Researcher basic information

• 北海道大学

• Doctor(Science), The University of Tokyo

• https://researchmap.jp/read0102911?lang=en

• https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200901030607620959
• https://www.cat.hokudai.ac.jp/takakusagi/

• 200901030607620959

• その場/オペランド計測
• X線吸収分光法
• 表面X線散乱
• 走査プローブ顕微鏡
• 電極表面科学
• 触媒表面科学

• Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering), Catalyst and resource chemical process
• Nanotechnology/Materials, Thin film/surface and interfacial physical properties
• Nanotechnology/Materials, Functional solid state chemistry
• Nanotechnology/Materials, Fundamental physical chemistry

• Master's degree program, Graduate School of Environmental Science
• Doctoral (PhD) degree program, Graduate School of Environmental Science

Research activity information

• 2025, 日本表面真空学会, 日本表面真空学会フェロー
  「その場/オペランド表面科学計測による表面反応プロセスの原子レベル可視化と機構解明」
  高草木 達
• 2021, 日本表面真空学会, 日本表面真空学会論文賞
  城戸大貴;上村洋平;三輪寛子;高草木達;朝倉清高
• 2017, American Vacuum Society, VTD Shop Note Awards
  Yoshihide Watanabe;Yusaku F. Nishimura;Ryo Suzuki;Hiromitsu Uehara;Tomoyuki Nimura;Atsushi Beniya;Noritake Isomura;Kiyotaka Asakura;Satoru Takakusagi
• 2015, BCSJ（日本化学会欧文誌）賞
  Tao Ma;Kotaro Miyazaki;Hiroko Ariga;Satoru Takakusagi;Kiyotaka Asakura
• 2015, 北海道大学研究総長賞奨励賞
  高草木 達
• 2014, 日本化学会北海道支部奨励賞
  高草木 達
• 2010, 日本化学会, 第90春季年会 「若い世代の特別講演会」証
  高草木 達
• 2008, The Best Poster Prize (ISSS-5)
  Satoru Takakusagi
• 2008, 日本化学会, 第88春季年会優秀講演賞（学術）
  高草木 達, Japan
• 2000, Student Poster Award（PACIFICHEM 2000）
  Satoru Takakusagi

