar. 2017
    Fujiyoshi Yasushi
    Simultaneous ground and in situ observations confirmed the consistent variation of many physical properties in the atmosphere. We also found that strong turbulence near the top of atmospheric boundary layer occurred only in the very narrow region adjacent to small cumulus clouds. We also investigated the spatial and temporal variability of the physical and optical properties of aerosols. We developed a new algorithm to estimate the vertical profiles of the aerosol physical and optical properties. Furthermore, the solar heating rate was estimated from the retrievals, which were directly validated by in situ data collected by a glider. The comparison of the retrieved extinction coefficient with that estimated from in situ measurements showed that our algorithm has a bias error due to the optimization of aerosol parameters to the optical thickness measured by the sky radiometer.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), Hokkaido University, 26287111
  • Hygroscopicity and optical properties of biogenic secondary organic aerosol formed in a forest area
    Grants-in-Aid for Scientific Research
    01 Apr. 2014 - 31 Mar. 2017
    Mochida Michihiro; DENG Yange; OGAWA Shuhei; KAGAMI Sara; YAI Hikari; KAWANA Kaori; KUBODERA Ryo; TACHIBANA Eri
    Field observations of the hygroscopicity and optical properties of atmospheric aerosol were conducted in a forest area of the Kii Peninsula. Hygroscopicity parameters of organic aerosol and biogenic secondary organic aerosol were calculated based on measurements of cloud condensation nuclei. The contributions of organic aerosol and biogenic secondary organic aerosol to the number concentrations of cloud condensation nuclei were assessed. Further, the coatings of black carbon particles were analyzed based on light absorption measurements of the aerosol with and without heating. The hygroscopic growth factors of aerosol particles, the concentrations of tracer species of biogenic secondary organic aerosol, and sky-radiometer data were also obtained. Results and data from this study are expected to be the basis for further characterization of forest aerosols.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), Nagoya University, 26281007
  • Composition, origin, transformation and hygroscopic properties of organic aerosols in East Asia and the North Pacific
    Grants-in-Aid for Scientific Research
    31 May 2012 - 31 Mar. 2017
    KAWAMURA Kimitaka
    In this project, we studied chemical compositions of atmospheric aerosols from East Asia and its outflow regions in the western North Pacific at levels of carbon, nitrogen, organic molecules including carboxylic acids, isotopes and inorganic ions. We found a decline of sulfate concentrations after 2006 due to the sulfur emission control in China, but organic aerosols showed a continuous increase from 2001 to 2013. This increase of organics is largely involved with the emissions of biomass burning of agriculture wastes such as wheat straw in China and other Asian countries. Those trends are consistent with an increase in the biomass-burning tracers such as levoglucosan in the marine aerosols.
    Hygroscopic properties of aerosol particles were measured for remote marine aerosols. We found that growth factors of marine aerosols are decreased when Asian dusts (Kosa) are transported over the ocean due to the formation of water-insoluble calcium oxalate in spring.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (S), 24221001
  • 含窒素有機物組成と同位体比測定による有機態窒素エアロゾルの起源の解明
    科研費補助金 基盤研究(B)
    Apr. 2013 - Mar. 2016
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • 海洋微生物に由来する大気微粒子ゲル状有機物に含まれるペプチド検出の試み
