研究者データベース
| LIST BENJAMIN(リスト ベンジヤミン) |
| 創成研究機構化学反応創成研究拠点 |
| 特任教授 |
Last Updated :2024/05/09
研究活動情報
論文
- Sebastian Armin Schwengers, Gabriela Guillermina Gerosa, Tynchtyk Amatov, Naoki Yasukawa, Sebastian Brunen, Markus Leutzsch, Benjamin Mitschke, Grigory Shevchenko, Benjamin ListAngewandte Chemie International Edition 2023年06月20日
- Hui Zhou, Roberta Properzi, Markus Leutzsch, Paola Belanzoni, Giovanni Bistoni, Nobuya Tsuji, Jung Tae Han, Chendan Zhu, Benjamin ListJournal of the American Chemical Society 145 9 4994 - 5000 2023年03月08日
- Nobuya Tsuji, Pavel Sidorov, Chendan Zhu, Yuuya Nagata, Timur Gimadiev, Alexandre Varnek, Benjamin ListAngewandte Chemie International Edition 62 11 2023年02月06日
- Hui Zhou, Jung Tae Han, Nils Nöthling, Monika M. Lindner, Judith Jenniches, Clemens Kühn, Nobuya Tsuji, Li Zhang, Benjamin ListJournal of the American Chemical Society 144 23 10156 - 10161 2022年06月15日
- Sebastian A. Schwengers, Chandra Kanta De, Oleg Grossmann, Joyce A. A. Grimm, Natascha R. Sadlowski, Gabriela G. Gerosa, Benjamin ListJournal of the American Chemical Society 143 36 14835 - 14844 2021年09月15日 [査読有り]
- Tynchtyk Amatov, Nobuya Tsuji, Rajat Maji, Lucas Schreyer, Hui Zhou, Markus Leutzsch, Benjamin ListJournal of the American Chemical Society 143 36 14475 - 14481 2021年09月15日 [査読有り]
- Carla Obradors, Benjamin ListJournal of the American Chemical Society 143 18 6817 - 6822 2021年05月12日 [査読有り]
- Chendan Zhu, Francesca Mandrelli, Hui Zhou, Rajat Maji, Benjamin ListJournal of the American Chemical Society 143 9 3312 - 3317 2021年03月10日 [査読有り]
- Jie Ouyang, Hanyong Bae, Samuel Jordi, Quang Minh Dao, Sandro Dossenbach, Stefanie Dehn, Julia B. Lingnau, Chandra Kanta De, Philip Kraft, Benjamin ListAngewandte Chemie International Edition 60 11 5666 - 5672 2021年03月08日 [査読有り]
- Pinglu Zhang, Nobuya Tsuji, Jie Ouyang, Benjamin ListJournal of the American Chemical Society 143 2 675 - 680 2021年01月20日 [査読有り]
- Roberta Properzi, Philip S. J. Kaib, Markus Leutzsch, Gabriele Pupo, Raja Mitra, Chandra Kanta De, Lijuan Song, Peter R. Schreiner, Benjamin ListNature Chemistry 12 12 1174 - 1179 2020年12月 [査読有り]
- Gabriela Guillermina Gerosa, Sebastian Armin Schwengers, Rajat Maji, Chandra Kanta De, Benjamin ListAngewandte Chemie International Edition 59 46 20485 - 20488 2020年11月09日 [査読有り]
- Zhipeng Zhang, Martin Klussmann, Benjamin ListSynlett 31 16 1593 - 1597 2020年10月 [査読有り]
Kinetic study of organic reactions, especially multistep catalytic reactions, is crucial to in-depth understanding of reaction mechanisms. Here we report our kinetic study on the chiral disulfonimide-catalyzed cyanosilylation of an aldehyde, which revealed that two molecules of TMSCN are involved in the rate-determining C–C bond-forming step. In addition, the apparent activation energy, enthalpy of activation, and entropy of activation were deduced through a study of the temperature dependence of the reaction rates. More importantly, a novel and efficient method that makes use of the progress rates was developed to treat kinetic data obtained by continuous monitoring of the progress of a reaction by in situ FTIR. - Benjamin Mitschke, Mathias Turberg, Benjamin ListChem 6 10 2515 - 2532 2020年10月 [査読有り]
- Benjamin List, Vijay N. Wakchaure, Carla ObradorsSynlett 31 17 1707 - 1712 2020年10月 [査読有り]
While imines are frequently used substrates in asymmetric Brønsted acid catalysis, their corresponding salts are generally considered unsuitable reaction partners. Such processes are challenging because they require the successful competition of a catalytic amount of a chiral anion with a stoichiometric amount of an achiral one. We now show that enantiopure disulfonimides enable the asymmetric reduction of N–H imine hydrochloride salts using Hantzsch esters as hydrogen source. Our scalable reaction delivers crystalline primary amine salts in great efficiency and enantioselectivity and the discovery suggests potential of this approach in other Brønsted acid catalyzed transformations of achiral iminium salts. Kinetic studies and acidity data suggest a bifunctional catalytic activation mode. - Hui Zhou, Han Yong Bae, Markus Leutzsch, Jennifer L. Kennemur, Diane Bécart, Benjamin ListJournal of the American Chemical Society 142 32 13695 - 13700 2020年08月12日 [査読有り]
- Santanu Ghosh, Sayantani Das, Chandra Kanta De, Diana Yepes, Frank Neese, Giovanni Bistoni, Markus Leutzsch, Benjamin ListAngewandte Chemie International Edition 59 30 12347 - 12351 2020年07月20日 [査読有り]