• Precise 3D structure determination of Cu single atoms on α-Al ₂ O ₃ (0001) surface by polarization-dependent total reflection fluorescence X-ray absorption fine structure and first-principles calculation
  Bang Lu; Can Liu; Min Gao; Haoran Xu; Daiki Kido; Masao KIMURA; Kotaro Takeyasu; Kiyotaka Asakura; Satoru Takakusagi
  Physical Chemistry Chemical Physics, Royal Society of Chemistry (RSC), 2026, [Peer-reviewed], [Invited], [Last author, Corresponding author]
  Scientific journal, The valence state and three-dimensional (3D) structure of vacuum-deposited Cu species on an Al-terminated (1×1) α-Al ₂ O ₃ (0001) surface have been studied using polarization-dependent total reflection fluorescence X-ray absorption fine structure (PTRF-XAFS)...
• Synergistic Plasma Catalysis for CO2 Conversion: Mechanistic Insights, Advanced Characterization, and Rational Design Strategies
  Dae-Yeong Kim; Shinya Furukawa; Satoru Takakusagi; Hyun-Ha Kim; Tomohiro Nozaki
  ACS Catalysis, 07 Nov. 2025
  Scientific journal
• One-step conversion of benzene to phenol in plasma-irradiated benzene solution
  Y. Inagaki; Y. R. Hayashi; K. Sasaki; S. Takakusagi; K. Okamoto; A. Nagaki; N. Shirai
  Journal of Applied Physics, 21 Sep. 2025, [Peer-reviewed]
  Scientific journal
• Deciphering Adsorbate–Adsorbate Interactions from Scanning Tunneling Microscopy Images: Integrated Topological, Statistical, and First-Principles Analysis of Methoxy Adsorbates on Pt/TiO₂(110)
  Can Liu; Min Gao; Daiki Kido; Masao Kimura; Kiyotaka Asakura; Bang Lu; Kotaro Takeyasu; Satoru Takakusagi
  The Journal of Physical Chemistry C, American Chemical Society (ACS), 18 Sep. 2025, [Peer-reviewed], [Last author, Corresponding author]
  Scientific journal
• High Turnover Frequency in the Electrocatalytic Reduction of Nitrous Oxide to Dinitrogen at a Binuclear Copper Complex of 3,5‐Diamino‐1,2,4‐Triazole
  Zhengwei Ma; Masaru Kato; Jenny Pirillo; Yuh Hijikata; Takeshi Watanabe; Yohei Uemura; Bang Lu; Satoru Takakusagi; Ken'ichi Kimijima; Hideo Notsu; Ichizo Yagi
  Angewandte Chemie International Edition, 02 Jul. 2025, [Peer-reviewed]
  Scientific journal
• Design Principles of Nitrogen‐Doped Carbon Catalysts for Oxygen Reduction Reaction
  Kenji Hayashida; Bang Lu; Satoru Takakusagi; Junji Nakamura; Kotaro Takeyasu
  ChemElectroChem, 20 Jun. 2025, [Peer-reviewed], [Invited]
  Scientific journal
• 3D Precise Structure Determination of Single-Atom Cu Species on TiO2 Using Polarization-Dependent Total Reflection Fluorescent X-ray Absorption Fine Structure Empowered by Chemically Constrained Micro Reverse Monte Carlo and Density Functional Theory
  Yunli Lin; Kai Oshiro; Jun-ya Hasegawa; Satoru Takakusagi; Wang-Jae Chun; Masao Tabuchi; Kiyotaka Asakura
  The Journal of Physical Chemistry C, 21 Apr. 2025, [Peer-reviewed]
  Scientific journal
• Plasma-driven redox mechanism in the reverse water–gas shift reaction over Ni–In intermetallic catalysts
  Dae-Yeong Kim; Zhang Wenjun; Kaiyue Dong; Bang Lu; Duanxing Li; Satoru Takakusagi; Shinya Furukawa; Tomohiro Nozaki
  EES Catalysis, 2025, [Peer-reviewed], [Invited]
  Scientific journal
• Plasma-Derived Atomic Hydrogen Enables Eley–Rideal-Type CO2 Methanation at Low Temperatures
  Dae-Yeong Kim; Yoshinobu Inagaki; Tsukasa Yamakawa; Bang Lu; Yoshiaki Sato; Naoki Shirai; Shinya Furukawa; Hyun-Ha Kim; Satoru Takakusagi; Koichi Sasaki; Tomohiro Nozaki
  JACS Au, 18 Nov. 2024, [Peer-reviewed]
  English, Scientific journal
• In situ Study on Structure of a Diluted Pt/HOPG Model Catalyst System Prepared by the Two-phase Liquid Reduction Method Using a Novel BCLA/HERFD+BI-XAFS Method
  Kaiyue Dong; Bing Hu; Md Harun Al Rashid; Bang Lu; Keiko Miyabayashi; Kotaro Higashi; Tomoya Uruga; Yasuhiro Iwasawa; Daiki Kido; Satoru Takakusagi; Kiyotaka Asakura
  e-Journal of Surface Science and Nanotechnology, Surface Science Society Japan, 15 Feb. 2024, [Peer-reviewed]
  English, Scientific journal
• Bio-catalytic nanoparticle shaping for preparing mesoscopic assemblies of semiconductor quantum dots and organic molecules
  Rumana Akter; Nicholas Kirkwood; Samantha Zaman; Bang Lu; Tinci Wang; Satoru Takakusagi; Paul Mulvaney; Vasudevanpillai Biju; Yuta Takano
  Nanoscale Horizons, 9, 7, 1128, 1136, Royal Society of Chemistry (RSC), 2024, [Peer-reviewed]
  Scientific journal, Mesoscopic particles are promising materials in various fields owing to the combined or synergistic nature of quantum and bulk effects. We present a new approach for preparing a variety of dispersible mesoscopic particles using bio-enzymes.
• The Effect of Structural Change during the Activation Process on the Catalysis of In/SiO₂ Nonoxidative Coupling of Methane: An Operando XAFS Study
  Takahiro Wada; Upendar Kashaboina; Yuta Nishikawa; Yuki Wakisaka; Deling Bao; Satoru Takakusagi; Yuta Inami; Fumiya Kuriyama; Arnoldus Lambertus Dipu; Hitoshi Ogihara; Shoji Iguchi; Ichiro Yamanaka; Daiki Kido; Masao Kimura; Motohiro Uo; Kiyotaka Asakura
  The Journal of Physical Chemistry C, American Chemical Society (ACS), 12 Dec. 2023, [Peer-reviewed]
  English, Scientific journal
• Can amine ligands atomically disperse Cu atoms on TiO2(110)? : Cu deposition on TiO2(110) premodified with o-anthranilic acid
  Cho Rong Kim; Honoka Maeda; Bang Lu; Yuto Nakamura; Yunli Lin; Yuki Wakisaka; Daiki Kido; Kiyotaka Asakura; Satoru Takakusagi
  Chemistry Letters, Dec. 2023, [Peer-reviewed], [Last author, Corresponding author], ［Internationally co-authored］, [International Magazine]
  English, Scientific journal
• Dynamic Behavior of Intermediate Adsorbates to Control Activity and Product Selectivity in Heterogeneous Catalysis: Methanol Decomposition on Pt/TiO2(110)
  Can Liu; Bang Lu; Hiroko Ariga-Miwa; Shohei Ogura; Takahiro Ozawa; Katsuyuki Fukutani; Min Gao; Jun-ya Hasegawa; Ken-ichi Shimizu; Kiyotaka Asakura; Satoru Takakusagi
  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 145, 36, 19953, 19960, Aug. 2023, [Peer-reviewed], [Last author, Corresponding author]
  English, Scientific journal
• Stacking of a Cofacially Stacked Iron Phthalocyanine Dimer on Graphite Achieved High Catalytic CH₄ Oxidation Activity Comparable to That of pMMO
  Yasuyuki Yamada; Kentaro Morita; Takuya Sugiura; Yuka Toyoda; Nozomi Mihara; Masanari Nagasaka; Hikaru Takaya; Kiyohisa Tanaka; Takanori Koitaya; Naoki Nakatani; Hiroko Ariga-Miwa; Satoru Takakusagi; Yutaka Hitomi; Toshiji Kudo; Yuta Tsuji; Kazunari Yoshizawa; Kentaro Tanaka
  JACS Au, 3, 3, 823, 833, American Chemical Society (ACS), 10 Jan. 2023, [Peer-reviewed]
  English, Scientific journal
• Metastable Structure of Photoexcited WO₃ Determined by the Pump-probe Extended X-ray Absorption Fine Structure Spectroscopy and Constrained Thorough Search Analysis
  Daiki Kido; Yohei Uemura; Yuki Wakisaka; Akihiro Koide; Hiromitsu Uehara; Yasuhiro Niwa; Shunsuke Nozawa; Kohei Ichiyanagi; Ryo Fukaya; Shin-ichi Adachi; Tokushi Sato; Harry Jenkins; Toshihiko Yokoyama; Satoru Takakusagi; Jun-ya Hasegawa; Kiyotaka Asakura
  Chemistry Letters, 51, 11, 1083, 1086, The Chemical Society of Japan, 05 Nov. 2022, [Peer-reviewed]
  English, Scientific journal
• High-Entropy Intermetallics Serve Ultrastable Single-Atom Pt for Propane Dehydrogenation
  Yuki Nakaya; Eigo Hayashida; Hiroyuki Asakura; Satoru Takakusagi; Shunsaku Yasumura; Ken-ichi Shimizu; Shinya Furukawa
  Journal of the American Chemical Society, 144, 35, 15944, 15953, American Chemical Society (ACS), 07 Sep. 2022, [Peer-reviewed]
