MURAYAMA Toru
| Institute for Catalysis Catalytic Transformation Research Division | Professor |
Last Updated :2025/11/06
■Researcher basic information
Researchmap personal page
Home Page URL
Researcher ID
- F-4924-2012
J-Global ID
Research Field
Educational Organization
- Master's degree program, Graduate School of Chemical Sciences and Engineering
- Doctoral (PhD) degree program, Graduate School of Chemical Sciences and Engineering
■Career
Career
- Apr. 2024 - Present
Hokkaido University, Institute for Catalysis, Professor, Japan - Dec. 2020 - Mar. 2024
Tokyo Metropolitan University, Research Center for Hydrogen Energy-based Society, Project Professor - Apr. 2020 - Mar. 2024
Yantai University, Yantai Key Laboratory of Gold Catalysis and Engineering, Shandong Applied Research Center of Gold Nanotechnology, School of Chemistry & Chemical Engineering, Professor, China - Apr. 2016 - Nov. 2020
Tokyo Metropolitan University, Research center for gold chemistry, Project professor - Apr. 2015 - Mar. 2016
Tokyo Metropolitan University, Research center for gold chemistry, Project associate professor - Apr. 2010 - Mar. 2015
Hokkaido University, Catalysis Research Center, assistant professor
Educational Background
■Research activity information
Papers
- Mo anchor as promoter to initiate selective catalytic ammonia oxidation to nitrogen at 40 ℃
Yiyang Zhang, Jialong Lin, Haifeng Wang, Kazuya Yamaguchi, Tamao Ishida, Jie Zhang, Guangli Xiu, Toru Murayama, Mingyue Lin
Catalysis Today, Dec. 2025, [Peer-reviewed], [Internationally co-authored], [International Magazine]
Scientific journal - Cu-based catalysts encased in a nanoporous carbon shell derived from furfuryl alcohol for isomeric nitrophenol degradation
Shinichi Hata, Izumi Takenaga, Sho Kitano, Hiroki Habazaki, Haifeng Wang, Toru Murayama, Tamao Ishida, Yukou Du, Naoki Toshima, Yukihide Shiraishi
MRS Communications, 22 May 2025, [Peer-reviewed], [International Magazine]
Scientific journal - Revealing the Role of Mn–O Bonds in Electrocatalytic Methanol Oxidation to Value-Added Formate in LaMnO3
Xinlin Wang, Fan Zhou, Yunfei Gao, Yuhang Li, Bingxue Cheng, Toru Murayama, Tamao Ishida, Mingyue Lin, Guangli Xiu
ACS Sustainable Chemistry & Engineering, 13, 12, 4845, 4856, 31 Mar. 2025, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Au Nanoclusters on Vanadium-Doped ZrO2 Nanoparticles for Propylene Oxidation: An Investigation into the Impact of V
Caixia Qi, Jingzhou Zhang, Xun Sun, Libo Sun, Huijuan Su, Toru Murayama
MATERIALS, 18, 5, Mar. 2025, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Nanocrystalline High-Dimensional Nb2O5 for Efficient Electroreductive Dicarboxylation of CO2 with Cycloalkane
Yuanming Xie, Xinlin Wang, Junjun Mao, Chenchen Zhang, Qingqing Song, Toru Murayama, Mingyue Lin, Jiawei Zhang, Yang Lou, Chengsi Pan, Ying Zhang, Yongfa Zhu
ACS Catalysis, 14, 24, 18624, 18632, 20 Dec. 2024, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Preparation and Catalytic Properties of Gold Single‐Atom and Cluster Catalysts Utilizing Nanoparticulate Mg‐Al Layered Double Hydroxides
Tamao Ishida, Akihiro Nakayama, Ayano Yoshida, Chika Aono, Tetsuo Honma, Norihito Sakaguchi, Ayako Taketoshi, Takashi Fujita, Toru Murayama, Tetsuya Shimada, Shinsuke Takagi
ChemPlusChem, 90, 3, 11 Oct. 2024, [Peer-reviewed], [International Magazine]
English, Scientific journal - CO Oxidation at Low Temperatures over the Au Cluster Supported on Crystalline Silicotitanate
Miyu Muraoka, Takuto Miyatani, Akihiro Sembuku, Tamao Ishida, Toru Murayama, Yoshihiro Kubota, Satoshi Inagaki
ACS Omega, 9, 40, 41696, 41702, 08 Oct. 2024, [Peer-reviewed], [International Magazine]
English, Scientific journal - Theoretical investigation of CO oxidation over polyoxometalate-supported Au cluster catalyst
Tomohisa Yonemori, Yasutaka Hamada, Tamao Ishida, Toru Murayama, Takashi Kawakami, Shusuke Yamanaka, Mitsutaka Okumura
Journal of Catalysis, 438, Oct. 2024, [Peer-reviewed], [International Magazine]
English, Scientific journal - High-Dimensional Nb2O5 with NbO6 Octahedra for Efficient Electrocatalytic Upgrading of Methanol to Formate
Xinlin Wang, Chuqian Xiao, Yuanming Xie, Chunqi Yang, Yuhang Li, Ying Zhang, Toru Murayama, Tamao Ishida, Mingyue Lin, Guangli Xiu
ACS Applied Materials & Interfaces, 16, 34, 44938, 44946, 28 Aug. 2024, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Efficient formation of propylene oxide under low hydrogen concentration in propylene epoxidation over Au nanoparticles supported on V-doped TS-1
Caixia Qi, Yanan Cheng, Zixuan Yang, Tamao Ishida, Huijuan Su, Jingzhou Zhang, Xun Sun, Libo Sun, Lijun Zhao, Toru Murayama
Journal of Catalysis, 436, Aug. 2024, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Ring–Opening Mechanism of O-heterocycles into α,ω-Diols over Ni−La(OH)
3 : C−O Bond Hydrogenolysis of THFA to 1,5-Pentanediol as a Case Study
Mohammed Al-Yusufi, Dirk Michalik, Christoph Kubis, Toru Murayama, Tamao Ishida, Ali M. Abdel-Mageed, Angela Köckritz
ChemCatChem, 16, 13, 08 Jul. 2024, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - In situ/operando spectroscopic evidence on associative redox mechanism for periodic unsteady-state water–gas shift reaction on Au/CeO2 catalyst
Ningqiang Zhang, Lingcong Li, Yuan Jing, Yucheng Qian, Duotian Chen, Nobutaka Maeda, Toru Murayama, Takashi Toyao, Ken-ichi Shimizu
Journal of Catalysis, 433, 115500, 115500, May 2024, [Peer-reviewed], [International Magazine]
English, Scientific journal - Highly Active and Sintering-Resistant Pt Clusters Supported on FeOx–Hydroxyapatite Achieved by Tailoring Strong Metal–Support Interactions
Yunxia Liu, Guandong Wu, Rile Ge, Xunzhu Jiang, Lin Li, Tamao Ishida, Toru Murayama, Botao Qiao, Junhu Wang
ACS Applied Materials & Interfaces, 16, 17, 22007, 22015, 01 May 2024, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Role of the heptagonal channel of crystalline Mo3VOx catalyst for the selective oxidation of acrolein and methacrolein
Satoshi Ishikawa, Nagisa Noda, Kosuke Shimoda, Toru Murayama, Wataru Ueda
Catalysis Science & Technology, 14, 11, 3160, 3166, 23 Apr. 2024, [Peer-reviewed], [International Magazine]
English, Scientific journal - The Development of the Regenerable Catalytic System in Selective Catalytic Oxidation of Ammonia with High N2 Selectivity
Haifeng Wang, Toru Murayama, Tamao Ishida, Ken-ichi Shimizu, Norihito Sakaguchi, Kazuya Yamaguchi, Hiroki Miura, Tetsuya Shishido
ACS Applied Materials & Interfaces, 16, 15, 18693, 18702, 17 Apr. 2024, [Peer-reviewed], [International Magazine]
English, Scientific journal - Prolonging the n-type conduction of thermoelectric carbon nanotubes exposed to warm air by mixing hydrated water into the adsorbed dopant layers composed of Li+-receptor molecules
Shinichi Hata, Chika Nakagawa, Ayako Taketoshi, Toru Murayama, Tamao Ishida, Yukou Du, Yukihide Shiraishi, Naoki Toshima
RSC Applied Interfaces, Royal Society of Chemistry (RSC), Apr. 2024, [Peer-reviewed], [International Magazine]
Scientific journal, The n-type properties of carbon nanotubes are stabilized in the ambient atmosphere by hydrated water on a cationic molecular adsorption layer supplemented with Li+, which slows the diffusion of thermally active oxygen molecules. - Manipulation of the electronic state of Au to boost the catalytic efficiency of Au/polyaniline by doping engineering
Libo Sun, Heshun Jing, Shuo Zhou, Wenyu Tan, Xinyuan Ren, Miao Zhang, Xun Sun, Haifeng Wang, Toru Murayama, Caixia Qi
Molecular Catalysis, 557, Mar. 2024, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Decoration of Gold and Platinum Nanoparticle Catalysts by 1 nm Thick Metal Oxide Overlayer and Its Effect on the CO Oxidation Activity
Kaho Okayama, Akihiro Nakayama, Toru Murayama, Norihito Sakaguchi, Feng Hong, Botao Qiao, Junhu Wang, Tetsuya Shimada, Shinsuke Takagi, Tamao Ishida
ACS Applied Materials & Interfaces, 16, 4, 4570, 4580, 19 Jan. 2024, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal - Niedrige Temperatur Hydrierung von CO2 zu Methanol in Wasser auf ZnO‐geträgerten CuAu‐Nanolegierungen
Jawaher Mosrati, Tamao Ishida, Hung Mac, Mohammed Al‐Yusufi, Tetsuo Honma, Magdalena Parliniska‐Wojtan, Yasuhiro Kobayashi, Alexander Klyushin, Toru Murayama, Ali M. Abdel‐Mageed
Angewandte Chemie, 18 Dec. 2023, [Peer-reviewed], [Internationally co-authored], [International Magazine]
Scientific journal - Low‐Temperature Hydrogenation of CO2 to Methanol in Water on ZnO‐Supported CuAu Nanoalloys
Jawaher Mosrati, Tamao Ishida, Hung Mac, Mohammed Al‐Yusufi, Tetsuo Honma, Magdalena Parliniska‐Wojtan, Yasuhiro Kobayashi, Alexander Klyushin, Toru Murayama, Ali M. Abdel‐Mageed
Angewandte Chemie International Edition, 62, 51, e202311340, 18 Dec. 2023, [Peer-reviewed], [Internationally co-authored], [International Magazine]
English, Scientific journal, Optimizing processes and materials for the valorization of CO2 to hydrogen carriers or platform chemicals is a key step for mitigating global warming and for the sustainable use of renewables. We report here on the hydrogenation of CO2 in water on ZnO-supported CuAu nanoalloys, based on ≤7 mol % Au. Cux Auy /ZnO catalysts were characterized using 197 Au Mössbauer, in situ X-ray absorption (Au LIII - and Cu K-edges), and ambient pressure X-ray photoelectron (APXP) spectroscopic methods together with X-ray diffraction and high-resolution electron microscopy. At 200 °C, the conversion of CO2 showed a significant increase by 34 times (from 0.1 to 3.4 %) upon increasing Cu93 Au7 loading from 1 to 10 wt %, while maintaining methanol selectivity at 100 %. Limited CO selectivity (4-6 %) was observed upon increasing temperature up to 240 °C but associated with a ≈3-fold increase in CO2 conversion. Based on APXPS during CO2 hydrogenation in an H2 O-rich mixture, Cu segregates preferentially to the surface in a mainly metallic state, while slightly charged Au submerges deeper into the subsurface region. These results and detailed structural analyses are topics of the present contribution. - Au/Nb2O5-catalyzed N-Formylation of Amines Utilizing High Selectivity to Formate Intermediate in CO2 Hydrogenation
Mitsuyo Hidaka, Mingyue Lin, Hiroki Yamakawa, Akihiro Nakayama, Toru Murayama, Tetsuya Shimada, Shinsuke Takagi, Tamao Ishida
CHEMISTRY LETTERS, 52, 12, 874, 877, Dec. 2023
English, Scientific journal - Dual-core drive hydrogen transfer heterogeneous catalysts based on iridium-enzyme co-modified carbon nanotubes for aromatic aldehyde hydrogenation
Li-Jun Zhao, Caimei Zhang, Shixin Zhang, Jiayang Chen, Xiaoyi Lv, Huijuan Su, Xun Sun, Toru Murayama, Caixia Qi
Journal of Catalysis, Dec. 2023
Scientific journal - High Selectivity Cofactor NADH Regeneration Organic Iridium Complexes Used for High-Efficiency Chem-Enzyme Cascade Catalytic Hydrogen Transfer
Li-Jun Zhao, Caimei Zhang, Shixin Zhang, Xiaoyi Lv, Jiayang Chen, Xun Sun, Huijuan Su, Toru Murayama, Caixia Qi
Inorganic Chemistry, 62, 43, 17577, 17582, 30 Oct. 2023, [International Magazine]
English, Scientific journal - In-situ Raman unveiled Nb-O-bond-dependency selectivity for methanol electro-oxidation at high current density
Xinlin Wang, Chuqian Xiao, Yuhang Li, Toru Murayama, Tamao Ishida, Mingyue Lin, Guangli Xiu
Applied Catalysis A: General, Aug. 2023
Scientific journal - Au Clusters Supported on Defect-Rich Ni-Ti Oxides Derived from Ultrafine Layered Double Hydroxides (LDHs) for CO Oxidation at Ambient Temperature
Ayu Takahashi, Akihiro Nakayama, Toru Murayama, Norihito Sakaguchi, Tetsuya Shimada, Shinsuke Takagi, Tamao Ishida
Catalysts, 13, 8, 1155, 1155, MDPI AG, 26 Jul. 2023
Scientific journal, Ultrafine layered double hydroxides (LDHs) have abundant hydroxy groups at their edge sites, serving as anchor sites for metal NPs. Furthermore, transformation of ultrafine LDHs into mixed metal oxides (MMOs) generates abundant oxygen vacancies, which are advantageous for O2 activation during Au-catalyzed CO oxidation. We used ultrafine Ni-Ti LDHs with low crystallinity or Ni-Ti MMOs supported on SiO2 onto which Au NPs were deposited by deposition–precipitation (DP) and DP–urea (DPU). The catalytic activity of the Au catalysts was significantly affected by the preparation method, with the highest activity obtained by depositing Au onto LDH/SiO2 by DPU, followed by transformation of LDH to MMO (Au/Ni-Ti MMO/SiO2 (LDH-DPU)). The presence of Au on LDHs affected the transformation of LDHs into MMOs, resulting in LDH-DPU having the greatest number of oxygen vacancies in the TiO2 domain in MMOs. Consequently, the adsorbed or the lattice oxygen on the surface of LDH-DPU can be easily utilized for CO oxidation at low temperatures. Moreover, the catalytic activity of LDH-DPU increased with water vapor concentration up to 100% relative humidity at room temperature, suggesting the potential of Au/Ni-Ti MMO/SiO2 as an air purification catalyst. - Metal–Support Interaction in Gold Zeolitic Octahedral Metal Oxide and the Catalytic Activity for Low-Temperature Alcohol Oxidation
Yukang Wang, Guijin Zheng, Qianqian Zhu, Qiangqiang Tong, Bolun Yu, Tamao Ishida, Toru Murayama, Yanshuo Li, Wataru Ueda, Zhenxin Zhang
Langmuir, 39, 29, 10163, 10177, 25 Jul. 2023, [International Magazine]
English, Scientific journal, Au nanoparticles are efficient catalysts for selective oxidations. The interaction between Au nanoparticles and supports is critical for achieving high catalytic activity. Herein, Au nanoparticles are supported on a zeolitic octahedral metal oxide based on Mo and V. The charge of Au is controlled by the surface oxygen vacancies of the supports, and the redox property of the zeolitic vanadomolybdate is highly dependent on Au loading. The Au-supported zeolitic vanadomolybdate is used as a heterogeneous catalyst for alcohol oxidation under mild conditions with molecular oxygen as an oxidant. The supported Au catalyst can be recovered and reused without the loss of activity. - Gold/Substituted Hydroxyapatites for Oxidative Esterification: Control of Thin Apatite Layer on Gold Based on Strong Metal-Support Interaction (SMSI) Results in High Activity.