    科研費補助金 挑戦的萌芽研究
    2013 - 2014
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • 複合トレーサーを用いた森林土壌への窒素負荷に伴う大気エアロゾル生成への影響の解明
    2012 - 2013
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • 森林生態系でのCO2固定に対する炭素性微小粒子生成への応答と制御要因の解明
    2011 - 2012
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • Studies of impacts of black carbon aerosol on climate based on aircraft observations
    Grants-in-Aid for Scientific Research
    2007 - 2011
    KONDO Yutaka; KOIKE Makoto; TAKEKAWA Nobuyuki; TAKEMURA Toshihiko; MIYAZAKI Yuzo
    We have developed a black carbon(BC) instrument. Using the BC instrument, aircraft campaigns have been conducted over the western Pacific and the Arctic. We measured various microphysical properties of BC aerosol(e. g., mass concentration, size distribution, mixing state) and showed spatial and temporal distribution, large-scale transport, transformation, and removal processes of BC. We also developed global and regional models that can represent the detailed BC microphysical properties. Model calculations were validated by measurements. Using these models, impact of BC on the Earth's climate has been evaluated quantitatively.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (S), The University of Tokyo, 19101001
  • 北方森林生態系における植生起源有機エアロゾル生成の観測研究
    2010 - 2010
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • 大気中の揮発性・半揮発性有機酸の測定とエアロゾル生成・変質・吸湿特性への寄与
    科学研究費助成事業
    2009 - 2010
    河村 公隆; 宮崎 雄三
    夏季の西部北太平洋において白鳳丸航海(KH08-02)で採取した降水・霧水試料中に低分子有機酸を測定した。測定には、河村らが開発したフィナシルエステル・GC法(Kawamura et al.,1985)の改良版を用いた。試料を、0.1M KOH水溶液にてpH=8.5に調製したのち、ロータリーエバポレーターを用いて濃縮する。濃縮液を陽イオン交換樹脂に通すことによりすべての有機酸をRCOO^-K^+の化学形にする。次に、溶離液を濃縮・乾燥後、誘導体試薬(α,p-ジブロモアセトフェノン)と触媒(クラウンエーテル:dicyclohexyl-18-crown)を加え、アセトニトリル溶媒中で80℃,2時間反応させ、カルボン酸をp-ブロモフィナシルエステルに誘導体化した。有機酸エステルをシリカゲルカラムにより精製した後、ヒドロキシ有機酸のOH基をBSTFAによりTMS化した。札幌および西部北太平洋で採取した試料から分離した有機酸エステルをキャピラリーGCにて測定した結果、C_1-C_<10>直鎖、側鎖および芳香族の有機酸を検出した。更に、乳酸、グリコール酸(ヒドロキシ有機酸)を検出し、それぞれを定量した。また、GC/MSを用いて化合物の同定を行った。
    西部北太平洋上の降水・霧水中において初めて低分子モノカルボン酸(C_1-C_7、乳酸、グリコール酸、3-ヒドロキシブタン酸)を検出した。降水中(4試料)のギ酸(C1)の濃度は4-725ng/g、酢酸(C2)では30-238ng/g、プロピオン酸(C3)では12-12.5ng/g、ブタン酸(C4)では0.1-5.1ng/g、イソブタン酸(iC4)では0.1-2.7ng/g,Valeic acid(C5)では0.0-1.9ng/g,Isovaleic acid(iC5)では0.0-0.9ng/g,Caproic acid(C6)では0.0-5.3ng/g,乳酸では0-153ng/g,Glycolic acidでは0-32ng/g,3-Hydroxybutanoic acidでは0.1-13ng/gであった。ギ酸・酢酸の濃度は、西部北太平洋で採取した降水中(MROO-K02,2000)のシュウ酸濃度よりも高い傾向にあることが明らかとなり、低分子モノカルボン酸は重要な有機物であることがわかった。一方、霧水試料(n=9)についても測定した結果、ギ酸・酢酸が優位であることがわかった。濃度は、ギ酸で63-360ng/g,酢酸で35-303ng/gであり、雨に比べて著しく高いわけではなかった。また、ヒドロキシカルボン酸も検出された。一つの試料中で乳酸の濃度はギ酸・酢酸よりも高かった。
    現在、乳酸の吸湿特性(Growth factor)を測定するため、H-TDMAの調整をしている。
    日本学術振興会, 挑戦的萌芽研究, 北海道大学, 21654079
  • 大気中における含窒素有機エアロゾルの化学的挙動の解明
    2009 - 2010
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • Chemical compositions, spatial distributions and hygroscopic properties of organic aerosols from East and South Asia
    Grants-in-Aid for Scientific Research
    2007 - 2010
    KAWAMURA Kimitaka; MOCHIDA Michihiro; MIYAZAKI Yuzo; SEKI Osamu
    Atmospheric aerosols, collected from China, Korea, Mongolia, India and Japan as well as coastal and remote islands, have been studied for organic chemical compositions. The aerosols from Manshan, 40 km north of Beijing, showed higher concentrations of dicarboxylic acids such as oxalic acid than those from Beijing, suggesting a secondary (photochemical) production of water-soluble organic acids during atmospheric transport. Indian aerosols from New Delhi showed very high concentrations of low molecular weight diacids. Aerosols from Ulaanbaatar were studied for the hygroscopicity, indicating that the growth factor (Gf=1.22) is close to that of biomass burning aerosols.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (A), Hokkaido University, 19204055