  English, Scientific journal
• Cooperative Catalysis of Vibrationally Excited CO₂ and Alloy Catalyst Breaks the Thermodynamic Equilibrium Limitation
  Dae-Yeong Kim; Hyungwon Ham; Xiaozhong Chen; Shuai Liu; Haoran Xu; Bang Lu; Shinya Furukawa; Hyun-Ha Kim; Satoru Takakusagi; Koichi Sasaki; Tomohiro Nozaki
  Journal of the American Chemical Society, 144, 31, 14140, 14149, 10 Aug. 2022, [Peer-reviewed]
  English, Scientific journal
• Abnormal Metal Bond Distances in PtAu Alloy Nanoparticles: In Situ Back-Illumination XAFS Investigations of the Structure of PtAu Nanoparticles on a Flat HOPG Substrate Prepared by Arc Plasma Deposition
  Bing Hu; Bapurao Bharate; Juan D. Jimenez; Jochen Lauterbach; Naoto Todoroki; Toshimasa Wadayama; Kotaro Higashi; Tomoya Uruga; Yasuhiro Iwasawa; Hiroko Ariga-Miwa; Satoru Takakusagi; Kiyotaka Asakura
  The Journal of Physical Chemistry C, 126, 2, 1006, 1016, American Chemical Society (ACS), 20 Jan. 2022, [Peer-reviewed]
  Scientific journal
• Analysis of Updated Literature Data up to 2019 on the Oxidative Coupling of Methane Using an Extrapolative Machine‐Learning Method to Identify Novel Catalysts
  Shinya Mine; Motoshi Takao; Taichi Yamaguchi; Takashi Toyao; Zen Maeno; S. M. A. Hakim Siddiki; Satoru Takakusagi; Ken‐ichi Shimizu; Ichigaku Takigawa
  ChemCatChem, 13, 16, 3636, 3655, Wiley, 20 Aug. 2021, [Peer-reviewed]
  Scientific journal
• Development of Operando Polarization-Dependent Total Reflection Fluorescence X-ray Absorption Fine Structure Technique for Three-Dimensional Structure Determination of Active Metal Species on a Model Catalyst Surface under Working Conditions
  Bang Lu; Daiki Kido; Yuta Sato; Haoran Xu; Wang-Jae Chun; Kiyotaka Asakura; Satoru Takakusagi
  The Journal of Physical Chemistry C, 125, 22, 12424, 12432, American Chemical Society ({ACS}), 10 Jun. 2021, [Peer-reviewed], [Invited], [Last author, Corresponding author]
  Scientific journal
• Close-Stacking of Iron-Oxo-Based Double-Decker Complex on Graphite Surface Achieved High Catalytic CH4 Oxidation Activity Comparable to that of Methane Monooxygenases
  Yasuyuki Yamada; Kentaro Morita; Takuya Sugiura; Yuka Toyoda; Nozomi Mihara; Masanari Nagasaka; Hikaru Takaya; Kiyohisa Tanaka; Takanori Koitaya; Naoki Nakatani; Hiroko Ariga-Miwa; Satoru Takakusagi; Yutaka Hitomi; Toshiji Kudo; Yuta Tsuji; Kazunari Yoshizawa; Kentaro Tanaka
  American Chemical Society (ACS), 04 Jun. 2021
  <div><div><div><p>Herein, we report that the close-stacking of a double-decker-type dinuclear iron phthalocyanine complex on a graphite surface is effective for achieving high methane oxidation activity, comparable to those of certain MMOs, in an aqueous solution. </p></div></div></div>
• Extracting the local electronic states of Pt polycrystalline films surface under electrochemical conditions using polarization-dependent total reflection fluorescence x-ray absorption near edge structure spectroscopy
  Yuki Wakisaka; Hiromitsu Uehara; Qiuyi Yuan; Daiki Kido; Takahiro Wada; Motohiro Uo; Yohei Uemura; Toshihiko Yokoyama; Yutaro Kamei; Seiichi Kuroda; Akihiro Ohira; Satoru Takakusagi; Kiyotaka Asakura
  Electronic Structure, 2, 4, 044003, 044003, IOP Publishing, 23 Jan. 2021, [Peer-reviewed], [Invited]
  Scientific journal
• Bent crystal Laue analyser combined with total reflection fluorescence X-ray absorption fine structure (BCLA + TRF-XAFS) and its application to surface studies
  Yuki Wakisaka; Bing Hu; Daiki Kido; Md. Harun Al Rashid; Wenhan Chen; Kaiyue Dong; Takahiro Wada; Bapurao Bharate; Quiyi Yuan; Shingo Mukai; Yasuo Takeichi; Satoru Takakusagi; Kiyotaka Asakura
  Journal of Synchrotron Radiation, 27, 6, 1618, 1625, International Union of Crystallography (IUCr), 01 Nov. 2020, [Peer-reviewed]
  Scientific journal, A bent crystal Laue analyser (BCLA) is an X-ray energy analyser used for fluorescence X-ray absorption fine-structure (XAFS) spectroscopy to separate the fluorescence X-ray emission line of a target atom from the elastic scattering X-rays and other fluorescence emission lines. Here, the feasibility of the BCLA for total reflection fluorescence XAFS (TRF-XAFS), which has a long X-ray footprint on the substrate surface owing to grazing incidence, was tested. The focal line of the BCLA was adjusted on the X-ray footprint and the XAFS signal for one monolayer of Pt deposited on a 60 nm Au film with high sensitivity was obtained. Although range-extended XAFS was expected by the rejection of Au fluorescence arising from the Au substrate, a small glitch was found in the Au L
  ₃ edge because of the sudden change of the complex refraction index of the Au substrate at the Au edge. This abnormal spectrum feature can be removed by reflectivity correction using Au foil absorption data. BCLA combined with TRF-XAFS spectroscopy (BCLA + TRF-XAFS) is a new technique for the in situ surface analysis of highly dispersed systems even in the presence of a liquid overlayer.
• Transfer hydrogenolysis of aromatic ethers promoted by the bimetallic Pd/Co catalyst
  F. Mauriello; H. Ariga-Miwa; E. Paone; R. Pietropaolo; S. Takakusagi; K. Asakura
  Catalysis Today, 357, 511, 517, Elsevier BV, Nov. 2020, [Peer-reviewed]
  English, Scientific journal
• Operando Observations of a Manganese Oxide Electrocatalyst for Water Oxidation Using Hard/Tender/Soft X-ray Absorption Spectroscopy
  Shun Tsunekawa; Futaba Yamamoto; Ke-Hsuan Wang; Masanari Nagasaka; Hayato Yuzawa; Satoru Takakusagi; Hiroshi Kondoh; Kiyotaka Asakura; Takeshi Kawai; Masaaki Yoshida
  The Journal of Physical Chemistry C, American Chemical Society (ACS), 20 Oct. 2020, [Peer-reviewed]
  English, Scientific journal
• Thorough Search Analysis of Extended X-ray Absorption Fine Structure Data for Complex Molecules and Nanomaterials Applications
  Daiki Kido; Yohei Uemura; Yuki Wakisaka; Hiroko Ariga-Miwa; Satoru Takakuasgi; Kiyotaka Asakura
  e-Journal of Surface Science and Nanotechnology, 18, 0, 249, 261, 01 Aug. 2020, [Peer-reviewed]
  English, Scientific journal
• Machine Learning for Catalysis Informatics: Recent Applications and Prospects
  Takashi Toyao; Zen Maeno; Satoru Takakusagi; Takashi Kamachi; Ichigaku Takigawa; Ken-ichi Shimizu
  ACS Catalysis, 10, 3, 2260, 2297, 07 Feb. 2020, [Peer-reviewed], [Invited]
  English, Scientific journal
• Erratum: Thorough search analysis of extended x-ray absorption fine structure data for complex molecules and nanomaterials applications (e-Journal of Surface Science and Nanotechnology (2020) 18 (249-261) DOI: 10.1380/ejssnt.2020.249)
  Daiki Kido; Yohei Uemura; Yuki Wakisaka; Hiroko Ariga-Miwa; Satoru Takakusagi; Kiyotaka Asakura
  e-Journal of Surface Science and Nanotechnology, 18, 268, The Japan Society of Vacuum and Surface Science, 2020
  English, Scientific journal
• Photoinduced anisotropic distortion as the electron trapping site of tungsten trioxide by ultrafast W L1-edge X-ray absorption spectroscopy with full potential multiple scattering calculations
  Akihiro Koide; Yohei Uemura; Daiki Kido; Yuki Wakisaka; Satoru Takakusagi; Bunsho Ohtani; Yasuhiro Niwa; Shunsuke Nozawa; Kohei Ichiyanagi; Ryo Fukaya; Shin-ichi Adachi; Tetsuo Katayama; Tadashi Togashi; Shigeki Owada; Makina Yabashi; Yusaku Yamamoto; Misaki Katayama; Keisuke Hatada; Toshihiko Yokoyama; Kiyotaka Asakura
  Physical Chemistry Chemical Physics, 22, 5, 2615, 2621, Royal Society of Chemistry (RSC), 2020, [Peer-reviewed], [International Magazine]
  English, Scientific journal,