Ayako Taketoshi, Yuvaraj Gangarajula, Ryusei Sodenaga, Akihiro Nakayama, Mitsutaka Okumura, Norihito Sakaguchi, Toru Murayama, Tetsuya Shimada, Shinsuke Takagi, Masatake Haruta, Botao Qiao, Junhu Wang, Tamao Ishida
ACS applied materials & interfaces, 15, 28, 34290, 34302, 19 Jul. 2023, [International Magazine]
English, Scientific journal, Gold nanoparticles (Au NPs) deposited on various cation- and anion-substituted hydroxyapatites (Au/sHAPs) show oxidative strong metal-support interaction (SMSI), wherein a thin layer of the sHAP covered the surface of the Au NPs by heat treatment in an oxidative atmosphere. Calcination of Au/sHAPs at 300 °C caused a partial SMSI and that at 500 °C gave fully encapsulated Au NPs. We investigated the influence of the substituted ions in sHAP and the degree of the oxidative SMSI on the catalytic performance of Au/sHAPs for oxidative esterification of octanal or 1-octanol with ethanol to obtain ethyl octanoate. The catalytic activity depends on the size of the Au NPs but not on the support used, owing to the similarity of the acid and base properties of sHAPs except for Au/CaFAP. The presence of a large number of acidic sites on CaFAP lowered the product selectivity, but all other sHAPs exhibited similar activity when the Au particle size was almost the same, owing to the similarity of the acid and base properties. Au/sHAPs_O2 with SMSI exhibited higher catalytic activity than Au/sHAPs_H2 without SMSI despite the fact that the number of exposed surface Au atoms was decreased by the SMSI. In addition, the oxidative esterification reaction proceeded even though the Au NPs were fully covered by the sHAP layer when the thickness of the layer was controlled to be less than 1 nm. The substrate can access the surfaces of the Au NPs covered by the thin sHAP layer (<1 nm), and the presence of the sHAP structure in close contact with the Au NPs resulted in significantly higher catalytic activity compared with that for fully exposed Au NPs deposited on the sHAPs. This result suggests that maximizing the contact area between the Au NPs and the sHAP support based on the SMSI enhances the catalytic activity of Au. - Sodium ion intercalation in vanadium oxide promotes low-temperature NH3-SCR activity: Sodium vanadium bronzes (Na0.33V2O5) for NOx removal
Yusuke Inomata, Hiroe Kubota, Yoshinori Honmatsu, Hiroaki Takamitsu, Sosuke Sakotami, Kazuhiro Yoshida, Takashi Toyao, Ken-ichi Shimizu, Toru Murayama
APPLIED CATALYSIS B-ENVIRONMENTAL, 328, Jul. 2023
English, Scientific journal - Selective formation of acetate intermediate prolongs robust ethylene removal at 0 degrees C for 15 days
Mingyue Lin, Haifeng Wang, Takashi Takei, Hiroki Miura, Tetsuya Shishido, Yuhang Li, Jinneng Hu, Yusuke Inomata, Tamao Ishida, Masatake Haruta, Guangli Xiu, Toru Murayama
NATURE COMMUNICATIONS, 14, 1, 2885, 2885, 20 May 2023, [Peer-reviewed], [International Magazine]
English, Scientific journal - Long-Alkyl-Chain Phosphonium Surfactant Molecular Wrapping to Block Oxygen Impurities in n-Type Carbon Nanotubes for Thermoelectric Applications
Shinichi Hata, Fumiya Kitano, Hiroki Ihara, Toru Murayama, Yukou Du, Yukihide Shiraishi, Naoki Toshima
ACS Applied Engineering Materials, American Chemical Society (ACS), 23 Feb. 2023
Scientific journal - Pd-Rh Alloyed Nanoparticles on Zeolite Imidazolide Framework-67 for Methyl Orange Degradation
Shinichi Hata, Yuki Sakai, Nanami Tani, Sho Kitano, Hiroki Habazaki, Akari Hirakawa, Hinako Tanaka, Yusuke Inomata, Toru Murayama, Masatake Haruta, Yukou Du, Yukihide Shiraishi, Naoki Toshima
ACS Applied Nano Materials, 5, 11, 16231, 16241, 25 Nov. 2022
Scientific journal - Obituary for Masatake Haruta (1947–2022)
Toru Murayama, Tamao Ishida
Gold Bulletin, Oct. 2022
Scientific journal - Enhancement effect of strong metal-support interaction (SMSI) on the catalytic activity of substituted-hydroxyapatite supported Au clusters
Akihiro Nakayama, Ryusei Sodenaga, Yuvaraj Gangarajula, Ayako Taketoshi, Toru Murayama, Tetsuo Honma, Norihito Sakaguchi, Tetsuya Shimada, Shinsuke Takagi, Masatake Haruta, Botao Qiao, Junhu Wang, Tamao Ishida
Journal of Catalysis, 410, 194, 205, Elsevier BV, Jun. 2022
Scientific journal - Understanding the Distinct Effects of Ag Nanoparticles and Highly Dispersed Ag Species on N2 Selectivity in NH3–SCO Reaction
Haifeng Wang, Toru Murayama, Mingyue Lin, Norihito Sakaguchi, Masatake Haruta, Hiroki Miura, Tetsuya Shishido
ACS Catalysis, 6108, 6118, American Chemical Society (ACS), 09 May 2022
Scientific journal - Defective NiO as a Stabilizer for Au Single-Atom Catalysts
Chihiro Mochizuki, Yusuke Inomata, Shunsaku Yasumura, Mingyue Lin, Ayako Taketoshi, Tetsuo Honma, Norihito Sakaguchi, Masatake Haruta, Ken-ichi Shimizu, Tamao Ishida, Toru Murayama
ACS Catalysis, 6149, 6158, American Chemical Society (ACS), 09 May 2022
Scientific journal - Effect of poly(N-vinylpyrrolidone) ligand on catalytic activities of Au nanoparticles supported on Nb2O5 for CO oxidation and furfural oxidation
Mingyue Lin, Chihiro Mochizuki, Tamao Ishida, Ying Zhang, Masatake Haruta, Toru Murayama
Catalysis Today, Elsevier BV, Apr. 2022
Scientific journal - Efficient non-volatile organogold complex for TiO
2 -supported gold cluster catalysts: Preparation and catalytic activity for CO oxidation
Luong Xuan Dien, Toru Murayama, Nguyen Tuan Hung, Quang Duc Truong, Huynh Dang Chinh, Masamichi Yoshimura, Masatake Haruta, Tamao Ishida
Journal of Catalysis, 408, 236, 244, Apr. 2022
Scientific journal - Transesterification of Ethyl-10-undecenoate Using a Cu-Deposited V2O5 Catalyst as a Model Reaction for Efficient Conversion of Plant Oils to Monomers and Fine Chemicals
Swetha Sudhakaran, Ayako Taketoshi, S. M. A. Hakim Siddiki, Toru Murayama, Kotohiro Nomura
ACS Omega, 7, 5, 4372, 4380, American Chemical Society ({ACS}), 08 Feb. 2022, [International Magazine]
English, Scientific journal, Transesterification of ethyl-10-undecenoate (derived from castor oil) with 1,4-cyclohexanedimethanol over a recyclable Cu-deposited V2O5 catalyst afforded 1,ω-diene, the corresponding cyclohexane-1,4-diylbis(methylene) bis(undec-10-enoate), a promising monomer for the synthesis of biobased polyesters, in an efficient manner. Deposition of Cu plays an important role in proceeding the reaction with high selectivity, and both the activity and the selectivity are preserved for five recycled runs by the addition of the substrates. The present catalyst was effective for transesterification with other alcohols, especially primary alcohols, demonstrating a possibility of using this catalyst for efficient conversion of plant oil to various fine chemicals. - Praseodymia–titania mixed oxide supported gold as efficient water gas shift catalyst: modulated by the mixing ratio of oxides
Weixuan Zhao, Junjie Shi, Mingyue Lin, Libo Sun, Huijuan Su, Xun Sun, Toru Murayama, Caixia Qi
RSC Advances, 12, 9, 5374, 5385, 2022, [International Magazine]
English, Scientific journal, Modulating the active sites for controllable tuning of the catalytic activity has been the goal of much research, however, this remains challenging. The O vacancy is well known as an active site in reducible oxides. To modify the activity of O vacancies in praseodymia, we synthesized a series of praseodymia-titania mixed oxides. Varying the Pr : Ti mole ratio (2 : 1, 1 : 2, 1 : 1, 1 : 4) allows us to control the electronic interactions between Au, Pr and Ti cations and the local chemical environment of the O vacancies. These effects have been studied study by X-ray photoelectron spectroscopy (XPS), CO diffuse reflectance Fourier transform infrared spectroscopy (CO-DRIFTS) and temperature-programmed reduction (CO-TPR, H2-TPR). The water gas shift reaction (WGSR) was used as a benchmark reaction to test the catalytic performance of different praseodymia-titania supported Au. Among them, Au/Pr1Ti2O x was identified to exhibit the highest activity, with a CO conversion of 75% at 300 °C, which is about 3.7 times that of Au/TiO2 and Au/PrO x . The Au/Pr1Ti2O x also exhibited excellent stability, with the conversion after 40 h time-on-stream at 300 °C still being 67%. An optimal ratio of Pr content (Pr : Ti 1 : 2) is necessary for improving the surface oxygen mobility and oxygen exchange capability, a higher Pr content leads to more O vacancies, however with lower activity. This study presents a new route for modulating the active defect sites in mixed oxides which could also be extended to other heterogeneous catalysis systems. - Anti-inflammatory effect of gold nanoparticles supported on metal oxides
Takashi Fujita, Maeva Zysman, Dan Elgrabli, Toru Murayama, Masatake Haruta, Sophie Lanone, Tamao Ishida, Jorge Boczkowski
Scientific Reports, 11, 1, 23129, 23129, Springer Science and Business Media LLC, Dec. 2021, [International Magazine]
English, Scientific journal,Abstract Gold (Au) can be deposited as nanoparticles (NPs) smaller than 10 nm in diameter on a variety of metal oxide (MOx) NPs. Au/MOx have high catalytic performance and selective oxidation capacity which could have implications in terms of biological activity, and more specifically in modulation of the inflammatory reaction. Therefore, the aim of this study was to examine the effect of Au/TiO2, Au/ZrO2 and Au/CeO2 on viability, phagocytic capacity and inflammatory profile (TNF-α and IL-1β secretion) of murine macrophages. The most important result of this study is an anti-inflammatory effect of Au/MOx depending on the MOx nature with particle internalization and no alteration of cell viability and phagocytosis. The effect was dependent on the MOx NPs chemical nature (Au/TiO2 > Au/ZrO2 > Au/CeO2 if we consider the number of cytokines whose concentration was reduced by the NPs), and on the inflammatory mediator considered. The effect of Au/TiO2 NPs was not related to Au NPs size (at least in the case of Au/TiO2 NPs in the range of 3–8 nm). To the best of our knowledge, this is the first demonstration of an anti-inflammatory effect of Au/MOx. - Bulk tungsten-substituted vanadium oxide for low-temperature NOx removal in the presence of water
Yusuke Inomata, Hiroe Kubota, Shinichi Hata, Eiji Kiyonaga, Keiichiro Morita, Kazuhiro Yoshida, Norihito Sakaguchi, Takashi Toyao, Ken-ichi Shimizu, Satoshi Ishikawa, Wataru Ueda, Masatake Haruta, Toru Murayama
Nature Communications, 12, 1, 557, 557, Springer Science and Business Media LLC, Dec. 2021, [International Magazine]
English, Scientific journal - Synthesis of Zeolitic Ti, Zr-Substituted Vanadotungstates and Investigation of Their Catalytic Activities for Low Temperature NH
3 -SCR
Meilin Tao, Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Yusuke Inomata, Akiho Kamiyama, Ichika Nakaima, Yuan Jing, Shinya Mine, Kosuke Shimoda, Takashi Toyao, Ken Ichi Shimizu, Wataru Ueda
ACS Catalysis, 11, 22, 14016, 14025, American Chemical Society ({ACS}), 19 Nov. 2021
Scientific journal - Catalytic Activities of Various Niobium Oxides for Hydrogen Absorption/Desorption Reactions of Magnesium
Keita Shinzato, Hiroyuki Gi, Toru Murayama, Masahiro Sadakane, Yongming Wang, Shigehito Isobe, Takayuki Ichikawa, Hiroki Miyaoka
ACS Omega, 6, 36, 23564, 23569, American Chemical Society (ACS), 14 Sep. 2021, [International Magazine]
English, Scientific journal, Five types of niobium(V) oxides (Nb2O5) were synthesized by hydrothermal and heat treatment processes, and their structural properties and catalytic activities for the hydrogen absorption/desorption reactions of magnesium were characterized. The synthesized Nb oxides were dispersed on magnesium hydride (MgH2), a typical hydrogen storage material, using the ball-milling method. All the synthesized Nb oxides improved the reaction kinetics of the hydrogen desorption/absorption reactions. The catalytic activities for the hydrogen desorption were comparable, while the hydrogen absorption rates were significantly different for each synthesized Nb oxide. This difference can be explained by the structural stability of Nb2O5, which is related to the formation of a catalytically active state by the reduction of Nb2O5 during the ball-milling process. Notably, the highest catalytic effect was observed for Nb2O5 with a highly crystalline pyrochlore structure and a low specific surface area, suggesting that pyrochlore Nb2O5 is a metastable phase. However, only the amorphous Nb oxide was out of order, even though there is a report on the high catalytic activity of amorphous Nb oxide. This is attributed to the initial condensed state of amorphous Nb oxide, because particle size affects the dispersion state on the MgH2 surface, which is also important for obtaining high catalytic activity. Thus, it is concluded that Nb2O5 with lower stability of the crystal structure and smaller particle size shows better catalysis for both hydrogen desorption and absorption reactions. - Analogous Mechanistic Features of NH
3 -SCR over Vanadium Oxide and Copper Zeolite Catalysts
Hiroe Kubota, Takashi Toyao, Zen Maeno, Yusuke Inomata, Toru Murayama, Naoto Nakazawa, Satoshi Inagaki, Yoshihiro Kubota, Ken Ichi Shimizu