  • A study on formation and removal processes of organic aerosol in Asia using an advanced mass spectrometry
    Grants-in-Aid for Scientific Research
    2007 - 2008
    TAKEGAWA Nobuyuki; KONDO Yutaka; KOIKE Makoto; MIYAZAKI Yuzo
    エアロゾル質量分析計(AMS)により得られたアジアの大都市(東京、広州、北京)におけるデータの解析とそれに関連する実験を行った。AMS の質量スペクトルや粒径分布から有機エアロゾルに関する多くの情報を引き出す方法を考案し、これに基づいてアジアの無機・有機エアロゾルの生成・消滅過程の研究を行った。夏季の北京において無機・有機エアロゾルが領域スケールで多量に生成され、それらが低気圧の通過に伴って広域へ輸送されていることが明らかになった。
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), The University of Tokyo, 19310005
  • 大気中における水溶性フミン状有機エアロゾルの高速自動測定法の開発
    2007 - 2008
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • Studies on Size Distribution and Mixing State of Black Carbon Aerosols in China
    Grants-in-Aid for Scientific Research
    2006 - 2007
    KOIKE Makoto; TAKEGAWA Nobuyki; MIYAZAKI Yuzo; KITA Kazuyuki
    Recent rapid growth of industrial activities in East Asia has been causing large increase in aerosols in this area. Atmospheric aerosols modify the radiation budget through scattering and absorption. Because black carbon (BC) aerosols (e.g., soot) efficiently absorb the solar radiation, they have been recognized one of the most important aerosol compounds the solar radiation, they have been recognized one of the mot important aerosol compounds for climate change.
    In the physical year of 2006, measurements of BC mass concentrations, size distribution, and mixing sate were in the Beijing region and Peal River Delta (PRD) region in China with Peking University Research Groups and some other international research groups. Aerosol chemical composition and some other parameters were also simultaneously measured.
    In the physical year of 2007, these data were precisely analyzed and interpreted from the viewpoint of emission sources, chemical production, transport processes, and removal processes using three-dimensional chemistry transport model. Observations show that BC concentrations in Beijing have a clear diurnal variation with a maximum during night. This feature was well reproduced by model calculations through diurnal variations, such as that in the boundary layer height. Although large day-to-day variations were found for secondary aerosols, such as inorganic aerosols, they were small for BC. Model calculations showed that BC concentrations were generally controlled by BC emissions within 100 km around Beijing within previous 24 hours. On the centrally, emissions as far as 500 km within previous 3 days were found to affect concentrations of secondary aerosols, such as sulfate through accumulations under stable synoptic-scale meteorological conditions.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), The University of Tokyo, 18310007
  • A study on formation process of anthropogenic organic aerosol using a highly advanced mass spectrometer
    Grants-in-Aid for Scientific Research
    2005 - 2006
    TAKEGAWA Nobuyuki; KONDO Yutaka; KOMAZAKI Yuichi; KOIKE Makoto; MIYAZAKI Yuzo
    1. Improvement of the accuracy of the Aerosol Mass Spectrometer (AMS)
    The particle collection efficiency (CE) of the AMS depends on relative humidity (RH) in sample air. The temperature of the AMS inlet manifold was maintained at > 10℃ above the ambient dew point to dry particles in the sample air (RH in the inlet < 53%). Assuming CE = 0.5 for the AMS, the mass concentrations of inorganic species (nitrate, sulfate, chloride, and ammonium) measured by the AMS agree with those measured by an Ion Chromatography analyzer (PILS-IC) to within 〜20%.
