Change of permeability in high-strength and ultra-low-permeability concrete in seawater
Satoshi Maezaki, Yoshitaka Nara, Masaji Kato, Kazutoshi Shibuya
5th ISRM Young Scholars' Symposium on Rock Mechanics and International Symposium on Rock Engineering for Innovative Future, YSRM 2019 971 - 976 2019
For geological disposal of radioactive wastes, the confinement of radionuclides is necessary. The geological disposal of radioactive waste is designed with a confinement function by suppressing the adsorption and migration of nuclides by natural and engineered barriers. However, long half-life low heat generating radioactive waste (TRU waste) contains wastes with a high concentration of nuclides that are difficult to adsorb on engineered and natural barriers. As an alternative method, long-term confinement with a waste package using High-Strength and Ultra-Low-Permeability Concrete (HSULPC) is considered so that a sufficient confinement function works even in such a case. It was shown that a macroscopic fracture in HSULPC in distilled water was sealed by the precipitation of calcium compounds. In artificial seawater, the precipitation of calcium compounds happened more significantly. However, none has not studied the permeability changes in HSULPC due to the fracture sealing by the precipitation of calcium compounds yet. In this study, we have conducted permeability measurements on a macro-fractured HSULPC. In particular, we kept the macro-fractured HSULPC specimen in an artificial seawater, and investigated the influence of calcium compound precipitation on hydraulic conductivity. It was shown that the introduction of macroscopic fracture increased the hydraulic conductivity. In addition, when the macro-fractured HSULPC was kept in artificial seawater, the fracture was filled partly by the precipitation of calcium compounds, which decreased the hydraulic conductivity. When HSULPC is put in the underground condition, the fracture closure in HSULPC can occur due to the existence of groundwater with high electrolyte concentration. Therefore, even if HSULPC is fractured, it is considered that self-healing of the fracture can occur, and the confining ability can be maintained for a long-term.