ACS Catalysis, 11, 17, 11180, 11192, American Chemical Society ({ACS}), 03 Sep. 2021
Scientific journal - Synthesis of bulk vanadium oxide with a large surface area using organic acids and its low-temperature NH3-SCR activity
Yusuke Inomata, Shinichi Hata, Eiji Kiyonaga, Keiichiro Morita, Kazuhiro Yoshida, Masatake Haruta, Toru Murayama
CATALYSIS TODAY, 376, 188, 196, Sep. 2021, [Peer-reviewed]
English, Scientific journal - Performance of Au/ZnO catalysts in CO2 reduction to methanol: Varying the Au loading / Au particle size
Shilong Chen, Ali M. Abdel-Mageed, Ashlee Hauble, Tamao Ishida, Toru Murayama, Magdalena Parlinska-Wojtan, R. Jürgen Behm
Applied Catalysis A: General, 624, Elsevier B.V., 25 Aug. 2021
English, Scientific journal - True Catalytically Active Structure in Mo-V-Based Mixed Oxide Catalysts for Selective Oxidation of Acrolein
Satoshi Ishikawa, Yudai Yamada, Naoki Kashio, Nagisa Noda, Kosuke Shimoda, Mio Hayashi, Toru Murayama, Wataru Ueda
ACS Catalysis, 11, 16, 10294, 10307, American Chemical Society, 20 Aug. 2021
English, Scientific journal - Controlling the O-Vacancy Formation and Performance of Au/ZnO Catalysts in CO2 Reduction to Methanol by the ZnO Particle Size
Shilong Chen, Ali M. Abdel-Mageed, Chihiro Mochizuki, Tamao Ishida, Toru Murayama, Jabor Rabeah, Magdalena Parlinska-Wojtan, Angelika Brückner, R. Jürgen Behm
ACS Catalysis, 11, 15, 9022, 9033, American Chemical Society (ACS), 06 Aug. 2021
Scientific journal - Selective catalytic oxidation of ammonia to nitrogen over zeolite-supported Pt-Au catalysts: Effects of alloy formation and acid sites
Haifeng Wang, Mingyue Lin, Toru Murayama, Shixiang Feng, Masatake Haruta, Hiroki Miura, Tetsuya Shishido
Journal of Catalysis, Elsevier BV, Aug. 2021
Scientific journal - Insights into Au Nanoparticle Size and Chemical State of Au/ZSM-5 Catalyst for Catalytic Cracking of n-Octane to Increase Propylene Production
Miao Zhang, Qi Liu, Houang Long, Libo Sun, Toru Murayama, Caixia Qi
Journal of Physical Chemistry C, 125, 29, 16013, 16023, American Chemical Society, 29 Jul. 2021
English, Scientific journal - Ag Size/Structure-Dependent Effect on Low-Temperature Selective Catalytic Oxidation of NH3 over Ag/MnO2
Haifeng Wang, Mingyue Lin, Toru Murayama, Shixiang Feng, Masatake Haruta, Hiroki Miura, Tetsuya Shishido
ACS Catalysis, 11, 14, 8576, 8584, American Chemical Society (ACS), 16 Jul. 2021
Scientific journal - Synthesis of Zeolitic Mo-Doped Vanadotungstates and Their Catalytic Activity for Low-Temperature NH3-SCR
Meilin Tao, Satoshi Ishikawa, Toru Murayama, Yusuke Inomata, Akiho Kamiyama, Wataru Ueda
INORGANIC CHEMISTRY, 60, 7, 5081, 5086, Apr. 2021, [International Magazine]
English, Scientific journal - Gold Nanoparticles Supported on Ce-Zr Oxides for Selective Hydrogenation of Acetylene
Xiaoyue Hua, Yuhua Zheng, Zixuan Yang, Libo Sun, Huijuan Su, Toru Murayama, Caixia Qi
TOPICS IN CATALYSIS, 64, 3-4, 206, 214, Mar. 2021
English, Scientific journal - High dimensionally structured W-V oxides as highly effective catalysts for selective oxidation of toluene
Toru Murayama, Satoshi Ishikawa, Norihito Hiyoshi, Yoshinori Goto, Zhenxin Zhang, Takashi Toyao, Ken-ichi Shimizu, Shutoku Lee, Wataru Ueda
CATALYSIS TODAY, 363, 60, 66, Mar. 2021
English, Scientific journal - Preparation of Polyaniline Microtubes as the Gold Catalyst Support with Improved Catalytic Performances for the Reduction of Nitrophenols
Libo Sun, Lin Jiang, Jie Zhang, Toru Murayama, Miao Zhang, Yuhua Zheng, Huijuan Su, Caixia Qi
TOPICS IN CATALYSIS, 64, 3-4, 215, 223, Mar. 2021
English, Scientific journal - C, N Co-Decorated Alumina-Supported Au Nanoparticles:Enhanced Catalytic Performance for Selective Hydrogenation of Acetylene
Yuan Zhang, Xun Sun, Yali Zhao, Huijuan Su, Toru Murayama, Caixia Qi
TOPICS IN CATALYSIS, 64, 3-4, 197, 205, Mar. 2021
English, Scientific journal - Influence of the support in aqueous phase oxidation of ethanol on gold/metal oxide catalysts studied by ATR-IR spectroscopy under working conditions
Ammara Waheed, Xianwei Wang, Nobutaka Maeda, Daniel M. Meier, Tamao Ishida, Toru Murayama, Masatake Haruta, Alfons Baiker
CATALYSIS COMMUNICATIONS, 148, Jan. 2021
English, Scientific journal - Features of Nb2O5 as a metal oxide support of Pt and Pd catalysts for selective catalytic oxidation of NH3 with high N-2 selectivity
Mingyue Lin, Baoxiang An, Takashi Takei, Tetsuya Shishido, Tamao Ishida, Masatake Haruta, Toru Murayama
JOURNAL OF CATALYSIS, 389, 366, 374, Sep. 2020
English, Scientific journal - Ligand effect of gold colloid in the preparation of Au/Nb2O5 for CO oxidation
Mingyue Lin, Chihiro Mochizuki, Baoxiang An, Tetsuo Honma, Masatake Haruta, Tamao Ishida, Toru Murayama
JOURNAL OF CATALYSIS, 389, 9, 18, Sep. 2020, [Peer-reviewed]
English, Scientific journal - Elucidation of Active Sites of Gold Nanoparticles on Acidic Ta2O5 Supports for CO Oxidation
Mingyue Lin, Chihiro Mochizuki, Baoxiang An, Yusuke Inomata, Tamao Ishida, Masatake Haruta, Toru Murayama
ACS CATALYSIS, 10, 16, 9328, 9335, Aug. 2020
English, Scientific journal - Gold Nanoparticles Supported on Nb2O5 for Low-Temperature CO Oxidation and as Cathode Materials for Li-ion Batteries
Luong Xuan Dien, Quang Duc Truong, Toru Murayama, Huynh Dang Chinh, Ayako Taketoshi, Itaru Honma, Masatake Haruta, Tamao Ishida
APPLIED CATALYSIS A-GENERAL, 603, 117747, 117747, Aug. 2020
English, Scientific journal - Low-Temperature Propylene Epoxidation Activity of CuO-CeO2 Catalyst with CO + O-2: Role of Metal-Support Interaction on the Reducibility and Catalytic Property of CuOx Species
Tinku Baidya, Tanmoy Mazumder, Konstantin Yu Koltunov, Pravin R. Likhar, Adam H. Clark, Khushubo Tiwari, Vladimir Sobolev, Soumitra Payra, Toru Murayama, Mingyue Lin, Parthasarathi Bera, Sounak Roy, Krishanu Biswas, Olga Safonova, Bolla Srinivasa Rao, Masatake Haruta
JOURNAL OF PHYSICAL CHEMISTRY C, 124, 26, 14131, 14146, Jul. 2020
English, Scientific journal - CO2 Reduction to Methanol on Au/CeO2 Catalysts: Mechanistic Insights from Activation/Deactivation and SSITKA Measurements
Azita Rezvani, Ali M. Abdel-Mageed, Tamao Ishida, Toru Murayama, Magdalena Parlinska-Wojtan, R. Juergen Behm
ACS CATALYSIS, 10, 6, 3580, 3594, Mar. 2020
English, Scientific journal - Importance of Size and Contact Structure of Gold Nanoparticles for the Genesis of Unique Catalytic Processes
Tamao Ishida, Toru Murayama, Ayako Taketoshi, Masatake Haruta
CHEMICAL REVIEWS, 120, 2, 464, 525, Jan. 2020, [International Magazine]
English, Scientific journal - Multi-dimensional Crystal Structuring of Complex Metal Oxide Catalysts of Group V and VI Elements by Unit-Assembling
Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Norihito Hiyoshi, Masahiro Sadakane, Wataru Ueda
TOPICS IN CATALYSIS, 62, 17-20, 1157, 1168, Nov. 2019, [Peer-reviewed]
English, Scientific journal - Effect of supported MAO cocatalysts in ethylene polymerization and ethylene/1-hexene copolymerization using Cp*TiCl
2 (O-2,6-iPr2 C6 H3 ) catalyst
Palawat Unruean, Wannida Apisuk, Youhei Kawabata, Toru Murayama, Boonyarach Kitiyanan, Kotohiro Nomura
Molecular Catalysis, 475, Oct. 2019
Scientific journal - Bulk Vanadium Oxide versus Conventional V2O5/TiO2: NH3-SCR Catalysts Working at a Low Temperature Below 150 degrees C
Yusuke Inomata, Shinichi Hata, Makoto Mino, Eiji Kiyonaga, Keiichiro Morita, Kenji Hikino, Kazuhiro Yoshida, Hiroe Kubota, Takashi Toyao, Ken-ichi Shimizu, Masatake Haruta, Toru Murayama
ACS CATALYSIS, 9, 10, 9327, 9331, Oct. 2019, [Peer-reviewed]
English, Scientific journal - Oxidative esterification of aliphatic aldehydes and alcohols with ethanol over gold nanoparticle catalysts in batch and continuous flow reactors
Ayako Taketoshi, Tamao Ishida, Toru Murayama, Tetsuo Honma, Masatake Haruta
Applied Catalysis A: General, 585, 117169, 117169, Elsevier BV, Sep. 2019
Scientific journal - CO Oxidation over Au/ZnO: Unprecedented Change of the Reaction Mechanism at Low Temperature Caused by a Different O-2 Activation Process
Takashi Fujita, Tamao Ishida, Kohei Shibamoto, Tetsuo Honma, Hironori Ohashi, Toru Murayama, Masatake Haruta
ACS CATALYSIS, 9, 9, 8364, 8372, Sep. 2019
English, Scientific journal - Influence of the structure of trigonal Mo-V-M3rd oxides (M3rd=-, Fe, Cu, W) on catalytic performances in selective oxidations of ethane, acrolein, and allyl alcohol
Satoshi Ishikawa, Toru Murayama, Benjamin Katryniok, Franck Dumeignil, Marcia Araque, Svetlana Heyte, Sebastien Paul, Yudai Yamada, Mizuki Iwazaki, Nagisa Noda, Wataru Ueda
APPLIED CATALYSIS A-GENERAL, 584, Aug. 2019
English, Scientific journal - Ultra-Low-Temperature CO Oxidation Activity of Octahedral Site Cobalt Species in Co3O4 Based Catalysts: Unravelling the Origin of the Unique Catalytic Property
Tinku Baidya, Toru Murayama, Subramanian Nellaiappan, Nirmal Kumar Katiyar, Parthasarathi Bera, Olga Safonova, Mingyue Lin, Kaustubh R. Priolkar, Samapti Kundu, Bolla Srinivasa Rao, Patrick Steiger, Sudhanshu Sharma, Krishanu Biswas, Swapan Kumar Pradhan, Nakka Lingaiah, Kirtiman Deo Malviya, Masatake Haruta
JOURNAL OF PHYSICAL CHEMISTRY C, 123, 32, 19557, 19571, Aug. 2019
English, Scientific journal - Redox-Active Zeolitic Transition Metal Oxides Based on epsilon-Keggin Units for Selective Oxidation
Zhenxin Zhang, Satoshi Ishikawa, Qianqian Zhu, Toru Murayama, Masahiro Sadakane, Michikazu Hara, Wataru Ueda
INORGANIC CHEMISTRY, 58, 9, 6283, 6293, May 2019, [Peer-reviewed], [International Magazine]
English, Scientific journal - New crystalline complex metal oxide catalysts with porous, acidic, and redox properties
Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Masahiro Sadakane, Wataru Ueda
Complex Oxides: An Introduction, 199, 222, World Scientific Publishing Co. Pte. Ltd., 20 Mar. 2019
English, In book - Role of the Acid Site for Selective Catalytic Oxidation of NH
3 over Au/Nb2 O5
Mingyue Lin, Baoxiang An, Nao Niimi, Yohei Jikihara, Tsuruo Nakayama, Tetsuo Honma, Takashi Takei, Tetsuya Shishido, Tamao Ishida, Masatake Haruta, Toru Murayama
ACS Catalysis, 9, 3, 1753, 1756, 01 Mar. 2019
Scientific journal - Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst
Yoshihiro Kon, Takuya Nakashima, Tadahiro Fujitani, Toru Murayama, Wataru Ueda
SYNLETT, 30, 3, 287, 292, Feb. 2019, [Peer-reviewed]
English, Scientific journal - Control of microporous property of W4V3O10 by an ion exchange and its catalytic activity for NH3-SCR
Kamiyama Akiho, Zhenxing Zhang, Ishikawa Satoshi, Inomata Yusuke, Murayama Toru, Ueda Wataru
Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2019, 0, 174, 174, The Japan Petroleum Institute, 2019, [Peer-reviewed]
Japanese,ミクロ細孔性W4V3O19複合酸化物(WVO)は、アンモニアを用いたSCRに対し高い触媒活性を示す。本研究では、WVOにTiやCuでイオン交換することでミクロ細孔容積が顕著に増大することを見出した。イオン交換後の試料は本反応に対し高い触媒活性、安定性を示した。発表ではイオン交換後試料の物性解析と触媒反応について、その詳細を述べる。
- NH3-SCR activity of bulk vanadium oxide catalysts containing tetravalent vanadium at a low temperature below 150oC
Inomata Yusuke, Kiyonaga Eiji, Morita Keiichiro, Yoshida Kazuhiro, Kubota Hiroe, Toyao Takashi, Shimizu Ken-ichi, Haruta Masatake, Murayama Toru
Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2019, 0, 175, 175, The Japan Petroleum Institute, 2019, [Peer-reviewed]
Japanese,Bulk vanadium oxide-based NH3-SCR catalysts were considered for denitration at a low temperature below 150oC. Vanadium oxalate as a precursor was calcined at 270oC for 1-4 h to synthesize vanadium oxide catalysts including tetravalent and pentavalent vanadium atoms. The NO conversions and reaction rates of these catalysts for NH3-SCR were greater than those of titania supported vanadium oxide catalysts and V2O5 catalyst that consist only of pentavalent vanadium. It was indicated that the existence of tetravalent vanadium leads to a decrease in the activation energy.
- Low-temperature NH3-SCR Activity of Nanoparticulate Gold Supported on a Metal Oxide
Yusuke Inomata, Makoto Mino, Shinichi Hata, Eiji Kiyonaga, Keiichiro Morita, Kenji Hikino, Kazuhiro Yoshida, Masatake Haruta, Toru Murayama
Journal of the Japan Petroleum Institute, 62, 5, 234, 243, 2019, [Peer-reviewed]
Scientific journal - Low-temperature NH3-SCR Activity of Nanoparticulate Gold Supported on a Metal Oxide
Yusuke Inomata, Makoto Mino, Shinichi Hata, Eiji Kiyonaga, Keiichiro Morita, Kenji Hikino, Kazuhiro Yoshida, Masatake Haruta, Toru Murayama
JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 62, 5, 234, 243, 2019, [Peer-reviewed]
English, Scientific journal - Control of catalytic nanoparticle synthesis: general discussion.
Adishev A, Arrigo R, Baletto F, Bordet A, Bukhtiyarov V, Carosso M, Catlow R, Conway M, Davies J, Davies P, De Masi D, Demirci C, Edwards JK, Friend C, Gallarati S, Hargreaves J, Huang H, Hutchings G, Lai S, Lamberti C, Macino M, Marchant D, Murayama T, Odarchenko Y, Peron J, Prati L, Quinson J, Richards N, Rogers S, Russell A, Selvam P, Shah P, Shozi M, Skylaris CK, Soulantica K, Spolaore F, Tooze B, Torrente-Murciano L, Trunschke A, Venezia B, Walker J, Whiston K
Faraday discussions, 208, 471, 495, Sep. 2018, [Peer-reviewed], [International Magazine]
English, Scientific journal - The challenges of characterising nanoparticulate catalysts: general discussion.