- Diana Yepes, Frank Neese, Benjamin List, Giovanni BistoniJournal of the American Chemical Society 142 7 3613 - 3625 2020年02月19日 [査読有り]
- Hyejin Kim, Gabriela Gerosa, Jonas Aronow, Pinar Kasaplar, Jie Ouyang, Julia B. Lingnau, Paul Guerry, Christophe Farès, Benjamin ListNature Communications 10 1 2019年12月 [査読有り]
- Lucas Schreyer, Roberta Properzi, Benjamin ListAngewandte Chemie International Edition 58 37 12761 - 12777 2019年09月09日 [査読有り]
- Francesca Mandrelli, Aurélie Blond, Thomas James, Hyejin Kim, Benjamin ListAngewandte Chemie International Edition 58 33 11479 - 11482 2019年08月12日 [査読有り]
- Denis Höfler, Richard Goddard, Nils Nöthling, Benjamin ListSynlett 30 04 433 - 436 2019年03月 [査読有り]
The design and synthesis of a strong, dendralenic C–H acid is described. Crystal structure analyses confirm the proposed structure. Despite the moderate stability of our motif, an application to Brønsted acid catalysis has been explored. - Jie Ouyang, Jennifer L. Kennemur, Chandra Kanta De, Christophe Farès, Benjamin ListJournal of the American Chemical Society 141 8 3414 - 3418 2019年02月27日 [査読有り]
- Benjamin List, Grigory Shevchenko, Gabriele PupoSynlett 30 01 49 - 53 2019年01月 [査読有り]
Enantiopure α-hydroxy carbonyl compounds are common scaffolds in natural products and pharmaceuticals. Although indirect approaches towards their synthesis are known, direct asymmetric methodologies are scarce. Herein, we report the first direct asymmetric α-hydroxylation of α-branched ketones through enol catalysis, enabling a facile access to valuable α-keto tertiary alcohols. The transformation, characterized by the use of nitrosobenzene as the oxidant and a new chiral phosphoric acid as the catalyst, delivers a good scope and excellent enantioselectivities. - Lucas Schreyer, Philip S. J. Kaib, Vijay N. Wakchaure, Carla Obradors, Roberta Properzi, Sunggi Lee, Benjamin ListScience 362 6411 216 - 219 2018年10月12日 [査読有り]
- Tim Gatzenmeier, Mathias Turberg, Diana Yepes, Youwei Xie, Frank Neese, Giovanni Bistoni, Benjamin ListJournal of the American Chemical Society 140 40 12671 - 12676 2018年10月10日 [査読有り]
- Benjamin List, Grigory Shevchenko, Stefanie DehnSynlett 29 17 2298 - 2300 2018年10月 [査読有り]
We report a Brønsted acid mediated direct α-hydroxylation of cyclic α-branched ketones via a tandem aminoxylation/N–O bond-cleavage process. Nitrosobenzene is used as the oxidant and subsequently promotes the liberation of the free alcohol. The desired products could be isolated in moderate to good yields at a maximum tested scale of 10 mmol. Derivatizations of the obtained products are presented. - Han Yong Bae, Benjamin ListChemistry - A European Journal 24 52 13767 - 13772 2018年09月18日 [査読有り]
- Sunggi Lee, Han Yong Bae, Benjamin ListAngewandte Chemie International Edition 57 37 12162 - 12166 2018年09月10日 [査読有り]
- J. Popovic, D. Höfler, J. P. Melchior, A. Münchinger, B. List, J. MaierThe Journal of Physical Chemistry Letters 9 17 5116 - 5120 2018年09月06日 [査読有り]
- Grigory A. Shevchenko, Barry Oppelaar, Benjamin ListAngewandte Chemie International Edition 57 33 10756 - 10759 2018年08月13日 [査読有り]
- Han Yong Bae, Denis Höfler, Philip S. J. Kaib, Pinar Kasaplar, Chandra Kanta De, Arno Döhring, Sunggi Lee, Karl Kaupmees, Ivo Leito, Benjamin ListNature Chemistry 10 8 888 - 894 2018年08月 [査読有り]
- Denis Höfler, Richard Goddard, Julia B. Lingnau, Nils Nöthling, Benjamin ListAngewandte Chemie International Edition 57 27 8326 - 8329 2018年07月02日 [査読有り]
- Nobuya Tsuji, Jennifer L. Kennemur, Thomas Buyck, Sunggi Lee, Sébastien Prévost, Philip S. J. Kaib, Dmytro Bykov, Christophe Farès, Benjamin ListScience 359 6383 1501 - 1505 2018年03月30日 [査読有り]
- Tim Gatzenmeier, Philip S. J. Kaib, Julia B. Lingnau, Richard Goddard, Benjamin ListAngewandte Chemie International Edition 57 9 2464 - 2468 2018年02月23日 [査読有り]
- Mattia Riccardo Monaco, Daniele Fazzi, Nobuya Tsuji, Markus Leutzsch, Saihu Liao, Walter Thiel, Benjamin ListJournal of the American Chemical Society 138 44 14740 - 14749 2016年10月 [査読有り][通常論文]
受賞
- 2021年 TCR Lecture,100th CSJ Annual Meeting, Japan
- 2021年 Herbert C. Brown Award 2022 for Creative Reasearch in Synthetic Methodes
- 2021年 Nobel Prize in Chemistry
- 2019年 Herbert C. Brown Lecture, Purdue University, Indiana, USA
- 2019年 Web of Science Citation Laureate™ in Chemistry
- 2018年 Member of the German National Academy of Science Leopoldina