  Ultrafast XANES spectra and full-potential multiple scattering reveal the anisotropic structure change of photoexcited WO₃.

• Statistical Analysis and Discovery of Heterogeneous Catalysts Based on Machine Learning from Diverse Published Data
  Suzuki Keisuke; Toyao Takashi; Maeno Zen; Takakusagi Satoru; Shimizu Ken-ichi; Takigawa Ichigaku
  CHEMCATCHEM, 11, 18, 4537, 4547, 19 Sep. 2019, [Peer-reviewed]
  English, Scientific journal
• Metamorphosis-like Transformation during Activation of In/SiO2 Catalyst for Non-oxidative Coupling of Methane: In Situ X-ray Absorption Fine Structure Analysis
  Kashaboina Upendar; Nishikawa Yuta; Wakisaka Yuki; Sirisit Natee; Nagamatsu Shin-ichi; Bao Deling; Ariga-Miwa Hiroko; Takakusagi Satoru; Inami Yuta; Kuriyama Fumiya; Dipu Arnoldus Lambertus; Ogihara Hitoshi; Iguchi Shoji; Yamanaka Ichiro; Wada Takahiro; Asakura Kiyotaka
  CHEMISTRY LETTERS, 48, 9, 1145, 1147, Sep. 2019, [Peer-reviewed]
  English, Scientific journal
• Linear Correlations between Adsorption Energies and HOMO Levels for the Adsorption of Small Molecules on TiO2 Surfaces
  Kamachi Takashi; Tatsumi Toshinobu; Toyao Takashi; Hinuma Yoyo; Maeno Zen; Takakusagi Satoru; Furukawa Shinya; Takigawa Ichigaku; Shimizu Ken-ichi
  JOURNAL OF PHYSICAL CHEMISTRY C, 123, 34, 20988, 20997, 29 Aug. 2019, [Peer-reviewed]
  English, Scientific journal
• Development of Surface Fluorescence X-Ray Absorption Fine Structure Spectroscopy Using a Laue-Type Monochromator
  Wakisaka Yuki; Kido Daiki; Uehara Hiromitsu; Yuan Qiuyi; Feiten Felix E; Mukai Shingo; Takakusagi Satoru; Uemura Yohei; Yokoyama Toshihiko; Wada Takahiro; Uo Motohiro; Sekizawa Oki; Uruga Tomoya; Iwasawa Yasuhiro; Asakura Kiyotaka
  CHEMICAL RECORD, 19, 7, 1157, 1165, Jul. 2019, [Peer-reviewed]
  Scientific journal
• Premodified Surface Method to Obtain Ultra-Highly Dispersed Metals and their 3D Structure Control on an Oxide Single-Crystal Surface
  Takakusagi Satoru; Iwasawa Yasuhiro; Asakura Kiyotaka
  CHEMICAL RECORD, 19, 7, 1244, 1255, Jul. 2019, [Peer-reviewed], [Invited]
  English, Scientific journal
• Structure-Activity Relation of In/SiO₂ and In/ZSM-5 Studied by QXAFS and Mass Spectroscopy
  Bao D.; Kido D.; Kashaboina U.; Miwa H.; Takakusagi S.; Nishikawa Y.; Inami Y.; Kuriyama F.; Iguchi S.; Yamanaka I.; Wada T.; Asakura K.
  Abstract book of Annual Meeting of the Japan Society of Vacuum and Surface Science, 2019, 1Ga01S, The Japan Society of Vacuum and Surface Science, 2019
  Japanese, Simultaneous measurement of Quick Scanning X-ray absorption fine structure (QXAFS) spectroscopy and Mass spectroscopy (MS) was applied to In catalysts for highly active methane conversion reaction during the activation processes and under the reaction conditions(1173 K, 1 bar CH₄ flow). The In catalysts deposited on SiO₂ and ZSM-5 were analyzed. We found the completely different behavior during the activation processes between two supports. In the In /SiO₂ we found the metallic In particles which showed dynamic structure change during the activation processes while In/ ZSM-5 were present in small In species which were reduced during the activation processes. We will discuss the structure -activity relation in the talk.
• Density Functional Theory Calculations of Oxygen Vacancy Formation and Subsequent Molecular Adsorption on Oxide Surfaces
  Hinuma Yoyo; Toyao Takashi; Kamachi Takashi; Maeno Zen; Takakusagi Satoru; Furukawa Shinya; Takigawa Ichigaku; Shimizu Ken-ichi
  JOURNAL OF PHYSICAL CHEMISTRY C, 122, 51, 29435, 29444, 27 Dec. 2018, [Peer-reviewed]
  English, Scientific journal
• Evidence for Multi-Atom Resonance X-ray Raman Spectroscopy-An in situ Low Z-element and Bond-specific X-ray Spectroscopy
  Sirisit N; Kido D; Wakisaka Y; Ariga-Miwa H; Takakusagi S; Asakura K; Sekizawa O; Sakata T; Uruga T; Iwasawa Y
  E-Journal of Surface Science and Nanotechnology, 16, 387, 390, 01 Sep. 2018, [Peer-reviewed]
  Scientific journal
• Reaction Stoichiometry and Mechanism of Pt Deposition via Surface Limited Redox Replacement of Copper UPD Layer on Au(111)
  Yuan Q; Wakisakai Y; Uemura Y; Wada T; Ariga-Miwa H; Takakusagi S; Asakura K; Brankovic S. R
  Journal of Physical Chemistry C, 122, 29, 16664, 16673, 26 Jul. 2018, [Peer-reviewed]
  English, Scientific journal
• Incorporation of Multinuclear Copper Active Sites into Nitrogen-Doped Graphene for Electrochemical Oxygen Reduction
  Kato Masaru; Muto Marika; Matsubara Naohiro; Uemura Yohei; Wakisaka Yuki; Yoneuchi Tsubasa; Matsumura Daiju; Ishihara Tomoko; Tokushima Takashi; Noro Shin-ichiro; Takakusagi Satoru; Asakura Kiyotaka; Yagi Ichizo
  ACS APPLIED ENERGY MATERIALS, 1, 5, 2358, 2364, May 2018, [Peer-reviewed]
  Scientific journal
• 分子修飾による酸化物単結晶表面での金属超高分散化とPTRF-XAFS 法による三次元構造解析
  高草木 達; 朝倉 清高
  表面と真空, 61, 5, 309, 314, May 2018, [Peer-reviewed], [Invited]
  Japanese, Scientific journal
• A demonstration of Pt L3-edge EXAFS free from Au L3-edge using log–spiral bent crystal laue analyzers
  Yuki Wakisaka; Daiki Kido; Hiromitsu Uehara; Qiuyi Yuan; Satoru Takakusagi; Yohei Uemura; Toshihiko Yokoyama; Takahiro Wada; Motohiro Uo; Tomohiro Sakata; Oki Sekizawa; Tomoya Uruga; Yasuhiro Iwasawa; Kiyotaka Asakura
  Catalysts, 8, 5, 01 May 2018, [Peer-reviewed]
  English, Scientific journal
• Toward Effective Utilization of Methane: Machine Learning Prediction of Adsorption Energies on Metal Alloys
  Takashi Toyao; Keisuke Suzuki; Shoma Kikuchi; Satoru Takakusagi; Ken-Ichi Shimizu; Ichigaku Takigawa
  Journal of Physical Chemistry C, 122, 15, 8315, 8326, 19 Apr. 2018, [Peer-reviewed]
  English, Scientific journal
• Phosphorous Diffusion Through Ni2P - Low Energy Diffusion Path and Its Unique Local Structure
  José Contreras-Mora; Hiroko Ariga-Miwa; Satoru Takakusagi; Christopher T. Williams; Kiyotaka Asakura
  Journal of Physical Chemistry C, 122, 11, 6318, 6322, 22 Mar. 2018, [Peer-reviewed]
  English, Scientific journal
• Smooth epitaxial copper film on sapphire surface suitable for high quality graphene growth
  Tao Ma; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura
  Thin Solid Films, 646, 12, 16, 31 Jan. 2018, [Peer-reviewed]
  English, Scientific journal
• Approach to highly sensitive XAFS by means of bent crystal laue Analyzers
  ASAKURA Kiyotaka
  J.Sur.Sci.Soc.Jpn, 38, 8, 378, 383, The Surface Science Society of Japan, Sep. 2017, [Peer-reviewed], [Invited]
  Japanese, Scientific journal,

  A log-spirally bent crystal Laue analyzer has been investigated and developed for highly sensitive in situ surface X-ray absorption fine structure (XAFS) measurement. Both calculations and experiments were conducted to obtain its intensity distributions on the different positions of the analyzer. A home-made log-spirally bent crystal Laue analyzer was made and evaluated. It was revealed that higher XAFS signals were obtained with the home-made analyzer than with the commercial one.