Arrigo R, Badmus K, Baletto F, Boeije M, Bowker M, Brinkert K, Bugaev A, Bukhtiyarov V, Carosso M, Catlow R, Chanerika R, Davies PR, Dononelli W, Freund HJ, Friend C, Gallarati S, Gates B, Genest A, Gibson EK, Hargreaves J, Helveg S, Huang H, Hutchings G, Irvine N, Johnston R, Lai S, Lamberti C, Macginley J, Marchant D, Murayama T, Nome R, Odarchenko Y, Quinson J, Rogers S, Russell A, Said S, Sermon P, Shah P, Simoncelli S, Soulantica K, Spolaore F, Tooze B, Torrente-Murciano L, Trunschke A, Willock D, Zhang J
Faraday discussions, 208, 339, 394, Sep. 2018, [Peer-reviewed], [International Magazine]
English, Scientific journal - A zeolitic vanadotungstate family with structural diversity and ultrahigh porosity for catalysis
Zhenxin Zhang, Qianqian Zhu, Masahiro Sadakane, Toru Murayama, Norihito Hiyoshi, Akira Yamamoto, Shinichi Hata, Hisao Yoshida, Satoshi Ishikawa, Michikazu Hara, Wataru Ueda
NATURE COMMUNICATIONS, 9, 1, 3789, 3789, Sep. 2018, [Peer-reviewed], [International Magazine]
English, Scientific journal - Control of catalytic nanoparticle synthesis: general discussion
Aldiar Adishev, Rosa Arrigo, Francesca Baletto, Alexis Bordet, Valerii Bukhtiyarov, Michele Carosso, Richard Catlow, Matthew Conway, Josh Davies, Philip Davies, Deborah De Masi, Cansunur Demirci, Jennifer K. Edwards, Cynthia Friend, Simone Gallarati, Justin Hargreaves, Haoliang Huang, Graham Hutchings, Stanley Lai, Carlo Lamberti, Margherita Macino, David Marchant, Toru Murayama, Yaroslav Odarchenko, Jennifer Peron, Laura Prati, Jonathan Quinson, Nia Richards, Scott Rogers, Andrea Russell, Parasuraman Selvam, Parag Shah, Mzamo Shozi, Chris-Kriton Skylaris, Katerina Soulantica, Federico Spolaore, Bob Tooze, Laura Torrente-Murciano, Annette Trunschke, Baldassarre Venezia, James Walker, Keith Whiston
FARADAY DISCUSSIONS, 208, 471, 495, Aug. 2018, [Peer-reviewed]
English - The challenges of characterising nanoparticulate catalysts: general discussion
Rosa Arrigo, Kassim Badmus, Francesca Baletto, Maurits Boeije, Michael Bowker, Katharina Brinkert, Aram Bugaev, Valerii Bukhtiyarov, Michele Carosso, Richard Catlow, Revana Chanerika, Philip R. Davies, Wilke Dononelli, Hans-Joachim Freund, Cynthia Friend, Simone Gallarati, Bruce Gates, Alexander Genest, Emma K. Gibson, Justin Hargreaves, Stig Helveg, Haoliang Huang, Graham Hutchings, Nicola Irvine, Roy Johnston, Stanley Lai, Carlo Lamberti, Joseph Macginley, David Marchant, Toru Murayama, Rene Nome, Yaroslav Odarchenko, Jonathan Quinson, Scott Rogers, Andrea Russell, Said Said, Paul Sermon, Parag Shah, Sabrina Simoncelli, Katerina Soulantica, Federico Spolaore, Bob Tooze, Laura Torrente-Murciano, Annette Trunschke, David Willock, Jiaguang Zhang
FARADAY DISCUSSIONS, 208, 339, 394, Aug. 2018, [Peer-reviewed]
English - W-Ti-O Mixed Metal Oxide Catalyzed Dehydrative Cross-etherification of Alcohols
Akira Yada, Toru Murayama, Jun Hirata, Takuya Nakashima, Masanori Tamura, Yoshihiro Kon, Wataru Ueda
CHEMISTRY LETTERS, 47, 4, 447, 449, Apr. 2018, [Peer-reviewed]
English, Scientific journal - Carbon Monoxide Oxidation by Polyoxometalate-Supported Gold Nanoparticulate Catalysts: Activity, Stability, and Temperature- Dependent Activation Properties
Takuya Yoshida, Toru Murayama, Norihito Sakaguchi, Mitsutaka Okumura, Tamao Ishida, Masatake Haruta
Angewandte Chemie, 57, 6, 1523, 1527, Wiley-Blackwell, 05 Feb. 2018, [Peer-reviewed]
English, Scientific journal - Carbon Monoxide Oxidation by Polyoxometalate-Supported Gold Nanoparticulate Catalysts: Activity, Stability, and Temperature-Dependent Activation Properties
Takuya Yoshida, Toru Murayama, Norihito Sakaguchi, Mitsutaka Okumura, Tamao Ishida, Masatake Haruta
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 57, 6, 1523, 1527, Feb. 2018, [Peer-reviewed], [International Magazine]
English, Scientific journal - V2O5 catalyst for low temperature NH3-SCR of NOx
Inomata Yusuke, Hata Shinichi, Kiyonaga Eiji, Morita Keiichiro, Yoshida Kazuhiro, Haruta Masatake, Murayama Toru
Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2018, 0, 184, 184, The Japan Petroleum Institute, 2018, [Peer-reviewed]
Japanese, NH3を還元剤とする選択的触媒還元法(NH3-SCR)は、NOxを無害化する方法として知られている。現在使用されている触媒の動作温度は高く、低温でも作用する脱硝プロセスの設計が望まれている。本研究では、酸化バナジウム触媒を調製し、低温条件下における触媒活性を調べた。その結果、150℃で90%以上の高いNO転化率を示した。 - Identification of the catalytically active component of Cu-Zr-O catalyst for the hydrogenation of levulinic acid to gamma-valerolactone
Satoshi Ishikawa, Daniel R. Jones, Sarwat Iqbal, Christian Reece, David J. Morgan, David J. Willock, Peter J. Miedziak, Jonathan K. Bartley, Jennifer K. Edwards, Toru Murayama, Wataru Ueda, Graham J. Hutchings
GREEN CHEMISTRY, 19, 1, 225, 236, Jan. 2017, [Peer-reviewed]
English, Scientific journal - Hydrothermal synthesis of a layered-type W-Ti-O mixed metal oxide and its solid acid activity
Toru Murayama, Kiyotaka Nakajima, Jun Hirata, Kaori Omata, Emiel J. M. Hensen, Wataru Ueda
CATALYSIS SCIENCE & TECHNOLOGY, 7, 1, 243, 250, Jan. 2017, [Peer-reviewed]
English, Scientific journal - NH3-efficient ammoxidation of toluene by hydrothermally synthesized layered tungsten-vanadium complex metal oxides
Yoshinori Goto, Ken-ichi Shimizu, Kenichi Kon, Takashi Toyao, Toru Murayama, Wataru Ueda
JOURNAL OF CATALYSIS, 344, 346, 353, Dec. 2016, [Peer-reviewed]
English, Scientific journal - Correlation between catalytic activity of supported gold catalysts for carbon monoxide oxidation and metal-oxygen binding energy of the support metal oxides
Takashi Fujita, Masanori Horikawa, Takashi Takei, Toru Murayama, Masatake Haruta
CHINESE JOURNAL OF CATALYSIS, 37, 10, 1651, 1655, Oct. 2016, [Peer-reviewed]
English, Scientific journal - Correlation between catalytic activity of supported gold catalysts for carbon monoxide oxidation and metal-oxygen binding energy of the support metal oxides
Takashi Fujita, Masanori Horikawa, Takashi Takei, Toru Murayama, Masatake Haruta
CHINESE JOURNAL OF CATALYSIS, 37, 10, 1651, 1655, Oct. 2016, [Peer-reviewed]
English, Scientific journal - Synthesis of Trigonal Mo-V-M(3)rd-O (M(3)rd = Fe, W) Catalysts by Using Structure-Directing Agent and Catalytic Performances for Selective Oxidation of Ethane
Satoshi Ishikawa, Toru Murayama, Masahiro Kumaki, Masaya Tashiro, Zhenxin Zhang, Akihiro Yoshida, Wataru Ueda
TOPICS IN CATALYSIS, 59, 17-18, 1477, 1488, Oct. 2016, [Peer-reviewed]
English, Scientific journal - Preparation of gold nanoparticles supported on Nb2O5 by deposition precipitation and deposition reduction methods and their catalytic activity for CO oxidation
Toru Murayama, Masatake Haruta
CHINESE JOURNAL OF CATALYSIS, 37, 10, 1694, 1701, Oct. 2016, [Peer-reviewed]
English, Scientific journal - Deposition of Gold Nanoparticles on Niobium Pentoxide with Different Crystal Structures for Room-Temperature Carbon Monoxide Oxidation
Toru Murayama, Wataru Ueda, Masatake Haruta
CHEMCATCHEM, 8, 16, 2620, 2624, Aug. 2016, [Peer-reviewed]
English, Scientific journal - Role of Crystalline Structure in Allyl Alcohol Selective Oxidation over Mo3VOx Complex Metal Oxide Catalysts
Toru Murayama, Benjamin Katryniok, Svetlana Heyte, Marcia Araque, Satoshi Ishikawa, Franck Dumeignil, Sebastien Paul, Wataru Ueda
CHEMCATCHEM, 8, 14, 2415, 2420, Jul. 2016, [Peer-reviewed]
English, Scientific journal - Hydrothermal synthesis of W-Ta-O complex metal oxides by assembling MO6 (M = W or Ta) octahedra and creation of solid acid
Toru Murayama, Nozomi Kuramata, Wataru Ueda
JOURNAL OF CATALYSIS, 339, 143, 152, Jul. 2016, [Peer-reviewed]
English, Scientific journal - ChemInform Abstract: Synthesis of Vanadium-Incorporated, Polyoxometalate-Based Open Frameworks and Their Applications for Cathode-Active Materials.
Zhenxin Zhang, Hirofumi Yoshikawa, Zhongyue Zhang, Toru Murayama, Masahiro Sadakane, Yasunori Inoue, Wataru Ueda, Kunio Awaga, Michikazu Hara
ChemInform, 47, 21, Wiley-Blackwell, May 2016, [Peer-reviewed]
Scientific journal - Synthesis of Vanadium-Incorporated, Polyoxometalate-Based Open Frameworks and Their Applications for Cathode-Active Materials
Zhenxin Zhang, Hirofumi Yoshikawa, Zhongyue Zhang, Toru Murayama, Masahiro Sadakane, Yasunori Inoue, Wataru Ueda, Kunio Awaga, Michikazu Hara
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 8, 1242, 1250, Mar. 2016, [Peer-reviewed]
English, Scientific journal - Hydrothermal synthesis of microporous W-V-O as an efficient catalyst for ammoxidation of 3-picoline
Yoshinori Goto, Ken-ichi Shimizu, Toru Murayama, Wataru Ueda
APPLIED CATALYSIS A-GENERAL, 509, 118, 122, Jan. 2016, [Peer-reviewed]
English, Scientific journal - Direct oxidative transformation of glycerol to acrylic acid over Nb-based complex metal oxide catalysts
Kaori Omata, Keeko Matsumoto, Toru Murayama, Wataru Ueda
CATALYSIS TODAY, 259, 205, 212, Jan. 2016, [Peer-reviewed]
English, Scientific journal - New crystalline complex metal oxides created by unit-synthesis and their catalysis based on porous and redox properties
Zhenxin Zhang, Satoshi Ishikawa, Yuta Tsuboi, Masahiro Sadakane, Toru Murayama, Wataru Ueda
FARADAY DISCUSSIONS, 188, 81, 98, 2016, [Peer-reviewed], [International Magazine]
English, Scientific journal - Ultrathin inorganic molecular nanowire based on polyoxometalates
Zhenxin Zhang, Toru Murayama, Masahiro Sadakane, Hiroko Ariga, Nobuhiro Yasuda, Norihito Sakaguchi, Kiyotaka Asakura, Wataru Ueda
NATURE COMMUNICATIONS, 6, 7731, 7731, Jul. 2015, [Peer-reviewed], [International Magazine]
English, Scientific journal - Redox Treatment of Orthorhombic Mo29V11O112 and Relationships between Crystal Structure, Microporosity and Catalytic Performance for Selective Oxidation of Ethane
Satoshi Ishikawa, Daichi Kobayashi, Takeshi Konya, Shunpei Ohmura, Toru Murayama, Nobuhiro Yasuda, Masahiro Sadakane, Wataru Ueda
JOURNAL OF PHYSICAL CHEMISTRY C, 119, 13, 7195, 7206, Apr. 2015, [Peer-reviewed]
English, Scientific journal - Synthesis of crystalline Mo–V–W–O complex oxides with orthorhombic and trigonal structures and their application as catalysts
Chuntian Qiu, Chen Chen, Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Wataru Ueda
Catalysis, Structure & Reactivity, 1, 2, 71, 77, Informa {UK} Limited, 08 Jan. 2015, [Peer-reviewed]
Scientific journal - Synthesis of crystalline Mo-V-W-O complex oxides with orthorhombic and trigonal structures and their application as catalysts
Chuntian Qiu, Chen Chen, Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Wataru Ueda
CATALYSIS STRUCTURE & REACTIVITY, 1, 2, 71, 77, 2015, [Peer-reviewed]
English, Scientific journal - Selective carbon dioxide adsorption of epsilon-Keggin-type zincomolybdate-based purely inorganic 3D frameworks
Zhenxin Zhang, Masahiro Sadakane, Shin-ichiro Noro, Toru Murayama, Takashi Kamachi, Kazunari Yoshizawa, Wataru Ueda
JOURNAL OF MATERIALS CHEMISTRY A, 3, 2, 746, 755, 2015, [Peer-reviewed]
English, Scientific journal - Catalysis field in orthorhombic Mo3VOx oxide catalyst for the selective oxidation of ethane, propane and acrolein
Satoshi Ishikawa, Xiaodong Yi, Toru Murayama, Wataru Ueda
CATALYSIS TODAY, 238, 35, 40, Dec. 2014, [Peer-reviewed]
English, Scientific journal - Hydrogen-transfer dehydration between alcohols over V2O3 and MoO2 catalysts for the formation of corresponding alkanes and aldehydes
Yoichi Nakamura, Toru Murayama, Wataru Ueda
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 394, 137, 144, Nov. 2014, [Peer-reviewed]
English, Scientific journal - ChemInform Abstract: Preparation, Structural Characterization, and Ion-Exchange Properties of Two New Zeolite-like 3D Frameworks Constructed by ε-Keggin-Type Polyoxometalates with Binding Metal Ions, H11.4 [ZnMo12O40Zn2]1.5- and H7.5 [Mn0.2Mo12O40Mn2] 2.1
Zhenxin Zhang, Masahiro Sadakane, Toru Murayama, Norihito Sakaguchi, Wataru Ueda
ChemInform, 45, 39, no, no, Wiley-Blackwell, 11 Sep. 2014, [Peer-reviewed]
English, Scientific journal - Investigation of the formation process of zeolite-like 3D frameworks constructed with epsilon-Keggin-type polyoxovanadomolybdates with binding bismuth ions and preparation of a nano-crystal
Zhenxin Zhang, Masahiro Sadakane, Toru Murayama, Wataru Ueda
DALTON TRANSACTIONS, 43, 36, 13584, 13590, Sep. 2014, [Peer-reviewed], [International Magazine]
English, Scientific journal - Crystalline Mo-V-W-mixed Oxide with Orthorhombic and Trigonal Structures as Highly Efficient Oxidation Catalysts of Acrolein to Acrylic Acid
Chuntian Qiu, Chen Chen, Satoshi Ishikawa, Toru Murayama, Wataru Ueda
TOPICS IN CATALYSIS, 57, 14-16, 1163, 1170, Sep. 2014, [Peer-reviewed]
English, Scientific journal - Seed-Assisted Synthesis of Crystalline Mo3VOx Oxides and Their Crystal Formation Mechanism
Satoshi Ishikawa, Masaya Tashiro, Toru Murayama, Wataru Ueda
CRYSTAL GROWTH & DESIGN, 14, 9, 4553, 4561, Sep. 2014, [Peer-reviewed]
English, Scientific journal - Preparation, Structural Characterization, and Ion-Exchange Properties of Two New Zeolite-like 3D Frameworks Constructed by epsilon-Keggin-Type Polyoxometalates with Binding Metal Ions, H-11.4[ZnMo12O40Zn2](1.5-) and H-7.5[Mn0.2Mo12O40Mn2](2.1-)
Zhenxin Zhang, Masahiro Sadakane, Toru Murayama, Norihito Sakaguchi, Wataru Ueda
INORGANIC CHEMISTRY, 53, 14, 7309, 7318, Jul. 2014, [Peer-reviewed], [International Magazine]
English, Scientific journal - Investigation of the formation process of zeolite-like 3D frameworks constructed with ε-Keggin-type polyoxovanadomolybdates with binding bismuth ions and preparation of a nano-crystal
Zhenxin Zhang, Masahiro Sadakane, Toru Murayama, Wataru Ueda
Dalton Trans., 43, 36, 13584, 13584, Jul. 2014, [Peer-reviewed]
English, Scientific journal - Direct Oxidative Transformation of Glycerol into Acrylic Acid over Phosphoric Acid-added W-V-Nb Complex Metal Oxide Catalysts
Kaori Omata, Keeko Matsumoto, Toru Murayama, Wataru Ueda
CHEMISTRY LETTERS, 43, 4, 435, 437, Apr. 2014, [Peer-reviewed]
English, Scientific journal - Reduced Vanadium and Molybdenum Oxides Catalyze the Equivalent Formation of Ethane and Acetaldehyde from Ethanol
Yoichi Nakamura, Toru Murayama, Wataru Ueda
CHEMCATCHEM, 6, 3, 741, 744, Mar. 2014, [Peer-reviewed]
English, Scientific journal - Heptagonal channel micropore of orthorhombic Mo3VOx as catalysis field for the selective oxidation of ethane
Satoshi Ishikawa, Xiaodong Yi, Toru Murayama, Wataru Ueda
APPLIED CATALYSIS A-GENERAL, 474, 10, 17, Mar. 2014, [Peer-reviewed]
English, Scientific journal - ChemInform Abstract: Tetrahedral Connection of ε-Keggin-Type Polyoxometalates to Form an All-Inorganic Octahedral Molecular Sieve with an Intrinsic 3D Pore System.
