[{ReI(CO)3(Hbim)}3(tpta)]2 (1, Hbim− = 2,2′-biimidazolate monoanion, tpta = 2,4,6-tripyridyl-1,3,5-triazine) was prepared as a nano-space supramolecule by using a new group of H-bonded coordination capsules.
Both two-step mechanoresponsive luminescence and mechanical stimuli-induced release of guest-molecules are exhibited by the same fluorescent cyclophane.
The solid solutions composed of different ratios of two Werner complexes showed controlled acetone gate-sorption properties.
POM based non-centrosymmetric inorganic–organic hybrids are designed by gradually introducing asymmetry into the building units.