• Controlling the inhomogeneity of solid catalysts at the mesoscopic scale
  Hua Huang; Takahiro Wada; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura; Yasuhiro Iwasawa
  CHEMICAL PHYSICS LETTERS, 683, 18, 21, Sep. 2017, [Peer-reviewed]
  English, Scientific journal
• Polarization-dependent Total Reflection Fluorescence X-ray Absorption Fine Structure (PTRF-XAFS) Studies on the Structure of a Pt Monolayer on Au(111) Prepared by the Surface-limited Redox Replacement Reaction
  Qiuyi Yuan; Satoru Takakusagi; Yuki Wakisaka; Yohei Uemura; Takahiro Wada; Hiroko Ariga; Kiyotaka Asakura
  CHEMISTRY LETTERS, 46, 8, 1250, 1253, Aug. 2017, [Peer-reviewed]
  English, Scientific journal
• Capturing local structure modulations of photoexcited BiVO4 by ultrafast transient XAFS.
  Yohei Uemura; Daiki Kido; Akihiro Koide; Yuki Wakisaka; Yasuhiro Niwa; Shunsuke Nozawa; Kohei Ichiyanagi; Ryo Fukaya; Shin-Ichi Adachi; Tetsuo Katayama; Tadashi Togashi; Shigeki Owada; Makina Yabashi; Keisuke Hatada; Akihide Iwase; Akihiko Kudo; Satoru Takakusagi; Toshihiko Yokoyama; Kiyotaka Asakura
  Chemical communications (Cambridge, England), 53, 53, 7314, 7317, 29 Jun. 2017, [Peer-reviewed], [International Magazine]
  English, Scientific journal
• An Origin for Lattice Expansion in PVP-Protected Small Pd Metal Nanoparticles
  Tadashi Ohba; Hitoshi Kubo; Yusuke Ohshima; Yuichi Makita; Noriaki Nakamura; Hiromitsu Uehara; Satoru Takakusagi; Kiyotaka Asakura
  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 90, 6, 720, 727, Jun. 2017, [Peer-reviewed]
  English, Scientific journal
• 組成情報と要素特徴量の統合に基づく化学反応量の予測
  鈴木 慶介; 瀧川 一学; 清水 研一; 高草木 達
  人工知能学会全国大会論文集, 2017, 4J13, 4J13, 一般社団法人 人工知能学会, 2017
  Japanese,

  メタンの酸化カップリング反応技術は,天然ガスを有効利用する手法の一つとして注目されており,機械学習を用いて反応量を予測する既存研究も存在する.本稿では既存研究に対して新たに,学習に用いるデータの形式(組成情報)と,特徴間の類似度を考慮したモデリングを行った結果を報告する.