Zhenxin Zhang, Masahiro Sadakane, Toru Murayama, Shoko Izumi, Nobuhiro Yasuda, Norihito Sakaguchi, Wataru Ueda
ChemInform, 45, 13, no, no, Wiley-Blackwell, Mar. 2014, [Peer-reviewed]
Scientific journal - Tetrahedral Connection of epsilon-Keggin-type Polyoxometalates To Form an All-Inorganic Octahedral Molecular Sieve with an Intrinsic 3D Pore System
Zhenxin Zhang, Masahiro Sadakane, Toru Murayama, Shoko Izumi, Nobuhiro Yasuda, Norihito Sakaguchi, Wataru Ueda
INORGANIC CHEMISTRY, 53, 2, 903, 911, Jan. 2014, [Peer-reviewed], [International Magazine]
English, Scientific journal - Hydrothermal synthesis of octahedra-based layered niobium oxide and its catalytic activity as a solid acid
Toru Murayama, Junli Chen, Jun Hirata, Keeko Matsumoto, Wataru Ueda
CATALYSIS SCIENCE & TECHNOLOGY, 4, 12, 4250, 4257, 2014, [Peer-reviewed]
English, Scientific journal - Single-Crystalline-Phase Mo3VOx: An Efficient Catalyst for the Partial Oxidation of Acrolein to Acrylic Acid
Chen Chen, Nakatani Kosuke, Toru Murayama, Wataru Ueda
CHEMCATCHEM, 5, 10, 2869, 2873, Oct. 2013, [Peer-reviewed]
English, Scientific journal - Electrocatalysis of heat-treated cobalt-porphyrin/carbon for hydrogen peroxide formation
Ichiro Yamanaka, Ryo Ichihashi, Tatsuya Iwasaki, Naoya Nishimura, Toru Murayama, Wataru Ueda, Sakae Takenaka
ELECTROCHIMICA ACTA, 108, 321, 329, Oct. 2013, [Peer-reviewed]
English, Scientific journal - ChemInform Abstract: Synthesis of Novel Orthorhombic Mo and V Based Complex Oxides Coordinating Alkylammonium Cation in Its Heptagonal Channel and Their Application as a Catalyst.
Satoshi Ishikawa, Toru Murayama, Shunpei Ohmura, Masahiro Sadakane, Wataru Ueda
ChemInform, 44, 34, no, no, Wiley-Blackwell, 01 Aug. 2013, [Peer-reviewed]
Scientific journal - Synthesis of Novel Orthorhombic Mo and V Based Complex Oxides Coordinating Alkylammonium Cation in Its Heptagonal Channel and Their Application as a Catalyst
Satoshi Ishikawa, Toru Murayama, Shunpei Ohmura, Masahiro Sadakane, Wataru Ueda
CHEMISTRY OF MATERIALS, 25, 11, 2211, 2219, Jun. 2013, [Peer-reviewed]
English, Scientific journal - Assembly of a Pentagonal Polyoxomolybdate Building Block, [Mo6O21](6-), into Crystalline MoV Oxides
Masahiro Sadakane, Keisuke Endo, Katsunori Kodato, Satoshi Ishikawa, Toru Murayama, Wataru Ueda
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 10-11, 1731, 1736, Apr. 2013, [Peer-reviewed]
English, Scientific journal - Hydrothermal synthesis of W-Nb complex metal oxides and their application to catalytic dehydration of glycerol to acrolein
Kaori Omata, Shoko Izumi, Toru Murayama, Wataru Ueda
CATALYSIS TODAY, 201, 7, 11, Mar. 2013, [Peer-reviewed]
English, Scientific journal - Quantitative Analysis of Coke Formation during Steam Reforming of Methane on a Nickel-Hydrotalcite Catalyst under Practical Operation Conditions
Tatsuya Takeguchi, Hiroshi Watanabe, Toru Murayama, Hiroki Takahashi, Wataru Ueda
CHEMISTRY LETTERS, 42, 2, 124, 126, Feb. 2013, [Peer-reviewed]
English, Scientific journal - An orthorhombic Mo3VOx catalyst most active for oxidative dehydrogenation of ethane among related complex metal oxides
Takeshi Konya, Tomokazu Katou, Toru Murayama, Satoshi Ishikawa, Masahiro Sadakane, Douglas Buttrey, Wataru Ueda
CATALYSIS SCIENCE & TECHNOLOGY, 3, 2, 380, 387, 2013, [Peer-reviewed]
English, Scientific journal - Morphology-controlled preparation of iron-based oxides using a paper template
Masahiro Sadakane, Rika Kato, Toru Murayama, Wataru Ueda
MATERIALS LETTERS, 81, 80, 83, Aug. 2012, [Peer-reviewed]
English, Scientific journal - Synthesis of porous and acidic complex metal oxide catalyst based on group 5 and 6 elements
Toru Murayama, Nozomi Kuramata, Shunsuke Takatama, Kosuke Nakatani, Shoko Izumi, Xiaodong Yi, Wataru Ueda
CATALYSIS TODAY, 185, 1, 224, 229, May 2012, [Peer-reviewed]
English, Scientific journal - Phosgene-Free Method for Diphenyl Carbonate Synthesis at the Pd 0 /Ketjenblack Anode
Toru Murayama, Tomohiko Hayashi, Ryoichi Kanega, Ichiro Yamanaka
J. Phys. Chem. C, 116, 19, 10607, 10616, May 2012, [Peer-reviewed]
English, Scientific journal - Motion Planning of Networked Multi-Vehicle System with Hybrid Measurement Model
Toru Murayama, Akinori Nagano, Kenneth Ho, Zhi-Wei Luo
2012 8TH INTERNATIONAL CONFERENCE ON COMPUTING AND NETWORKING TECHNOLOGY (ICCNT, INC, ICCIS AND ICMIC), 207, 212, 2012
English, International conference proceedings - Preparation and formation mechanism of three-dimensionally ordered macroporous (3DOM) MgO, MgSO4, CaCO3, and SrCO3, and photonic stop band properties of 3DOM CaCO3
Masahiro Sadakane, Rika Kato, Toru Murayama, Wataru Ueda
JOURNAL OF SOLID STATE CHEMISTRY, 184, 8, 2299, 2305, Aug. 2011, [Peer-reviewed]
English, Scientific journal - Catalytic neutral hydrogen peroxide synthesis from O-2 and H-2 by PEMFC fuel
Toru Murayama, Satoshi Tazawa, Sakae Takenaka, Ichiro Yamanaka
CATALYSIS TODAY, 164, 1, 163, 168, Apr. 2011, [Peer-reviewed]
English, Scientific journal - Electrosynthesis of Neutral H2O2 Solution from O-2 and Water at a Mixed Carbon Cathode Using an Exposed Solid-Polymer-Electrolyte Electrolysis Cell
Toru Murayama, Ichiro Yamanaka
JOURNAL OF PHYSICAL CHEMISTRY C, 115, 13, 5792, 5799, Apr. 2011, [Peer-reviewed]
English, Scientific journal - Catalytic synthesis of neutral H2O2 solution by a fuel cell with a CoN2Cx/carbon cathode
Ichiro Yamanaka, Satoshi Tazawa, Toru Murayama
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 241, Mar. 2011, [Peer-reviewed]
English - Direct synthesis of diphenyl carbonate by mediated electrocarbonylation of phenol at Pd2+-supported activated carbon anode
Toru Murayama, Tomohiko Hayashi, Yuji Arai, Ichiro Yamanaka
ELECTROCHIMICA ACTA, 56, 7, 2926, 2933, Feb. 2011, [Peer-reviewed]
English, Scientific journal - A Fuel-Cell Reactor for the Direct Synthesis of Hydrogen Peroxide Alkaline Solutions from H-2 and O-2
Ichiro Yamanaka, Takeshi Onisawa, Toshikazu Hashimoto, Toru Murayama
CHEMSUSCHEM, 4, 4, 494, 501, 2011, [Peer-reviewed], [International Magazine]
English, Scientific journal - Redox tunable reversible molecular sieves: orthorhombic molybdenum vanadium oxide
Masahiro Sadakane, Shunpei Ohmura, Katsunori Kodato, Takumi Fujisawa, Kazuo Kato, Ken-ichi Shimidzu, Toru Murayama, Wataru Ueda
CHEMICAL COMMUNICATIONS, 47, 38, 10812, 10814, 2011, [Peer-reviewed], [International Magazine]
English, Scientific journal - Direct Synthesis of Diphenyl Carbonate by Electrocarbonylation at a Pd2+-supported Anode
Toru Murayama, Yuji Arai, Tomohiko Hayashi, Ichiro Yamanaka
CHEMISTRY LETTERS, 39, 4, 418, 419, Apr. 2010, [Peer-reviewed]
English, Scientific journal - Neutral H2O2 Synthesis by Electrolysis of O-2 and Water
T. Murayama, I. Yamanaka
SYNTHETIC AND MECHANISTIC ORGANIC ELECTRON TRANSFER REACTIONS, 25, 18, 19, 24, 2010, [Peer-reviewed]
English, International conference proceedings - Study of the Electrochemical Carbonylation of Ethanol and Ethylene at Pd/C Anode
A. Funakawa, T. Murayama, I. Yamanaka
SYNTHETIC AND MECHANISTIC ORGANIC ELECTRON TRANSFER REACTIONS, 25, 18, 35, 40, 2010, [Peer-reviewed]
English, International conference proceedings - Catalytic Synthesis of Neutral Hydrogen Peroxide at a CoN2Cx Cathode of a Polymer Electrolyte Membrane Fuel Cell (PEMFC)
Ichiro Yamanaka, Satoshi Tazawa, Toru Murayama, Tatsuya Iwasaki, Sakae Takenaka
CHEMSUSCHEM, 3, 1, 59, 62, 2010, [Peer-reviewed], [International Magazine]
English, Scientific journal - Neutral H2O2 Synthesis by Electrolysis of O-2 and Water
T. Murayama, I. Yamanaka
SYNTHETIC AND MECHANISTIC ORGANIC ELECTRON TRANSFER REACTIONS, 25, 18, 19, 24, 2010, [Peer-reviewed]
English, International conference proceedings - Neutral H2O2 synthesis by electrolysis of water and O-2
Ichiro Yamanaka, Toru Murayama
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 47, 10, 1900, 1902, 2008, [Peer-reviewed], [International Magazine]
English, Scientific journal - Catalytic Synthesis of Neutral H2O2 Solutions from O-2 and H-2 by a Fuel Cell Reaction
Ichiro Yamanaka, Satoshi Tazawa, Toru Murayama, Ryo Ichihashi, Noriko Hanaizumi
CHEMSUSCHEM, 1, 12, 988, 992, 2008, [Peer-reviewed], [International Magazine]
English, Scientific journal
Other Activities and Achievements
- ポリオキソメタレート上に担持した金ナノ粒子触媒によるCO酸化反応に関する理論的研究
米森朋久, 村山徹, 川上貴資, 山中秀介, 奥村光隆, 触媒討論会予稿集(CD-ROM), 134th, 2024 - コロイド固定化法により調製した担持Au触媒を用いたバイオマス由来フラン化合物の酸化的エステル化反応
新井直, SHEET Nirupama, 大須賀遼太, 菅沼学史, 村山徹, 中島清隆, 触媒討論会予稿集(CD-ROM), 134th, 2024 - Cu-Au/ZrO2触媒による二酸化炭素水素化
野本賢俊, 丁渤桓, 王海峰, 村山徹, 石田玉青, 石田玉青, 三浦大樹, 三浦大樹, 宍戸哲也, 宍戸哲也, 触媒討論会予稿集(CD-ROM), 134th, 2024 - Ni-Ti層状複水酸化物(LDH)を利用した担持金触媒によるCO-PROX反応
中山晶皓, 坂口紀史, 村山徹, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会予稿集(CD-ROM), 134th, 2024 - 担持金触媒を用いた芳香族化合物のC-H官能基化反応
荒田晃生, 中山晶皓, 村山徹, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会予稿集(CD-ROM), 134th, 2024 - 金ナノ粒子担持ポリオキソメタレート触媒による低温CO酸化反応における水分子の影響に関する理論的研究
米森朋久, 村山徹, 川上貴資, 山中秀介, 奥村光隆, 触媒討論会予稿集(CD-ROM), 133rd, 2024 - ポリオキソメタレート上に担持した金ナノ粒子触媒によるCO酸化に関する理論研究
米森朋久, 村山徹, 奥村光隆, 触媒討論会予稿集(CD-ROM), 131st, 2023 - Theoretical study on the formation of active oxygen by porous polyoxometalate-supported metal catalysts
米森朋久, 村山徹, 川上貴資, 山中秀介, 奥村光隆, 分子科学討論会講演プログラム&要旨(Web), 17th, 2023 - Ni-Ti層状複水酸化物から変換した複合酸化物を用いた担持金クラスター触媒のCO酸化活性評価
高橋あゆ, 中山晶皓, 村山徹, 坂口紀人, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会予稿集(CD-ROM), 131st, 2023 - ナノ粒子状の層状複水酸化物(LDH)を利用した担持金クラスター触媒の開発
中山晶皓, 吉田彩乃, 青野智香, 本間徹生, 坂口紀史, 竹歳絢子, 藤田隆史, 村山徹, 村山徹, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会予稿集(CD-ROM), 131st, 2023 - Development of supported nickel oxide catalysts for Markovnikov-selective hydroboration of styrenes
竹歳絢子, 平野英司, 木村友星, 村山徹, 村山徹, 山口佳隆, 日本プロセス化学会サマーシンポジウム講演要旨集(Web), 2023, 2023 - 層状複水酸化物を変換したNi-Ti複合金属酸化物担持金触媒を用いたCO-PROX反応
高橋あゆ, 中山晶皓, 村山徹, 坂口紀史, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会予稿集(CD-ROM), 132nd, 2023 - 微小な層状複水酸化物(LDH)を利用した担持金クラスター触媒によるCO-PROX反応
中山晶皓, 吉田彩乃, 本間徹生, 坂口紀史, 村山徹, 村山徹, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会予稿集(CD-ROM), 132nd, 2023 - 担持酸化ニッケル触媒を用いたスチレン類のマルコフニコフ選択的ヒドロホウ素化反応
竹歳絢子, 平野英司, 木村友星, 村山徹, 村山徹, 山口佳隆, 触媒討論会予稿集(CD-ROM), 132nd, 2023 - 担持Au触媒を用いた5-ホルミル-2-フランカルボン酸メチルの酸化的エステル化
新井直, SHEET Nirupama, 大須賀遼太, 菅沼学史, 村山徹, 中島清隆, 触媒討論会予稿集(CD-ROM), 132nd, 2023 - Au/ZrO2触媒によるフタル酸ジメチルの酸化的C-Hカップリング反応
荒田晃生, 中山晶皓, 村山徹, 村山徹, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会予稿集(CD-ROM), 132nd, 2023 - Development of Solid Acid-supported Gold Nanoparticle Catalysts for Air Purification at Room Temperature
村山徹, 村山徹, LIN Mingyue, LIN Mingyue, LIN Mingyue, Journal of the Japan Petroleum Institute (Web), 65, 2, 2022 - 金属-有機構造体で被覆したAu/TiO2触媒によるアルコール酸化
門脇伸太朗, 中山晶皓, 村山徹, 高木慎介, 嶋田哲也, 石田玉青, 触媒討論会講演予稿集(CD-ROM), 129th, 2022 - 層状複水酸化物(LDH)を用いたAu/SiO2表面への新たなCO酸化活性界面の形成
岡山夏帆, 中山晶皓, 村山徹, 坂口紀史, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会講演予稿集(CD-ROM), 129th, 2022 - ハイドロキシアパタイト担持貴金属触媒における強い金属-担体相互作用(SMSI)の効果
中山晶皓, 袖永竜生, GANGARAJULA Yuvaraj, 竹歳絢子, 村山徹, 村山徹, 本間徹生, 坂口紀史, 嶋田哲也, 高木慎介, 春田正毅, QIAO Botao, WANG Junhu, 石田玉青, 触媒討論会講演予稿集(CD-ROM), 129th, 2022 - Development of gold nanoparticle composite catalysts supported on metal oxides using layered double hydroxide (LDH) nanoparticles
吉田彩乃, 岡山夏帆, 中山晶皓, 村山徹, 藤田隆史, 坂口紀史, 嶋田哲也, 高木慎介, 石田玉青, 日本化学会春季年会講演予稿集(Web), 102nd, 2022 - 金属-有機構造体で被覆した金属酸化物担持金ナノ粒子触媒の調製とアルコール酸化触媒活性
門脇伸太朗, 中山晶皓, 坂口紀史, 村山徹, 高木慎介, 嶋田哲也, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 130th, 2022 - 層状複水酸化物(LDH)ナノ粒子を用いた担持金クラスター触媒の開発
中山晶皓, 吉田彩乃, 青野智香, 岡山夏帆, 本間徹生, 坂口紀史, 竹歳絢子, 藤田隆史, 村山徹, 村山徹, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 130th, 2022 - 層状複水酸化物ナノシートを用いた金属ナノ粒子触媒表面の修飾とその触媒活性
岡山夏帆, 中山晶皓, 村山徹, 坂口紀史, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 130th, 2022 - Ag/Al2O3触媒を用いたアンモニアの選択酸化(NH3-SCO)におけるAg粒子サイズが選択性に与える影響
WANG Haifeng, 村山徹, 村山徹, LIN Mingyue, 坂口紀史, 三浦大樹, 宍戸哲也, 触媒討論会討論会A予稿集(CD-ROM), 130th, 2022 - Ni-Ti層状複水酸化物から変換したNi-Ti複合酸化物担持Auクラスター触媒によるCO酸化反応
高橋あゆ, 中山晶皓, 村山徹, 坂口紀人, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 130th, 2022 - バナジウムブロンズ化合物を用いた低温NH3-SCR
猪股雄介, 窪田博愛, 本松吉典, 迫谷聡介, 吉田和広, 鳥屋尾隆, 清水研一, 村山徹, 村山徹, 触媒討論会討論会A予稿集(CD-ROM), 130th, 2022 - 受賞講演 低温空気浄化のための酸化ニオブ担持金ナノ粒子触媒の開発 : 2020年度奨励賞—特集 2020年度受賞講演(2)
村山 徹, ペトロテック = Petrotech : 石油学会情報誌 / 石油学会 編, 44, 10, 672, 677, Oct. 2021
東京 : 石油学会 ; 1978-, Japanese - Recent Development of Gold Catalysts and Their Commercialization.