    2. Analysis of the mass spectra of selected organic compounds
    We have evaluated the contribution of selected low molecular weight dicarboxylic acids (diacids) to the m/z 44 signal of the AMS mass spectrum. We used ambient measurement data obtained in Tokyo and laboratory experiment data obtained using authentic standards of the selected organic acids. We have reported for the first time that the selected organic acids could account for 14% of the observed m/z 44 signal on average during the measurement period.
    3. Investigation of the seasonal and diurnal variations of anthropogenic organic aerosol in Tokyo
    In situ measurements of trace gases and aerosols were conducted at an urban site in Tokyo. Organic aerosol (OA) is classified into primary organic aerosol (POA) and secondary organic aerosol (SOA) using correlation with carbon monoxide (CO). We have found that POA does not exhibit a distinct diurnal variation for the summer, fall, and winter periods, while SOA shows a clear diurnal pattern. We have also found that the OA concentrations can be significantly enhanced within 〜0.5 days under conditions of high photochemical activity.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), The University of Tokyo, 17310006
  • Studies on physical-chemical processes of aerosol-cloud interaction
    Grants-in-Aid for Scientific Research
    2005 - 2006
    KONDO Yutaka; TAKEGAWA Nobuyuki; MIYAZAKI Yuzo; KOIKE Makoto
    Cloud condensation nuclei (CCN) activity is determined by aerosol diameter, fraction of water soluble components, and surface tension. We quantified CCN activities as a function of these parameters and related them with cloud formation processes.
    A)Controlling factors of CCN activities of aerosol in urban air
    We measured chemical composition, mixing states, and CCN activity of aerosol in Tokyo using an aerosol mass spectrometer, black carbon (BC) instruments, and a CCN counter. We found that CCN activity of thickly coated BC is controlled by the chemical composition of water soluble compounds. The CCN activity of thinly coated BC is controlled by the thickness of the coating.
    B)Measurements of aerosol-cloud interaction
    We conducted aircraft measurements of aerosol and cloud particles inside and outside of clouds located at 1-2 km near Japan in spring. We showed that thickly coated BC particles were taken up into clouds efficiently, consistent with the ground based measurements. This also shows that BC can be a good tracer to quantitatively study aerosol-cloud interaction.
    C)Time constant of CCN formation
    We showed that CCN activity of aerosol transported from the Asian continent within a few days is controlled mainly by the fraction of water soluble components from the data obtained in Jeju Island, Korea. Decrease in the surface tension of organic aerosol is also estimated to is contribute to the CCN activity. The CCN activity of various types of aerosol was measured also near Beijing. The observed CCN activity is consistent with the understandings obtained in Tokyo and Jeju Is.
    D)Calibration of the cloud probe and its aerodynamical characteristics
    Light scattering cloud probe was calibrated using standard particles with high precision. We made aerodynamical calculations of airflows around the probe mounted on the aircraft and found high collection efficiency of cloud droplets.