• Various Active Metal Species Incorporated within Molecular Layers on Si(111) Electrodes for Hydrogen Evolution and CO2 Reduction Reactions
  Takuya Masuda; Yu Sun; Hitoshi Fukumitsu; Hiromitsu Uehara; Satoru Takakusagi; Wang-Jae Chun; Toshihiro Kondo; Kiyotaka Asakura; Kohei Uosaki
  JOURNAL OF PHYSICAL CHEMISTRY C, 120, 29, 16200, 16210, Jul. 2016, [Peer-reviewed]
  English, Scientific journal
• A New Indicator for Single Metal Dispersion on a TiO2(110) Surface Premodified with a Mercapto Compound
  Satoru Takakusagi; Akitoshi Kunimoto; Natee Sirisit; Hiromitsu Uehara; Tadashi Ohba; Yohei Uemuara; Takahiro Wada; Hiroko Ariga; Wang-Jae Chun; Yasuhiro Iwasawa; Kiyotaka Asakura
  JOURNAL OF PHYSICAL CHEMISTRY C, 120, 29, 15785, 15791, Jul. 2016, [Peer-reviewed]
  English, Scientific journal
• In Situ X-ray Absorption Fine Structure Analysis of PtCo, PtCu, and PtNi Alloy Electrocatalysts: The Correlation of Enhanced Oxygen Reduction Reaction Activity and Structure
  Takahiro Kaito; Hiroyuki Tanaka; Hisashi Mitsumoto; Seiho Sugawara; Kazuhiko Shinohara; Hiroko Ariga; Hiromitsu Uehara; Satoru Takakusagi; Kiyotaka Asakura
  JOURNAL OF PHYSICAL CHEMISTRY C, 120, 21, 11519, 11527, Jun. 2016, [Peer-reviewed]
  English, Scientific journal
• Structural Relationship between CoO6 Cluster and Phosphate Species in a Cobalt-Phosphate Water Oxidation Catalyst Investigated by Co and P K-edge XAFS
  Masaaki Yoshida; Takehiro Mineo; Yosuke Mitsutomi; Futaba Yamamoto; Hirokatsu Kurosu; Satoru Takakusagi; Kiyotaka Asakura; Hiroshi Kondoh
  CHEMISTRY LETTERS, 45, 3, 277, 279, Mar. 2016, [Peer-reviewed]
  English, Scientific journal
• Portable ultrahigh-vacuum sample storage system for polarization-dependent total-reflection fluorescence x-ray absorption fine structure spectroscopy
  Yoshihide Watanabe; Yusaku F. Nishimura; Ryo Suzuki; Hiromitsu Uehara; Tomoyuki Nimura; Atsushi Beniya; Noritake Isomura; Kiyotaka Asakura; Satoru Takakusagi
  JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 34, 2, Mar. 2016, [Peer-reviewed]
  English, Scientific journal
• Surface XAFS using Bent Crystal Laue Monochromator and its Application to Fuel Cells.
  Wakisaka Yuki; Kido Daiki; Uehara Hiromitsu; Uemura Yohei; takakusagi satoru; wada takahiro; Yuan Qiuyi; Asakura Kiyotaka
  Abstract of annual meeting of the Surface Science of Japan, 36, 106, 106, The Surface Science Society of Japan, 2016
  Japanese, 広い立体角をもつ分光器Bent Crystal Laue Monochromator（ＢＣLA）は、高感度な蛍光XAFSを可能とし、表面への応用が期待されてきたが、未だに十分な感度が達成されていない。われわれはこの５年間BCLAの改良に取り組んできた。 本講演ではその取り組みを総括し、現状（表面感度について）を述べ、今後の展開について議論したい。特に、HOPGを基板としたモデル燃料電池Pt触媒へのこの手法の応用についても議論する。
• Machine-learning prediction of the d-band center for metals and bimetals
  Ichigaku Takigawa; Ken-ichi Shimizu; Koji Tsuda; Satoru Takakusagi
  RSC ADVANCES, 6, 58, 52587, 52595, 2016, [Peer-reviewed]
  English, Scientific journal
• Dynamics of Photoelectrons and Structural Changes of Tungsten Trioxide Observed by Femtosecond Transient XAFS
  Yohei Uemura; Daiki Kido; Yuki Wakisaka; Hiromitsu Uehara; Tadashi Ohba; Yasuhiro Niwa; Shunsuke Nozawa; Tokushi Sato; Kohei Ichiyanagi; Ryo Fukaya; Shin-ichi Adachi; Tetsuo Katayama; Tadashi Togashi; Sigeki Owada; Kanade Ogawa; Makina Yabashi; Keisuke Hatada; Satoru Takakusagi; Toshihiko Yokoyama; Bunsho Ohtani; Kiyotaka Asakura
  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55, 4, 1364, 1367, Jan. 2016, [Peer-reviewed]
  English, Scientific journal
• Investigation of the Cleanliness of Transferred Graphene: The First Step toward Its Application as a Window Material for Electron Microscopy and Spectroscopy
  Tao Ma; Kotaro Miyazaki; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura
  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 88, 8, 1029, 1035, Aug. 2015, [Peer-reviewed]
  English, Scientific journal
• EXAFS Studies of Pd Nanoparticles: Direct Evidence for Unusual Pd-Pd Bond Elongation
  Tadashi Ohba; Hitoshi Kubo; Yusuke Ohshima; Yuichi Makita; Noriaki Nakamura; Hiromitsu Uehara; Satoru Takakusagi; Kiyotaka Asakura
  CHEMISTRY LETTERS, 44, 6, 803, 805, Jun. 2015, [Peer-reviewed]
  English, Scientific journal
• Exploring the catalytic properties of supported palladium catalysts in the transfer hydrogenolysis of glycerol
  F. Mauriello; H. Ariga; M. G. Musolino; R. Pietropaolo; S. Takakusagi; K. Asakura
  APPLIED CATALYSIS B-ENVIRONMENTAL, 166, 121, 131, May 2015, [Peer-reviewed]
  English, Scientific journal
• A high-temperature in situ cell with a large solid angle for fluorescence X-ray absorption fine structure measurement
  Naoyoshi Murata; Makoto Kobayashi; Yukari Okada; Takuya Suzuki; Hiroaki Nitani; Yasuhiro Niwa; Hitoshi Abe; Takahiro Wada; Shingo Mukai; Hiromitsu Uehara; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura
  REVIEW OF SCIENTIFIC INSTRUMENTS, 86, 3, 034102, Mar. 2015, [Peer-reviewed]
  English, Scientific journal
• In situ XAFS spectroscopy of a carbon-supported dinuclear copper electrocatalyst for oxygen reduction
  Kato Masaru; Kimijima Ken'ichi; Shibata Mari; Notsu Hideo; Ogino Kazuya; Inokuma Kiyoshi; Ohta Narumi; Oyaizu Nobuhisa; Uehara Hiromitsu; Ohba Tadashi; Uemura Yohei; Takakusagi Satoru; Asakura Kiyotaka; Yagi Ichizo
  Abstract of annual meeting of the Surface Science of Japan, 35, 357, 357, The Surface Science Society of Japan, 2015
  固体高分子形燃料電池の酸素還元電極触媒としては主に白金系合金が用いられているが、埋蔵量やコスト面に問題を抱えているため、安価かつ高活性な非白金系酸素還元電極触媒の開発が近年盛んに行われている。本発表では、銅系酸素還元電極触媒の中で特に高い触媒活性を示す銅二核錯体触媒に着目し、その高い触媒活性を示す理由を解明するためにin situ XAFS測定を行ったので、その結果に関して報告する。
• Bond distance expansion in Pd nanoclusters
  Asakura Kiyotaka; Ohba Tadashi; Uehara Hiromitsu; Takakusaki Satoru
  Abstract of annual meeting of the Surface Science of Japan, 35, 324, 324, The Surface Science Society of Japan, 2015
  Pdナノ粒子は脱硝触媒、部分水素化触媒等で広く用いられる。Pdナノ粒子において，ナノ粒子化すると格子が拡張するという奇妙な現象が報告されてきた．本研究では，この格子拡張をEXAFSで直接調べ，Pd-Pd結合の伸長に起因することを確認し，また水素吸蔵に伴う現象でないことをしめした．この奇妙なナノ粒子に関する現象について，可能性を議論したい．
• Deprotonation of a dinuclear copper complex of 3,5-diamino-1,2,4-triazole for high oxygen reduction activity
  Masaru Kato; Ken'ichi Kimijima; Mari Shibata; Hideo Notsu; Kazuya Ogino; Kiyoshi Inokuma; Narumi Ohta; Hiromitsu Uehara; Yohei Uemura; Nobuhisa Oyaizu; Tadashi Ohba; Satoru Takakusagi; Kiyotaka Asakura; Ichizo Yagi
  PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 17, 14, 8638, 8641, 2015, [Peer-reviewed]
  English, Scientific journal
• In situ real-time study on potential induced structure change at Au(111) and Au(100) single crystal electrode/sulfuric acid solution interfaces by surface x-ray scattering
  Toshihiro Kondo; Joerg Zegenhagen; Satoru Takakusagi; Kohei Uosaki
  SURFACE SCIENCE, 631, 96, 104, Jan. 2015, [Peer-reviewed]
  English, Scientific journal
• Deprotonation of a dinuclear copper complex of 3,5-diamino-1,2,4-triazole for high oxygen reduction activity
  Masaru Kato; Ken'ichi Kimijima; Mari Shibata; Hideo Notsu; Kazuya Ogino; Kiyoshi Inokuma; Narumi Ohta; Hiromitsu Uehara; Yohei Uemura; Nobuhisa Oyaizu; Tadashi Ohba; Satoru Takakusagi; Kiyotaka Asakura; Ichizo Yagi
  PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 17, 14, 8638, 8641, 2015, [Peer-reviewed]
  English, Scientific journal
• Electrodeposition Study on a Single-crystal Titanium Dioxide Electrode: Platinum on a Niobium-doped Titanium Dioxide(110) Electrode