春田正毅, 春田正毅, 村山徹, 村山徹, 村山徹, 触媒, 63, 1, 2021 - アクロレイン選択酸化反応用工業触媒としての多元系Mo-V複合酸化物の触媒活性場の考察
石川理史, 山田雄大, 樫尾直樹, 下田光祐, 野田渚紗, 村山徹, 上田渉, 触媒討論会講演予稿集(CD-ROM), 127th, 2021 - 低温空気浄化のための酸化ニオブ担持金ナノ粒子触媒の開発
村山徹, ペトロテック, 44, 10, 2021 - 金担持触媒を利用した低温での気相酸化反応~金ナノ粒子から金シングルアトム~
村山徹, 村山徹, 触媒討論会討論会A予稿集(CD-ROM), 128th, 2021 - ハイドロキシアパタイト担持金触媒における強い金属-担体相互作用(SMSI)が触媒特性に与える影響
中山晶皓, 袖永竜生, GANGARAJURA Yuvaraj, 竹歳絢子, 村山徹, 本間徹生, 坂口紀史, 嶋田哲也, 高木慎介, 春田正毅, WANG Junhu, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 128th, 2021 - Transesterification of Unsaturated Longchain Aliphatic Ester by Cu deposited Vanadium Oxide Catalyst
SUDHAKARAN Swetha, 竹歳絢子, 村山徹, 野村琴広, 触媒討論会討論会A予稿集(CD-ROM), 128th, 2021 - 層状複水酸化物(LDH)を用いたAu/SiO2表面の修飾とCO酸化活性に及ぼす効果
岡山夏帆, 中山晶皓, 村山徹, 嶋田哲也, 高木慎介, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 128th, 2021 - W置換V2O5触媒による低温・水蒸気雰囲気下でのNH3-SCRと反応機構解析
猪股雄介, 清永英嗣, 盛田啓一郎, 吉田和広, 窪田博愛, 鳥屋尾隆, 清水研一, 春田正毅, 村山徹, 村山徹, 触媒討論会講演予稿集(CD-ROM), 127th, 2021 - 金ナノ粒子触媒の最新動向
村山 徹, ペトロテック = Petrotech : 石油学会情報誌 / 石油学会 編, 43, 6, 1p,432, 436, Jun. 2020
東京 : 石油学会 ; 1978-, Japanese - 担持金ナノ粒子触媒を用いたフルフラール酸化反応における担体が与える影響と金粒子サイズの効果
望月ちひろ, LIN Mingyue, 竹歳絢子, 石田玉青, 宍戸哲也, 中島清隆, 春田正毅, 村山徹, 触媒討論会講演予稿集(CD-ROM), 125th, 2020 - 強い金属-担体相互作用(SMSI)を利用した置換ハイドロキシアパタイト担持金ナノ粒子触媒による3,4-diacetoxybut-1-eneの異性化反応
中山晶皓, 袖永竜生, GANGARAJURA Yuvaraj, 竹歳絢子, 村山徹, 本間徹生, 坂口紀史, 嶋田哲也, 高木慎介, 春田正毅, WANG Junhu, 石田玉青, 触媒討論会講演予稿集(CD-ROM), 125th, 2020 - 置換ハイドロキシアパタイト担持金触媒による3,4-diacetoxybut-1-eneの異性化反応-強い金属-担体相互作用(SMSI)の効果-
中山晶皓, 袖永竜生, GANGARAJURA Yuvaraj, 竹歳絢子, 村山徹, 本間徹生, 坂口紀史, 嶋田哲也, 高木慎介, 春田正毅, WANG Junhu, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 126th, 2020 - 水蒸気存在下での低温脱硝を目指したタングステン添加酸化バナジウム触媒
猪股雄介, 清永英嗣, 盛田啓一郎, 吉田和広, 窪田博愛, 鳥屋尾隆, 清水研一, 春田正毅, 村山徹, 村山徹, 石油・石油化学討論会講演要旨, 50th (Web), 2020 - ミクロ細孔を有するW4V3O19複合酸化物へのTiの導入およびNH3-SCR活性評価
神山曜帆, 石川理史, 猪股雄介, 村山徹, 上田渉, 触媒討論会討論会A予稿集(CD-ROM), 126th, 2020 - 150°C以下でNH3-SCR活性を示すバルク酸化バナジウム触媒
猪股雄介, 秦慎一, 清永英嗣, 盛田啓一郎, 吉田和広, 窪田博愛, 鳥屋尾隆, 清水研一, 春田正毅, 村山徹, 触媒討論会講演予稿集(CD-ROM), 125th, 2020 - 水分共存下にて高い低温脱硝作用を示すW添加V2O5触媒
猪股雄介, 清永英嗣, 盛田啓一郎, 吉田和広, 窪田博愛, 鳥屋尾隆, 清水研一, 春田正毅, 村山徹, 村山徹, 触媒討論会討論会A予稿集(CD-ROM), 126th, 2020 - The Effects of Dopants on the Cu-ZrO2 Catalyzed Hydrogenation of Levulinic Acid
Jun Hirayama, Igor Orlowski, Sarwat Iqbal, Mark Douthwaite, Satoshi Ishikawa, Peter J. Miedziak, Jonathan K. Bartley, Jennifer Edwards, Qian He, Robert L. Jenkins, Toru Murayama, Christian Reece, Wataru Ueda, David J. Willock, Graham J. Hutchings, JOURNAL OF PHYSICAL CHEMISTRY C, 123, 13, 7879, 7888, Apr. 2019
English - Supported gold cluster catalysts prepared by solid grinding using a non-volatile organogold complex for low-temperature CO oxidation and the effect of potassium on gold particle size
Luong Xuan Dien, Tamao Ishida, Ayako Taketoshi, Duc Q. Truong, Huynh Dang Chinh, Tetsuo Honma, Toru Murayama, Masatake Haruta, APPLIED CATALYSIS B-ENVIRONMENTAL, 241, 539, 547, Feb. 2019
English - フルフラール選択的酸化反応における担持金ナノ粒子触媒の担体・サイズ効果
望月ちひろ, 竹歳絢子, 石田玉青, 春田正毅, 村山徹, 石油学会年会講演要旨, 62nd, 2019 - 酸化亜鉛に担持した金ナノ粒子触媒によるCO酸化-低温における酸素の活性化過程の変化-
藤田隆史, 石田玉青, 芝本幸平, 本間徹生, 大橋弘範, 村山徹, 春田正毅, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019 - Au/Nb2O5による5-ヒドロキシメチルフルフラールの選択的光酸化
望月ちひろ, 宍戸哲也, 石田玉青, 春田正毅, 村山徹, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019 - 担持金ナノ粒子触媒における金ナノ粒子の電子状態がフルフラール酸化反応に与える影響
望月ちひろ, LIN Mingyue, 竹歳絢子, 石田玉青, 中島清隆, 春田正毅, 村山徹, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019 - 強い金属-担体相互作用をもつハイドロキシアパタイト担持金ナノ粒子触媒によるビニル基交換反応
石田玉青, 袖永竜生, GANGARAJULA Yuvaraj, 中山晶晧, 竹歳絢子, 村山徹, WANG Junhu, 春田正毅, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019 - ハイドロキシアパタイト担持金ナノ粒子触媒による脂肪族アルデヒドの酸化的エステル化:カチオンおよびアニオン置換効果
竹歳絢子, GANGARAJULA Yuvaraj, 袖永竜生, 村山徹, WANG Junhu, 春田正毅, 石田玉青, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019 - 酸化ニオブによる5-ヒドロキシメチルフルフラールの選択的光酸化における金ナノ粒子担持効果
望月ちひろ, 宍戸哲也, 石田玉青, 春田正毅, 村山徹, 石油・石油化学討論会講演要旨, 49th (Web), 2019 - 150°C以下でNOのNH3-SCRに活性を示す酸化バナジウム触媒
猪股雄介, 秦慎一, 清永英嗣, 盛田啓一郎, 吉田和広, 春田正毅, 村山徹, 触媒討論会講演予稿集(CD-ROM), 123rd, 2019 - Low-temperature NH3-SCR Activity of Nanoparticulate Gold Supported on a Metal Oxide
猪股雄介, 美濃真, 秦慎一, 秦慎一, 清永英嗣, 盛田啓一郎, 引野健治, 吉田和広, 春田正毅, 村山徹, Journal of the Japan Petroleum Institute (Web), 62, 5, 2019 - 150°C以下でNH3-SCR活性を示すバルク酸化バナジウム触媒-4価バナジウムの効果-
猪股雄介, 秦慎一, 清永英嗣, 盛田啓一郎, 吉田和広, 春田正毅, 村山徹, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019 - Versatile etherification of alcohols with allyl alcohol by a titanium oxide- supported molybdenum oxide catalyst: gradual generation from titanium oxide and molybdenum oxide
Yoshihiro Kon, Tadahiro Fujitani, Takuya Nakashima, Toru Murayama, Wataru Ueda, CATALYSIS SCIENCE & TECHNOLOGY, 8, 18, 4618, 4625, Oct. 2018
English - Synthesis of gold nanoparticulate catalysts deposited on polyoxometalate and their catalytic activity for CO oxidation
村山徹, 吉田拓也, 坂口紀史, 石田玉青, 春田正毅, 触媒討論会講演予稿集, 121st, 20‐22, 09 Mar. 2018
Japanese - Facile Formation of Lactic Acid from a Triose Sugar in Water over Niobium Oxide with a Deformed Orthorhombic Phase
Nakajima, K., Hirata, J., Kim, M., Gupta, N.K., Murayama, T., Yoshida, A., Hiyoshi, N., Fukuoka, A., Ueda, W., ACS Catalysis, 8, 1, 283, 290, 2018 - Selective dehydrative allylation using TiO2 supported MoO3 catalyst
Kon Yoshihiro, Yada Akira, Nakamura Yoichi, Fujitani Tadahiro, Nakashima Takuya, Murayama Toru, Ueda Wataru, Proc. JPI, 2018, 0, 2018
従来の電子材料用途アリルエーテルの合成法では、塩化アリルを原料に用いるため、製品純度の低下、副生成物の処理、触媒コストが問題となる。我々は、アリルアルコールと1-オクタノールをTiO<sub>2</sub>+MoO<sub>3</sub>触媒存在下140 ℃で4時間反応させると、アリルオクチルエーテルが収率84%で得られることを発見し、塩素フリーな高選択的アリルエーテルの合成法を開発した。副生物は水のみで触媒は回収再使用できる。詳細な触媒解析と反応成績の考察から、反応機構の検討も行なった。, The Japan Petroleum Institute, Japanese - Active site structure of W-V oxide catalysts for selective oxidation of toluene to benzoic acid
Shimizu Kenichi, Goto Yoshinori, Toyao Takashi, Murayama Toru, Hiyoshi Norihito, Ueda Wataru, Proc. JPI, 61st, 0, 2018
水熱合成によりW-V複合酸化物触媒を合成した。各種キャラクタリゼーションにより本触媒のバルク・表面構造を決定した。本触媒はトルエンの安息香酸への選択酸化に高い収率(70%)を示した。対照触媒との比較から活性種の局所構造を提案する。, The Japan Petroleum Institute, Japanese - 酸化物に担持した金ナノ粒子の抗炎症作用
藤田隆史, 石田玉青, 村山徹, 春田正毅, ラノーン ソフィー, ボクツコウスキ ジョージ, 日本生化学会大会(Web), 91st, 2018 - 担持金ナノ粒子触媒による脂肪族アルデヒド,アルコールの酸化的エステル化
竹歳絢子, 石田玉青, 村山徹, 春田正毅, 触媒討論会討論会A予稿集, 122nd, 2018 - フルフラール酸化における金ナノ粒子触媒の担体・サイズ効果
望月ちひろ, 竹歳絢子, 石田玉青, 春田正毅, 村山徹, 酸化反応討論会講演要旨集, 51st, 2018 - 酸化モリブデン担持触媒によるアミンのアリル化反応
今喜裕, 藤谷忠博, 中島拓哉, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 122nd, 2018 - 低温(200°C以下)でのNOのNH3-SCRにおけるV2O5の触媒作用
秦慎一, 猪股雄介, 美濃真, 清永英嗣, 盛田啓一郎, 吉田和広, 春田正毅, 村山徹, 触媒討論会討論会A予稿集, 122nd, 2018 - ポリオキソメタレートに担持した金クラスター触媒によるCO酸化反応-ポリオキソメタレート担体の効果-
猪股雄介, 吉田拓也, 春田正毅, 村山徹, 触媒討論会討論会A予稿集, 122nd, 2018 - 酸化バナジウムを用いた低温(200°C以下)におけるNOのNH3-SCR
秦慎一, 秦慎一, 猪股雄介, 美濃真, 清永英嗣, 盛田啓一郎, 吉田和広, 春田正毅, 村山徹, 分子科学討論会講演プログラム&要旨(Web), 12th, 2018 - Low-Temperature CO Oxidation over Combustion Made Fe- and Cr-Doped Co3O4 Catalysts: Role of Dopant's Nature toward Achieving Superior Catalytic Activity and Stability
Tinku Baidya, Tom Murayama, Parthasarathi Bera, Olga V. Safonova, Patrick Steiger, Nirmal Kumar Katiyar, Krishanu Biswas, Masatake Haruta, JOURNAL OF PHYSICAL CHEMISTRY C, 121, 28, 15256, 15265, Jul. 2017
English - Synthesis of Crystalline Microporous Mo-V-Bi Oxide for Selective (Amm)Oxidation of Light Alkanes
Ishikawa, S., Goto, Y., Kawahara, Y., Inukai, S., Hiyoshi, N., Dummer, N.F., Murayama, T., Yoshida, A., Sadakane, M., Ueda, W., Chemistry of Materials, 29, 7, 2939, 2950, 2017 - Furfral oxidation by gold nanoparticle catalyst deposited on Nb2O5
Murayama Toru, Taketoshi Ayako, Ishida Tamao, Haruta Masatake, Proc. JPI, 2017, 0, 2017
金ナノ粒子を担持した酸化ニオブを用いてフルフラールの酸化反応を行った。実験は液相流通式反応装置を用いた。担体にアモルファス酸化ニオブ、単斜晶酸化ニオブ、斜方晶酸化ニオブ、層状酸化ニオブを用いて検討したところ、層状酸化ニオブに金を担持すると高活性であった。金担持層状酸化ニオブを用いたフルフラールの酸化反応は、反応温度が50℃から100℃において効率よく進行し、それ以上はフロ酸への選択率が低下した。, The Japan Petroleum Institute, Japanese - Effects of crystalline structure of Nb2O5 and its solid acidity on the catalytic activity for gas/liquid phase oxidation over Au/Nb2O5 catalysts
村山徹, GUPTA Navneet Kumar, 中島清隆, 福岡淳, 春田正毅, 触媒討論会講演予稿集, 119th, 2017 - 結晶性Mo-V-Bi複合酸化物の合成とそれを用いた低級アルカン(アンモ)酸化反応
石川理史, 後藤文倫, 河原義人, 犬飼将槙, 日吉範人, DUMMER Nicholas F., 村山徹, 吉田暁弘, 定金正洋, 上田渉, 触媒討論会討論会A予稿集, 120th, 2017 - 金ナノ粒子担持触媒を用いたフルフラール酸化
村山徹, GUPTA Navneet Kumar, 中島清隆, 福岡淳, 春田正毅, 触媒討論会討論会A予稿集, 120th, 2017 - 酸化バナジウムを用いた低温(200°C以下)におけるNOのNH3-SCR
秦慎一, 村山徹, 美濃真, 清永英嗣, 盛田啓一郎, 引野健治, 春田正毅, 触媒討論会討論会A予稿集, 120th, 2017 - メソポーラスシリカ上に調製した酸化ニオブ薄膜を担体とした金ナノ粒子触媒の触媒活性評価
日吉優貴, 大須賀遼太, 横井俊之, 村山徹, 春田正毅, 野村淳子, 触媒討論会討論会A予稿集, 120th, 2017 - マグネシウムの水素吸蔵放出反応における種々のNb酸化物の触媒効果
宮岡裕樹, 新里恵多, 魏弘之, 定金正洋, 村山徹, 市川貴之, 日本金属学会講演概要(CD-ROM), 161st, 2017 - ポリオキソメタレートに担持した金クラスター触媒によるCO酸化反応
吉田拓也, 村山徹, 春田正毅, 触媒討論会講演予稿集, 119th, 2017 - W-Ti-O複合金属酸化物触媒によるアルコールの脱水交差エーテル化反応
矢田陽, 村山徹, 平田純, 中島拓哉, 今喜裕, 上田渉, 触媒討論会討論会A予稿集, 120th, 2017 - Synthesis of microporous crystalline Mo-V-Oxide and its application for selective oxidations
石川理史, 村山徹, 上田渉, ゼオライト, 33, 4, 110, 120, 15 Oct. 2016
ゼオライト学会, Japanese - Lactic acid formation from triose sugar in water over crystalline niobic acid
Nakajima Kiyotaka, Murayama Tohru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2016, 0, 130, 130, 2016
水溶性ニオブ錯体を水熱処理することによって結晶性のニオブ酸が合成できる。得られたニオブ酸はブレンステッド酸とルイス酸を有しており、それらの酸触媒サイトは吸着水存在下において塩基性プローブ分子と相互作用することができる。この触媒をトリオース水溶液に加えて加熱したところ、約80%の収率で乳酸が生成した。高い触媒活性は水中で機能するルイス酸およびブレンステッド酸の有効酸量が大きいためであると考えられる。, The Japan Petroleum Institute, Japanese - Synthesis of trigonal Mo-V-M-O (M = Fe, W) catalysts by using structure-directing agent and catalytic performances for selective oxidations of ethane and acrolein