    E)We calculated size distribution of cloud droplets predicted from various CCN concentrations using a trajectory model. Sensitivity of CCN-cloud interaction was estimated by the numerical experiments.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (A), The University of Tokyo, 17201003
  • 水溶性有機エアロゾルの高感度実時間連続測定法の開発
    2005 - 2006
    宮﨑 雄三
    Principal investigator, Competitive research funding
  • Temporal variation of nano-particle, elemental carbon and organic carbon in the urban atmosphere
    Grants-in-Aid for Scientific Research
    2004 - 2005
    KOMAZAKI Yuichi; KONDO Yutaka; TAKEGAWA Nobuyuki; KOIKE Makoto
    EC comprises a significant portion of nano-particles, which are harmful to human health. EC has also been identified as making important contributions to the radiative heating of the atmosphere. Mass concentrations of EC in fine mode and CO were measured in Tokyo. EC were measured using a semi-continuous thermal-optical analyzer. The mass concentrations of non-volatile fine-particle measured by the calibrated SMPS combined with a heated inlet agreed with the independent EC measurements, demonstrating that the mass concentrations of non-volatile particle well those for EC. EC mass concentration was in volume equivalent diameters between 50-200 nm, peaking at around 130 nm. The correlation of EC and CO was generally compact throughout the measurement period. The slope of the EC-CO correlation (ΔEC/ΔCO) is therefore a useful parameter in validating EC emission inventories. The EC concentration and ΔEC/ΔCO showed distinct diurnal variation. On weekdays, EC and ΔEC/ΔCO reached maximum values, respectively, in the early morning, when the traffic density of heavy-duty trucks with diesel engines was highest. In addition, these values were lower by a factor of 2 on Sundays. The heavy truck traffic showed similar diurnal and weekday/weekend variations, indicating that exhaust from diesel engines is an important source of EC. Monthly mean ΔEC/ΔCO showed a seasonal variation, reaching broad maximum values in spring-autumn and reaching minimum values in midwinter. More stringent regulation of emissions of particles from diesel cars started in the Tokyo metropolitan area in October 2003. The ΔEC/ΔCO values did not change significantly (10%) after one year from the start of the new regulations, when the temperature dependence is taken into account. This indicates that the regulation of particle emissions in the Tokyo Metropolitan Area was not effective in reducing the EC concentrations after one year.
    Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), The University of Tokyo, 16310003
  • 東アジア大陸における元素状炭素および有機炭素の動態の解明
    科学研究費助成事業
    2004 - 2005
    近藤 豊; 小池 真; 宮崎 雄三
    元素状炭素(EC、あるいはブラックカーボン)は、高濃度になる地域では人体に悪影響を及ぼす。さらに太陽光の吸収が強いため大気の放射収支にも重要な影響を与える。本研究では都市域においてECの長期観測を行い、COをトレーサーとして用いることでECの排出源と大気中での挙動(季節変化、日変化、粒径分布)やそれらを支配する要因を明らかにした。このために高い時間分解能(1時間)と測定精度を持つ熱・光学方式によるEC計、及び大気導入部を加熱したScanning Mobility Particle Sizer(SMPS)(不揮発性粒子を選択的に測定)を用いて観測を行った。観測は代表的なメガシティーである東京都市域において通年(2003年5月ー2005年2月)で行ってきた。
    SMPSにより測定された不揮発性粒子の質量濃度とEC分析装置によるEC質量濃度は10%の範囲内で良く一致し、不揮発性粒子の質量濃度はEC質量濃度を代表することが示された。また、EC質量濃度の大部分は体積等価粒径130nm付近にピークを持つことがわかった。ECとCOは良い相関(R^2=0.62)を示し、類似の排出源を持つことが示唆された。観測全期間のEC、COの中央値はそれぞれ1.8±1.8μgm^<-3>、368±274ppbvであった。また、ディーゼル車からの排出が卓越する早朝のΔEC/ΔCO比は7.2±2.6×10^<-3>ngm^<-3>/ppbvと変動は小さい。ΔEC1ΔCO比は気温の季節変化に対応し春-秋に最大値を示した。東京都におけるEC排出の規制開始(2003年10月)後1年で東京都での粒子排出規制後1年でΔEC/ΔCO比に自然変動(10%)以上の変化は見られなかった。
    日本学術振興会, 特定領域研究, 東京大学, 16030203
  • 大気中における極性有機エアロゾルの挙動・起源の解明
    2004
    Competitive research funding