  Satoru Takakusagi; Takafumi Ogawa; Hiromitsu Uehara; Hiroko Ariga; Ken-ichi Shimizu; Kiyotaka Asakura
  CHEMISTRY LETTERS, 43, 11, 1797, 1799, Nov. 2014, [Peer-reviewed]
  English, Scientific journal
• Photoexcited Hole Transfer to a MnOx Cocatalyst on a SrTiO3 Photoelectrode during Oxygen Evolution Studied by In Situ X-ray Absorption Spectroscopy
  Masaaki Yoshida; Takumi Yomogida; Takehiro Mineo; Kiyofumi Nitta; Kazuo Kato; Takuya Masuda; Hiroaki Nitani; Hitoshi Abe; Satoru Takakusagi; Tomoya Uruga; Kiyotaka Asakura; Kohei Uosaki; Hiroshi Kondoh
  JOURNAL OF PHYSICAL CHEMISTRY C, 118, 42, 24302, 24309, Oct. 2014, [Peer-reviewed]
  English, Scientific journal
• Reactivity of Ni2P (101b0) surface for NO evaluated by STM.
  K. Kono; H. Ariga; S. Takakusagi; S. Otani; K. Asakura
  Hyomen Kagaku, 35, 8, 415, 419, Aug. 2014, [Peer-reviewed], [Invited]
  Japanese, Scientific journal
• A new spectroelectrochemical cell for in situ measurement of Pt and Au K-edge X-ray absorption fine structure
  Takahiro Kaito; Hisashi Mitsumoto; Seiho Sugawara; Kazuhiko Shinohara; Hiromitsu Uehara; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura
  REVIEW OF SCIENTIFIC INSTRUMENTS, 85, 8, 084104, Aug. 2014, [Peer-reviewed]
  English, Scientific journal
• In Situ Picosecond XAFS Study of an Excited State of Tungsten Oxide
  Yohei Uemura; Hiromitsu Uehara; Yasuhiro Niwa; Shunsuke Nozawa; Tokushi Sato; Shinichi Adachi; Bunsho Ohtani; Satoru Takakusagi; Kiyotaka Asakura
  CHEMISTRY LETTERS, 43, 7, 977, 979, Jul. 2014, [Peer-reviewed]
  English, Scientific journal
• Micro Reverse Monte Carlo Approach to EXAFS Analysis. e-Journal of Surface Science and Nanotechnology
  K. Fujikawa; H. Ariga; S. Takakusagi; H. Uehara; T. Ohba; K. Asakura
  e-Journal of Surface Science and Nanotechnology, 12, 322, 329, The Surface Science Society of Japan, Jun. 2014, [Peer-reviewed]
  English, Scientific journal, We have developed a new Reverse Monte Carlo code, called the micro Reverse Monte Carlo (m-RMC), which is applicable to structure analysis of nanomaterials and surface species. In the m-RMC, Reverse Monte Carlo is applied to an ensemble of replica files, each of which contains one molecule or one small cluster, because the Extended X-ray Absorption Fine Structure (EXAFS) is sensitive to short-range structures and has negligible interaction between molecules or clusters. We apply the m-RMC to face-centered cubic metals (Cu, Pd, and Pt) and discuss the advantages, validation, and problems of the m-RMC. The bond distance and some cumulant coefficients can be determined from the EXAFS using m-RMC. Some 50-100 replica files are sufficient to reproduce the EXAFS oscillations and radial distributions. The bond distance can be determined, including the asymmetric distributions,by m-RMC. We also apply m-RMC to α-MoO₃ and Au clusters. The m-RMC analysis of MoO₃ shows that three radial distribution peaks appear corresponding to three types of Mo–O bonds. The m-RMC analysis of Au cluster indicates the presence of Au₅₅ cuboctahedral structure with Au-Au distance at 0.288 nm. We obtain a 3 D image of Au₅₅ nanocluster from the unified file. The m-RMC method can be applied to the analysis of the EXAFS for chemical systems with appropriate care. [DOI: 10.1380/ejssnt.2014.322]
• K-Edge X-ray Absorption Fine Structure Analysis of Pt/Au Core-Shell Electrocatalyst: Evidence for Short Pt-Pt Distance
  Takahiro Kaito; Hisashi Mitsumoto; Seiho Sugawara; Kazuhiko Shinohara; Hiromitsu Uehara; Hiroko Ariga; Satoru Takakusagi; Yoshikiyo Hatakeyama; Keiko Nishikawa; Kiyotaka Asakura
  JOURNAL OF PHYSICAL CHEMISTRY C, 118, 16, 8481, 8490, Apr. 2014, [Peer-reviewed]
  English, Scientific journal
• MRMCによるナノ粒子のXAFS構造解析
  藤川 圭介; 高草木 達; 朝倉 清高
  表面科学学術講演会要旨集, 34, 34, 34, 公益社団法人 日本表面科学会, 2014
  MRMC(Micro Reverse Monte Carlo〕法は，非対称分布を考慮して，XAFSを解析できる手法である．この手法を用いて，AuおよびIナノ粒子の構造解析を行った． 解が一意的であるかということに関して問題はあるものの，熱振動の分布や動径分布関数を求めることができ，ナノ粒子の構造解析に有力な手法となる．
• 酸化物単結晶上金属ナノ構造の反応特性と制御
  高草木達; 朝倉清高
  触媒誌, 56, 306, 2014, [Peer-reviewed], [Invited]
  Japanese, Scientific journal
• Hydrodeoxygenation of fatty acids and triglycerides by Pt-loaded Nb2O5 catalysts
  Kenichi Kon; Wataru Onodera; Satoru Takakusagi; Ken-ichi Shimizu
  CATALYSIS SCIENCE & TECHNOLOGY, 4, 10, 3705, 3712, 2014, [Peer-reviewed]
  English, Scientific journal
• In situ back-side illumination fluorescence XAFS (BI-FXAFS) studies on platinum nanoparticles deposited on a HOPG surface as a model fuel cell: a new approach to the Pt-HOPG electrode/electrolyte interface
  Hiromitsu Uehara; Yohei Uemura; Takafumi Ogawa; Kentaro Kono; Ryoichi Ueno; Yasuhiro Niwa; Hiroaki Nitani; Hitoshi Abe; Satoru Takakusagi; Masaharu Nomura; Yasuhiro Iwasawa; Kiyotaka Asakura
  PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 16, 27, 13748, 13754, 2014, [Peer-reviewed]
  English, Scientific journal
• Polarization-Dependent Total-Reflection Fluorescence X-ray Absorption Fine Structure for 3D Structural Determination and Surface Fine Tuning
  Satoru Takakusagi; Wang-Jae Chun; Hiromitsu Uehara; Kiyotaka Asakura; Yasuhiro Iwasawa
  TOPICS IN CATALYSIS, 56, 15-17, 1477, 1487, Nov. 2013, [Peer-reviewed]
  English, Scientific journal
• Anisotropic growth of a nickel trimer formed on a highly-stepped TiO2(110) surface
  Hiromitsu Uehara; Muhammad Haneef Bin Hanaffi; Yuichiro Koike; Keisuke Fujikawa; Shushi Suzuki; Hiroko Ariga; Satoru Takakusagi; Wang-Jae Chun; Yasuhiro Iwasawa; Kiyotaka Asakura
  CHEMICAL PHYSICS LETTERS, 570, 64, 69, May 2013, [Peer-reviewed]
  English, Scientific journal
• Au Clusters on TiO2(110) (1 x 1) and (1 x 2) Surfaces Examined by Polarization-Dependent Total Reflection Fluorescence XAFS
  Wang-Jae Chun; Kotaro Miyazaki; Naoki Watanabe; Yuichiro Koike; Satoru Takakusagi; Keisuke Fujikawa; Masaharu Nomura; Yasuhiro Iwasawa; Kiyotaka Asakura
  JOURNAL OF PHYSICAL CHEMISTRY C, 117, 1, 252, 257, Jan. 2013, [Peer-reviewed]
  English, Scientific journal
• Density function theoretical investigation on the Ni3PP structure and the hydrogen adsorption property of the Ni2P(0001) surface
  Hiroko Ariga; Mayumi Kawashima; Satoru Takakusagi; Kiyotaka Asakura
  Chemistry Letters, 42, 12, 1481, 1483, 2013, [Peer-reviewed]
  English, Scientific journal
• Silver-modulated SiO2-supported copper catalysts for selective hydrogenation of dimethyl oxalate to ethylene glycol
  Ying Huang; Hiroko Ariga; Xinlei Zheng; Xinping Duan; Satoru Takakusagi; Kiyotaka Asakura; Youzhu Yuan
  Journal of Catalysis, 307, 74, 83, 2013, [Peer-reviewed]
  English, Scientific journal
• Fine tuning and orientation control of surface Cu complexes on TiO2(110) premodified with mercapto compounds: the effect of different mercapto group positions
  Satoru Takakusagi; Hirotaka Nojima; Hiroko Ariga; Hiromitsu Uehara; Kotaro Miyazaki; Wang-Jae Chun; Yasuhiro Iwasawa; Kiyotaka Asakura
  PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 15, 33, 14080, 14088, 2013, [Peer-reviewed]
  English, Scientific journal
• In situ observation of carrier transfer in the Mn-oxide/Nb:SrTiO3 photoelectrode by X-ray absorption spectroscopy