Ishikawa Satoshi, Murayama Toru, Tashiro Masaya, Zhenxin Zhang, Yoshida Akihiro, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2015, 0, 196, 196, 05 Nov. 2015
Crystalline trigonal Mo-V-M-O (M = Fe, W) catalysts were obtained by using structure-directing agent. Trigonal Mo-V-O is a layered structure and the cross-section is comprised of the netwark structure based Mo pentagonal unit and V octahedral, forming pentagonal, hexagonal, and heptagonal channels in the structure. Fe was located in the hepgatonal channel and W was placed at the Mo pentagonal unit by substituting Mo. Mo-V-O and Mo-V-W-O showed almost the same catalytic activity for the selective oxidations of ethane and acrolein, on the other hand, the activities decreased by the location of Fe inside the channel. Clear relationship in catalyst structure and catalytic activity was found., The Japan Petroleum Institute, Japanese - Cu‐Zr‐O触媒を用いたレブリン酸の水素化反応およびその触媒活性化部位
石川理史, 石川理史, JONES Daniel R, IQBAL Sarwat, MORGAN David J, WILLOCK David J, BARTLEY Jonathan K, EDWARDS Jennifer K, 村山徹, 清水研一, 上田渉, HUTCHINGS, Graham J, 触媒討論会討論会A予稿集, 116th, 203, 09 Sep. 2015
Japanese - Ultrathin inorganic molecular nanowire based on polyoxometalates
Zhenxin Zhang, Toru Murayama, Masahiro Sadakane, Hiroko Ariga, Nobuhiro Yasuda, Norihito Sakaguchi, Kiyotaka Asakura, Wataru Ueda, NATURE COMMUNICATIONS, 6, 0, Jul. 2015
English - Intramolecular hydrogen-transfer reaction for diols conversion over V2O3 and MoO2 catalysts
Nakamura Yoichi, Murayama Toru, Shimizu Kenichi, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2015, 0, 51, 51, 26 May 2015
V<sub>2</sub>O<sub>3</sub>およびMoO<sub>2</sub>触媒を用いたジオール転換反応について検討した。V<sub>2</sub>O<sub>3</sub>およびMoO<sub>2</sub>触媒によるプロピレングリコールの転換反応では主生成物としてアセトンが観測され、副生成物としてプロピオンアルデヒドとプロピレンが同程度の選択率で生成した。V<sub>2</sub>O<sub>3</sub>およびMoO<sub>2</sub>触媒によるプロピオンアルデヒドの生成は触媒表面に存在する酸サイトにて進行したと考えられる。本反応メカニズムの詳細を検討したところ、V<sub>2</sub>O<sub>3</sub>およびMoO<sub>2</sub>触媒におけるアセトン生成は、水素移行脱水反応がプロピレングリコールの分子内にて進行すると提案した。, The Japan Petroleum Institute, Japanese - V2O3およびMoO2触媒を用いた水素移行脱水反応によるアルコールからのアルカン,アルデヒドおよびケトン同時生成
中村陽一, 村山徹, 上田渉, 触媒討論会講演予稿集, 115th, 34, 36, 10 Mar. 2015
Japanese - 水熱合成により調製したW‐M‐O(M=Ti,Zr,Nb,Ta)触媒による加水分解および脱水反応
村山徹, 上田渉, 触媒討論会講演予稿集, 115th, 73, 10 Mar. 2015
Japanese - Light alkane activation chemistry and technology using high dimensional crystalline complex metal oxide catalysts
Wataru Ueda, Satoshi Ishikawa, Toru Murayama, King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers, 2015-January, 2, 12, 01 Jan. 2015 - Light alkane activation chemistry and technology using high dimensional crystalline complex metal oxide catalysts
Wataru Ueda, Satoshi Ishikawa, Tom Murayama, International Air Safety Seminar Proceedings, 2015-January, 8, 18, 01 Jan. 2015 - 結晶性Mo3VOxの7員環反応場を利用した低級アルカン,アルデヒド,アルコールの酸化反応
村山徹, 石川理史, QIU Chuntian, 後藤文倫, 上田渉, 酸化反応討論会講演要旨集, 47th, 62, 64, 14 Nov. 2014
Japanese - W‐Ti‐O触媒によるスルフィドの高選択酸化反応の開発
今喜裕, 村山徹, 田中真司, 平田純, 中島拓哉, 佐藤一彦, 上田渉, 酸化反応討論会講演要旨集, 47th, 103, 105, 14 Nov. 2014
Japanese - 水熱合成法により調製したW‐Nb(‐V)‐O複合酸化物触媒による乳酸酸化反応
村山徹, 小俣香織, KATRYNIOK Benjamin, PAUL Sebastien, 上田渉, 石油・石油化学討論会講演要旨, 44th, 0, 139, 16 Oct. 2014
水熱合成法により調製したW-Nb-V-O複合酸化触媒を用いて乳酸の酸化反応を行った。合成した触媒は、共通して金属オクタヘドラル構造が点共有によりC軸方向に積層した層状の構造を有していた。Vの含有量を変化させて乳酸の酸化反応を行ったところ、V含有量が多くなるに従い、ピルブアルデヒドの生成量が増加した。触媒の金属組成比がW<sub>2</sub>Nb<sub>2.7</sub>V<sub>1.2</sub>O<sub>x</sub>のとき、ピルブアルデヒドの収率が19 %であった。, 公益社団法人 石油学会, Japanese - 種結晶添加法による結晶性MoVO複合酸化物触媒の合成と低級アルカン選択酸化反応
田代雅也, 石川理史, 村山徹, 上田渉, 石油・石油化学討論会講演要旨, 44th, 0, 357, 16 Oct. 2014
結晶性MoVO複合酸化物は低級アルカンの選択酸化反応に高い活性を示す触媒である。前駆体溶液のpHを調整することで斜方晶、三方晶などの結晶相が作り分けられる。今回、種結晶添加法をMoVO合成に応用することにより、広いpH領域において容易に触媒の作り分けが可能となった。得られた触媒のキャラクタリゼーションや反応活性試験から、種結晶を用いて合成した試料も種結晶と同様に高い活性を示すことが明らかとなった。, 公益社団法人 石油学会, Japanese - 水熱合成W‐V‐O複合酸化物触媒によるピコリンのアンモ酸化
後藤文倫, 村山徹, 清水研一, 上田渉, 触媒討論会討論会A予稿集, 114th, 0, 126, 18 Sep. 2014
当研究室では水熱法により合成した結晶性層状構造複合酸化物触媒を報告してきた。一連の触媒はその構造に由来した高い活性を有している。本研究では同様の構造を有するW-V-O複合酸化物がピコリンのアンモ酸化反応において高収率でシアノピリジンを与えることを見出した。各組成の触媒性能の違いから活性要因についても考察する。, 公益社団法人 石油学会, Japanese - 水素移行脱水反応機構によるV2O3およびMoO2上でのアルコールからのアルカン,アルデヒド同時生成
中村陽一, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 114th, 424, 18 Sep. 2014
Japanese - 種結晶添加による斜方晶MoOx酸化物の水熱合成
田代雅也, 石川理史, 坂口紀史, 村山徹, 清水研一, 上田渉, 触媒討論会討論会A予稿集, 114th, 150, 18 Sep. 2014
Japanese - 斜方晶Mo30V10O112複合酸化物触媒の酸化還元処理に伴うミクロ細孔径制御およびそのエタン選択酸化触媒活性
石川理史, 小林大地, 紺谷岳史, 大村俊平, 村山徹, 定金正洋, 上田渉, 触媒討論会講演予稿集, 113th, 32, 34, 10 Mar. 2014
Japanese - Effects of W on the selective oxidation of acrolein to acrylic acid over orthorhombic and trigonal Mo-V-W-O
Qiu Chuntian, Ishikawa Satoshi, Murayama Toru, Ueda Wataru, Proc. JPI, 2014, 0, 2014
Orthorhombic and trigonal phase Mo-V-W-O complex oxides were synthesized with one-step hydrothermal method. And their catalytic activity for selective oxidation of acrolein to acrylic acid was investigated. The results showed that both of orthorhombic and trigonal phase Mo-V-W-O complex oxides are excellent catalysts for acrolein oxidation to acrylic acid especially under low water partial pressure. , The Japan Petroleum Institute, Japanese - W複合酸化物触媒によるグリセロールからのアクリル酸合成
小俣香織, 松本慶江子, 村山徹, 上田渉, 酸化反応討論会講演要旨集, 46th, 109, 111, 15 Nov. 2013
Japanese - 層構造を有するW系複合酸化物の水熱合成およびその固体酸性質
平田純, 小俣香織, 倉又望, 村山徹, 上田渉, 石油・石油化学討論会講演要旨, 43rd, 0, 25, 14 Nov. 2013
我々はこれまで水熱合成法により合成したW-M-O酸化物(M=Zr,Ti,Nb,V,Ta)が固体酸性質を有しており、フリーデル・クラフツアルキル化反応に高い活性を示すことを報告してきた。今回、種々の水熱合成条件の検討を行い、調製したW-M-O複合酸化物触媒の結晶構造、細孔特性,酸触媒性能の評価を行った。その結果、XRDにおいて積層構造を示す23°にピークを与える物質が高い固体酸触媒性質を有していることが分かった。, 公益社団法人 石油学会, Japanese - Metal Oxide Catalysts with Complex Crystal Structures for Selective Oxidation
上田渉, 村山徹, 石川理史, 化学工業, 64, 10, 785, 791, 01 Oct. 2013
小峰工業出版, Japanese - Metal Oxide Catalysts with Complex Crystal Structures for Selective Oxidation
上田 渉, 村山 徹, 石川 理史, 化學工業, 64, 10, 785, 791, Oct. 2013
小峰工業出版, Japanese - 三方晶Mo‐V‐M‐O(M=Fe,Cu,Nb,Ta,W)の合成および低級アルカン選択酸化触媒活性
石川理史, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 112th, 274, 11 Sep. 2013
Japanese - 種結晶を用いた結晶性Mo‐V‐O複合酸化物の調製と水熱下生成機構
田代雅也, 石川理史, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 112th, 487, 11 Sep. 2013
Japanese - W複合酸化物触媒の表面機能とグリセロール転換反応の選択性との関連
小俣香織, 松本慶江子, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 112th, 210, 11 Sep. 2013
Japanese - Selective Oxidation of Light Alkane over the Mo-V-O Complex Metal Oxide
MURAYAMA Toru, UEDA Wataru, 觸媒 = Catalyst, 55, 3, 148, 153, 10 Jun. 2013
触媒学会, Japanese - Effects of reduced species of vanadium oxide catalyst on the formation of ethane from ethanol
Nakamura Yoichi, Murayama Toru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2013, 38, 38, 28 May 2013
バナジウム酸化物触媒を用いてエタノール転換反応にて触媒性能を検討したところ、エタンおよびアセトアルデヒドが各々収率約30 %で生成した。バナジウム酸化物によるエタノールの選択酸化反応では、生成物としてアセトアルデヒドやエチレンが生成するという報告例は多数あるが、エタン生成に関する報告例はない。そこで本研究では、バナジウム酸化物の新たな触媒性能を検討するために、バナジウム酸化物におけるアルコールからのアルカン生成についての詳細な検討を行った。, The Japan Petroleum Institute, Japanese - Hydrothermal synthesis of W-Ti-O complex oxide catalyst and their acid properties
Hirata Jun, Murayama Toru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2013, 0, 37, 37, 28 May 2013
硫酸チタン(III)、メタタングステン酸アンモニウムおよびシュウ酸の混合水溶液を175 ℃で24時間水熱合成を行い、複合酸化物を調製した。前駆体のW/Tiモル比および、前駆体濃度およびシュウ酸の添加量を変化させることにより、積層構造を有するW-Ti-O複合酸化物触媒が得られた。合成したW-Ti-O複合酸化物触媒は、ピリジン吸着IRおよびアンモニアTPDにより固体酸性質を有することが分かった。種々の基質を用いてフリーデルクラフツ・アルキル化反応を検討したところ、既報の固体酸触媒と比較し高い反応活性を示した。, The Japan Petroleum Institute, Japanese - グリセロールからのアクリル酸一段階合成のためのW複合酸化物触媒の開発
小俣香織, 松本慶江子, 村山徹, 上田渉, 触媒討論会講演予稿集, 111th, 14, 16, 11 Mar. 2013
Japanese - 界面活性剤を添加して合成した斜方晶Mo3VOxの低級アルカン選択酸化活性
石川理史, 村山徹, 上田渉, 酸化反応討論会講演要旨集, 45th, 188, 190, 16 Nov. 2012
Japanese - Alcohol transformation using solid acid catalyst of complex metal oxide
Murayama Toru, Nakamura Yoichi, Kuramata Nozomi, Hirata Jun, Omata Kaori, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2012, 0, 166, 166, 11 Oct. 2012
複合酸化物型固体酸触媒を合成し、アルコールの転換反応を検討した。触媒はタングステン、モリブデン、バナジウム、ニオブ、タンタルの5,6族元素を用いて水熱処理により種々の複合酸化物を合成した。調製した固体酸触媒は、XRD、NH<sub>3</sub>-TPD、STEMでキャラクタリゼーションを行った。また、得られた生成物を比較検討することで、触媒の持つ酸性質を検討した。, The Japan Petroleum Institute, Japanese - 界面活性剤を用いた結晶性Mo‐V‐O複合酸化物の合成および低級アルカン選択酸化活性
石川理史, XI Xiaodong, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 110th, 390, 14 Sep. 2012
Japanese - Alcohol transformation using solid acid catalyst of complex metal oxide
Murayama Toru, Nakamura Yoichi, Kuramata Nozomi, Hirata Jun, Omata Kaori, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2012, 0, 166, 166, 2012
複合酸化物型固体酸・塩基触媒を合成し,アルコールの転換反応を検討した.触媒はW,Mo,Zrなどの遷移金属およびSi,Mgの組み合わせを水熱条件下または固相法にて複合化し調製した.調製した固体酸・塩基触媒は,XRD,NH<sub>3</sub>-TPD,CO<sub>2</sub>-TPD,SEM,元素分析でキャラクタリゼーションを行った.合成した触媒の活性および生成物選択性を基に,触媒の構造と構成元素の役割および固体酸・塩基性質の解明を試みた., The Japan Petroleum Institute, Japanese - Epoxidation of olefin catalyzed by a new microporous material based on molybdenum, vanadium, and bismuth
Zhang Zhenxin, Izumi Shoko, Murayama Toru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2012, 0, 122, 122, 2012
A novel microporous complex metal oxide based on molybdenum, vanadium, and bismuth (Mo-V-Bi oxide) was synthesized by hydrothermal method and characterized by STEM, TEM, XRD, FT-IR, Raman, TPD, NH<sub>3</sub>-TPD, and N<sub>2</sub> adsorption. The results showed that Mo-V-Bi oxide was crystalline material with high porosity and surface area. The single crystal of Mo-V-Bi oxide was obtained for single crystal analysis to gain full structural information of this material. This material was used as a heterogeneous catalyst for olefin epoxidation with TBHP. The stable catalyst could be reused for several times without loss of activity., The Japan Petroleum Institute, Japanese - W-Nb-O複合酸化物の合成と酸触媒機能
小俣香織, 泉彰子, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 109th, 2012 - 水熱合成法によるMo-(Nb,Ta)-O複合酸化物触媒の合成と酸触媒能の評価
村山徹, 倉又望, 泉彰子, 上田渉, 触媒討論会討論会A予稿集, 109th, 2012 - 5,6族元素を用いた複合酸化物の合成と固体酸性質評価
村山徹, YI Xiaodong, 高玉峻介, 泉彰子, 上田渉, 触媒討論会討論会A予稿集, 107th, 2011 - Pd(0)ナノ粒子担持炭素触媒によるフェノールの電解カルボニル化
村山徹, 林外茂彦, 山中一郎, 触媒討論会討論会A予稿集, 108th, 2011 - 低級アルカン酸化反応におけるMo3VOxの触媒性能と活性点について
紺谷岳史, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 108th, 2011 - 各種有機アンモニウムモリブデン酸塩を用いたMo-V-O複合酸化物の合成および低級アルカン酸化活性
石川理史, 紺谷岳史, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 108th, 2011 - 熱活性化Fe-TPP/C触媒による炭化水素の選択部分酸化
柳下亮, 越智紀明, 村山徹, 上田渉, 山中一郎, 触媒討論会討論会A予稿集, 108th, 2011 - 熱活性活性化Co-TPP/C電極触媒による過酸化水素の選択合成
岩崎達也, 西村直也, 村山徹, 上田渉, 山中一郎, 触媒討論会討論会A予稿集, 108th, 2011 - 水熱合成法によるW-Zr-O複合酸化物の合成と酸触媒特性
安藤雅郎, 泉彰子, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 108th, 2011 - 種々の水熱条件で合成した多孔性W-Ta-O複合酸化物の結晶構造および酸触媒能
倉又望, 泉彰子, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 108th, 2011 - Mo-Nb-O複合酸化物を用いた酸触媒能の評価
村山徹, 泉彰子, YI Xiaodong, 上田渉, 触媒討論会討論会A予稿集, 108th, 2011 - 低級アルカン酸化反応におけるMo3VOx触媒の還元度の影響
紺谷岳史, 村山徹, 上田渉, 酸化反応討論会講演要旨集, 44th, 2011 - Synthesis of porous and acidic complex metal oxide based on group 5 and 6 elements
Murayama Toru, Yi Xiaodong, Kuramata Nozomi, Izumi Syoko, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2011, 0, 9, 9, 2011
既に我々は、水熱合成により細孔を有する結晶性Mo-V-O触媒の合成に成功し報告した。この手法を応用し、5、6族元素をベースとした新規結晶性複合金属酸化物触媒の合成に展開した。実際に水熱合成法を用いてMoVO、MoNbO、MoTaO、WVO、WNbO、WTaOを合成し、合成した酸化物の固体酸性質をフリーデル・クラフツアルキル化反応を用いて評価した。, 公益社団法人 石油学会, Japanese - The propane ammoxidation over trigonal Mo-V-Te-O catalysts
Yi Xiaodong, Murayama Toru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2011, 0, 8, 8, 2011
The selective oxidation of propane to oxygenates has attracted a lot of attention. Among the catalysts that has been tested for propane oxidation so far, MoVTeNbO is the most active and selective catalyst for the oxidation of propane. Our group have succeeded in synthesizing monophasic orthorhombic MoVO with or without other element(Te, Sb or Nb) under hydrothermal conditions. In the present study, we tried to synthesize single-phase MoVTeO with trigonal structure and tested its catalytic activity by propane ammoxidation., 公益社団法人 石油学会, Japanese - None-phosgene method for DPC synthesis by electrocarbonylation of phenol
Yamanaka Ichiro, Murayama Toru, Hayashi Tomohiko, Kanega Ryouichi, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2011, 0, 186, 186, 2011
既に我々は、PdCl2/ACアノードがフェノールの酸化的カルボニル化による炭酸ジフェニル合成に活性を示すことを報告している。今回アノード触媒の適切化を行ったところ、Pdナノ金属粒子を炭素上に担持した触媒が炭酸ジフェニル合成に高活性を示すことを見出した。Pd粒子径とカルボニル化活性の間には強い依存性があることを見出した。, The Japan Petroleum Institute, Japanese - Synthesis of acrolein from glycerol over W-Nb complex metal oxide
Omata Kaori, Izumi Shoko, Murayama Toru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2011, 0, 52, 52, 2011
水熱合成法により調製したWとNb複合酸化物は、層構造に起因するXRDパターンを有する。このW-Nb複合酸化物をグリセロール転換反応に用いたところ、脱水により高選択的にアクロレインが得られることが分かった。発表では、W-Nb複合酸化物の調製条件や、種々の金属添加が、生成物分布に与える影響について述べる。, The Japan Petroleum Institute, Japanese - The selective oxidation of alkane over trigonal Mo-V-M-O catalysts
Yi Xiaodong, Kobayashi Daichi, Konya Takeshi, Murayama Toru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2011, 0, 95, 95, 2011
プロパンのアンモ酸化反応には、MoVNbTeO複合酸化触媒が高い活性を示すと数多くの報告がある。しかしながら、それぞれの金属元素の役割につては明確ではない。これまで我々は、Mo、Vのみを構成元素に用いた三方晶Mo-V-Oを合成し報告を行ってきた。今回、三方晶Mo-V-Oおよび、第三成分としてNbまたはTeを添加した三方晶MoV(Nb,Te)O複合酸化触媒を調製し、アンモ酸化反応,プロパン酸化,エタン酸化,メタン酸化により活性を評価することにより、触媒の結晶構造および金属成分の役割の解明を検討した。, The Japan Petroleum Institute, Japanese - Direct Synthesis of Diphenyl Carbonate by Pd Electrocatalyst under Ambient Conditions
MURAYAMA Toru, HAYASHI Tomohiko, ARAI Yuji, YAMANAKA Ichiro, 觸媒 = Catalyst, 52, 6, 405, 407, 04 Sep. 2010
触媒学会, Japanese - Direct Synthesis of Diphenyl Carbonate by Electrocarbonylation at a Pd2+-supported Anode
Toru Murayama, Yuji Arai, Tomohiko Hayashi, Ichiro Yamanaka, CHEMISTRY LETTERS, 39, 4, 418, 419, Apr. 2010
English - CoPc/CカソードによるCO2の気相電解
田端恭介, 村山徹, 加藤之貴, 小原徹, 山中一郎, 電気化学会大会講演要旨集, 77th, 2010 - フェノールの電解カルボニル化による炭酸ジフェニル直接合成
林外茂彦, 村山徹, 山中一郎, 電気化学会大会講演要旨集, 77th, 2010 - 酸触媒アシル化反応からのピルビン酸エチルからα-アセトキシアクリル酸エチルの合成
中村陽一, 村山徹, 二宮航, 安川隼也, 大谷内健, 定金正洋, 上田渉, 触媒討論会討論会A予稿集, 106th, 2010 - 水熱合成法による5,6族元素を用いた多孔性固体酸複合酸化物の合成
村山徹, 陳俊利, 高玉峻介, 泉彰子, 上田渉, 触媒討論会討論会A予稿集, 106th, 2010 - Mo3VOx酸化物における細孔構造と選択酸化反応
紺谷岳史, 村山徹, 上田渉, 触媒討論会討論会A予稿集, 106th, 2010 - Mo3VOx触媒の構造特性および炭化水素選択酸化反応
村山徹, 中谷浩介, 紺谷岳史, 上田渉, 酸化反応討論会講演要旨集, 43rd, 2010 - Selective oxidation of acrolein over Mo-V-O based complex metal oxide
Nakatani Kosuke, Murayama Toru, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2010, 0, 46, 46, 2010
当研究室では結晶性Mo-V-O複合金属酸化物の合成に成功し、アクロレインの選択酸化反応触媒として非常に高い活性と選択性を有することを報告してきた。今回,種々の結晶構造を有するMo-V-O酸化物を触媒として用いることにより、構造の担う役割を明らかにすることを目的とした。それに加え、他の金属元素を添加し触媒性能との相関を調べることで、各金属元素の担う役割の解明および触媒性能の改良を検討した。, The Japan Petroleum Institute, Japanese - Synthesis of mesoporous molybdenum niobium oxide by hydrothermal method
Murayama Toru, Takatama Syunsuke, Izumi Syoko, Ueda Wataru, Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2010, 0, 57, 57, 2010
我々はこれまで水熱合成法による結晶性Mo-V-O複合金属酸化物の合成に成功し、アルコールやアルカンの選択酸化触媒として高い活性を有することを報告してきた。今回,水熱合成法による複合酸化物調製を応用し,MO-Nb-O複合酸化物触媒の合成に展開した.調整した触媒について,詳細にキャラクタリゼーションを行った結果,MoNbOxのメソ孔構造は棒状の粒子が不規則に積み重なり形成されていることが示唆された., The Japan Petroleum Institute, Japanese - Catalytic synthesis of neutral H_2O_2 solution at a CoN_2C_x/carbon cathode
YAMANAKA Ichiro, TAZAWA Satoshi, MURAYAMA Toru, TAKENAKA Sakae, 觸媒 = Catalyst, 51, 6, 420, 422, 10 Sep. 2009
触媒学会, Japanese - Direct neutral hydrogen peroxide synthesis at a heat-treated Co-TPP/VGCF cathode using PEMFC
YAMANAKA Ichiro, TAZAWA Satoshi, MURAYAMA Toru, ICHIHASHI Ryo, HANAIZUMI Noriko, 觸媒 = Catalyst, 51, 2, 96, 98, 10 Mar. 2009
触媒学会, Japanese - Pdアノード上での電解酸化カルボニル化によるDPCの直接合成-アルキルアミン添加効果-
村山徹, 荒井悠二, 山中一郎, 触媒討論会討論会A予稿集, 104th, 2009 - Pdアノード上での電解カルボニル化反応によるDPCの直接合成-ナトリウムフェノキシド添加効果-
林外茂彦, 村山徹, 荒井悠二, 山中一郎, 触媒討論会討論会A予稿集, 104th, 2009 - 熱処理活性化Co(NO3)2(phen)/XC72電極による触媒的中性H2O2合成
岩崎達也, 田澤慧, 村山徹, 山中一郎, 触媒討論会討論会A予稿集, 104th, 2009 - 燃料電池反応法を用いた中性H2O2水の合成
田澤慧, 村山徹, 市橋亮, 山中一郎, 電気化学会大会講演要旨集, 75th, 2008 - SPE電解法を利用したCO2還元反応
古澤崇, 村山徹, 山中一郎, 触媒討論会討論会A予稿集, 102nd, 2008 - 膜触媒を用いたO2とH2からのH2O2の直接合成
平木大介, 田澤慧, 村山徹, 山中一郎, 触媒討論会討論会A予稿集, 102nd, 2008 - Neutral H_2O_2 Synthesis by Electrolysis of Water and Air
MURAYAMA Toru, YAMANAKA Ichiro, 触媒 = Catalysts & Catalysis, 49, 6, 453, 455, 05 Sep. 2007
触媒学会, Japanese - 中性過酸化水素の電解合成 (3)
村山徹, 山田淳, 井関正博, 山中一郎, 触媒討論会討論会A予稿集, 99th, 2007 - 燃料電池反応法を用いた中性H2O2水の合成
田澤慧, 村山徹, 市橋亮, 山中一郎, 触媒討論会討論会A予稿集, 100th, 2007 - 中性過酸化水素水の電解合成
村山徹, 山中一郎, 山田淳, 井関正博, 触媒討論会討論会A予稿集, 98th, 2006 - 固体高分子電解質膜を用いた中性過酸化水素水の電解合成
村山徹, 山中一郎, 触媒討論会討論会A予稿集, 96th, 2005
Affiliated academic society
Research Themes
- カチオン欠陥サイトを導入した酸化物担体へのAuシングルアトム調製と触媒反応
科学研究費助成事業
28 Feb. 2024 - 31 Mar. 2027
村山 徹
日本学術振興会, 基盤研究(B), 東京都立大学, 23K26456 - Invesigation of charge states and catalytic reactions on metal oxide surfaces with nanostructures by AFM
Grants-in-Aid for Scientific Research
01 Apr. 2022 - 31 Mar. 2025
李 艶君, 菅原 康弘, 村山 徹
Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (A), Osaka University, 22H00282 - Hydrothermal Synthesis of Complex Metal Oxides by Assembling MO6 Octahedra and Creation of Solid Acid
Grants-in-Aid for Scientific Research
01 Apr. 2012 - 31 Mar. 2015
MURAYAMA Toru
Layered-structure-type tungsten based complex oxides (W-M-O, M= Ti, Zr, Nb, Ta) were synthesized by the hydrothermal method. The synthesized W-M-O showed characteristic peaks at 2θ = 22.7° and 46.2° in an X-ray diffraction pattern (Cu-Ka), indicating linear corner-sharing of MO6 octahedra in the c-direction. The same layered-type materials were obtained with a wide range of W and M composition ratios by using soluble precursors. The catalytic activity of W-M-O increased with increase in the W ratio, suggesting that strong acid sites were generated. From Raman and adsorption measurements of W-M-O with various crystalline structures, it was revealed that the crystalline motif of W-M-O in the a-b plane was an interconnection of MO6 octahedra and {M6O21} pentagonal units and micropore channels but without long-range order.
Japan Society for the Promotion of Science, Grant-in-Aid for Young Scientists (B), Hokkaido University, Principal investigator, Competitive research funding, 24760635 - Structure engineering of functional solid catalysts by unit-network methodology
Grants-in-Aid for Scientific Research
01 Apr. 2011 - 31 Mar. 2014
UEDA Wataru, TAKEGUCHI Tatsuya, SHIMIZU Kenichi, MURAYAMA Toru, SADAKANE Masahiro, KAMIYA Yuichi
Structure engineering of functional solid catalysts has been conducted on the basis of unit-network methodology of molecular-type polyoxide units under hydrothermal condition for creating three-dimensional network structure of the units. The methods were applied to metal oxide components in 6, 5 and 4 element group and successfully gave various solids with nano-size structure with a heptagonal structural unit, confirming the applicability of the method for creating high-dimensional solid structures. This method was also found useful for creating a new three-dimensional zeolite-type porous solid based on molecular-type polyoxide units. The materials are totally new and showed unique adsorption property for CO2 and ethane. These obtained materials showed solid-acid property and incomparable catalytic property based on an asymmetric porous structure.
Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (A), Hokkaido University, 23246135
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