  Masaaki Yoshida; Takumi Yomogida; Takehiro Mineo; Kiyofumi Nitta; Kazuo Kato; Takuya Masuda; Hiroaki Nitani; Hitoshi Abe; Satoru Takakusagi; Tomoya Uruga; Kiyotaka Asakura; Kohei Uosaki; Hiroshi Kondoh
  CHEMICAL COMMUNICATIONS, 49, 71, 7848, 7850, 2013, [Peer-reviewed]
  English, Scientific journal
• Preparation and structure of a single Au atom on the TiO2(110) surface: control of the Au-metal oxide surface interaction
  Kiyotaka Asakura; Satoru Takakusagi; Hiroko Ariga; Wang-Jae Chun; Shushi Suzuki; Yuichiro Koike; Hiromitsu Uehara; Kotaro Miyazaki; Yasuhiro Iwasawa
  FARADAY DISCUSSIONS, 162, 165, 177, 2013, [Peer-reviewed]
  English, Scientific journal
• Operando Observation of Ni2P Structural Changes during Catalytic Reaction: Effect of H2S Pretreatment
  Takahiro Wada; Kyoko K. Bando; S. Ted Oyama; Takeshi Miyamoto; Satoru Takakusagi; Kiyotaka Asakura
  CHEMISTRY LETTERS, 41, 10, 1238, 1240, Oct. 2012, [Peer-reviewed]
  English, Scientific journal
• In Situ Pt K-Edge XAFS Study on Pt/Au Nanoclusters for Fuel Cell Catalysts
  Takahiro Kaito; Hisashi Mitsumoto; Seiho Sugawara; Kazuhiko Shinohara; Hiromitsu Uehara; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura
  ECS Meeting Abstracts, MA2012-02, 13, 1651, 1651, The Electrochemical Society, 04 Jun. 2012
  Scientific journal, Abstract not Available.
• Operando QEXAFS studies of Ni2P during thiophene hydrodesulfurization: direct observation of Ni-S bond formation under reaction conditions
  Takahiro Wada; Kyoko K. Bando; Takeshi Miyamoto; Satoru Takakusagi; S. Ted Oyama; Kiyotaka Asakura
  JOURNAL OF SYNCHROTRON RADIATION, 19, 205, 209, Mar. 2012, [Peer-reviewed]
  English, Scientific journal
• Combined in situ QXAFS and FTIR analysis of a Ni phosphide catalyst under hydrodesulfurization conditions
  Kyoko K. Bando; Takahiro Wada; Takeshi Miyamoto; Kotaro Miyazaki; Satoru Takakusagi; Yuichiro Koike; Yasuhiro Inada; Masaharu Nomura; Aritomo Yamaguchi; Travis Gott; S. Ted Oyama; Kiyotaka Asakura
  JOURNAL OF CATALYSIS, 286, 165, 171, Feb. 2012, [Peer-reviewed]
  English, Scientific journal
• Remarkable enhancement of Cu catalyst activity in hydrogenation of dimethyl oxalate to ethylene glycol using gold
  Ya-nan Wang; Xinping Duan; Jianwei Zheng; Haiqiang Lin; Youzhu Yuan; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura
  CATALYSIS SCIENCE & TECHNOLOGY, 2, 8, 1637, 1639, 2012, [Peer-reviewed]
  English, Scientific journal
• Molecular Catalysts Confined on and Within Molecular Layers Formed on a Si(111) Surface with Direct Si-C Bonds
  Takuya Masuda; Hitoshi Fukumitsu; Satoru Takakusagi; Wang-Jae Chun; Toshihiro Kondo; Kiyotaka Asakura; Kohei Uosaki
  ADVANCED MATERIALS, 24, 2, 268, 272, Jan. 2012, [Peer-reviewed]
  English, Scientific journal
• Precise control of the structures and their reaction properties on alpha-Sb2O4/VSbO4 Catalyst
  Hua Huang; Haraguchi Yui; Wada Takahiro; Ariga Hiroko; Takakusagi Satoru; Asakura Kiyotaka
  Abstract of annual meeting of the Surface Science of Japan, 32, 113, 113, The Surface Science Society of Japan, 2012
  電子線リソグラフィー法を用いてSb2O4の線幅や間隔を変化させた不均一規制αーSb2O4/VSbO4 触媒を調製し，プロピレンの部分酸化反応を調べた．アクロレンへの選択性がSb2O4のミクロレベルの構造により変化することを見出した．これをリモートコントロール機構で説明した．
• Preparation of well-defined inhomogeneous α-Sb2O4/VSbO4 catalyst by electron lithography and their catalytic activities
  Y. Haraguchi; T. Wada; Y. Ominami; N. Matsudaira; H. Ariga; S. Takakusagi; K. Asakura
  Hyomen Kagaku, 33, 8, 426, 430, The Surface Science Society of Japan, 2012, [Peer-reviewed]
  Japanese, Scientific journal, Well-defined inhomogeneous α-Sb₂O₄/VSbO₄ catalysts were prepared using an electron lithography method to investigate the effects of µm order structures on an atomic scale catalytic reaction. X-ray photoelectron spectroscopy (XPS) and laser microscopy revealed that µm order structures were successfully developed on a Si substrate where an α-Sb₂O₄ micro line with a controlled width was deposited on VSbO₄. We carried out a propene partial oxidation reaction on this surface and found that the acrolein formation rate was significantly influenced by the width and interval of the α-Sb₂O₄ µm line. The results of this study indicate the possibility of controlling the surface reaction by the inhomogeneity of the surface structure in the µm order.
• Carbon Nanotube-Supported RuFe Bimetallic Nanoparticles as Efficient and Robust Catalysts for Aqueous-Phase Selective Hydrogenolysis of Glycerol to Glycols
  Bodong Li; Juan Wang; Youzhu Yuan; Hiroko Ariga; Satoru Takakusagi; Kiyotaka Asakura
  ACS CATALYSIS, 1, 11, 1521, 1528, Nov. 2011, [Peer-reviewed]
  English, Scientific journal
• Angle resolved total reflection fluorescence XAFS and its application to Au clusters on TiO2(110) (1 x 1)
  Wang-Jae Chun; Kotaro Miyazaki; Naoki Watanabe; Yuichiro Koike; Satoru Takakusagi; Keisuke Fujikawa; Masaharu Nomura; Kiyotaka Asakura
  JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 119, 1395, 890, 893, Nov. 2011, [Peer-reviewed]
  English, Scientific journal
• Dynamical LEED analysis of Ni2P (0001)-1 x 1: Evidence for P-covered surface structure
  Alvin B. Hernandez; Hiroko Ariga; Satoru Takakusagi; Kumiko Kinoshita; Shushi Suzuki; Shigeki Otani; S. Ted Oyama; Kiyotaka Asakura
  CHEMICAL PHYSICS LETTERS, 513, 1-3, 48, 52, Sep. 2011, [Peer-reviewed]
  English, Scientific journal
• Construction of multilayers of bare and Pd modified gold nanoclusters and their electrocatalytic properties for oxygen reduction
  Motoko Harada; Hidenori Noguchi; Nikolas Zanetakis; Satoru Takakusagi; Wenbo Song; Kohei Uosaki
  SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 12, 4, 44606, Aug. 2011, [Peer-reviewed]
  English, Scientific journal
• In Situ Electrochemical, Electrochemical Quartz Crystal Microbalance, Scanning Tunneling Microscopy, and Surface X-ray Scattering Studies on Ag/AgCl Reaction at the Underpotentially Deposited Ag Bilayer on the Au(111) Electrode Surface
  Kohei Uosaki; Jun Morita; Tomoko Katsuzaki; Satoru Takakusagi; Kazuhisa Tamura; Masamitu Takahasi; Jun'ichiro Mizuki; Toshihiro Kondo
  JOURNAL OF PHYSICAL CHEMISTRY C, 115, 25, 12471, 12482, Jun. 2011, [Peer-reviewed]
  English, Scientific journal
• Resonance surface X-ray scattering technique to determine the structure of electrodeposited Pt ultrathin layers on Au(111) surface
  Toshihiro Kondo; Masayo Shibata; Naoko Hayashi; Hitoshi Fukumitsu; Takuya Masuda; Satoru Takakusagi; Kohei Uosaki
  ELECTROCHIMICA ACTA, 55, 27, 8302, 8306, Nov. 2010, [Peer-reviewed]
  English, Scientific journal
• First Direct Visualization of Spillover Species Emitted from Pt Nanoparticles
  Satoru Takakusagi; Ken-ichi Fukui; Ryugo Tero; Kiyotaka Asakura; Yasuhiro Iwasawa
  LANGMUIR, 26, 21, 16392, 16396, Nov. 2010, [Peer-reviewed]
  English, Scientific journal
• 表面反応プロセスの原子・分子レベル可視化と機構解明
  高草木 達
  化学と工業, 63, 9, 741, 741, Sep. 2010
  Japanese, Research society
• STM studies on the reconstruction of the Ni2P (10(1)over-bar0) surface
  Donghui Guo; Yuta Nakagawa; Hiroko Ariga; Shushi Suzuki; Kumiko Kinoshita; Takeshi Miyamoto; Satoru Takakusagi; Kiyotaka Asakura; Shigeki Otani; S. Ted Oyama
  SURFACE SCIENCE, 604, 17-18, 1347, 1352, Aug. 2010, [Peer-reviewed]
  English, Scientific journal
• In situ FTIR and XANES studies of thiophene hydrodesulfurization on Ni2P/MCM-41
  S. Ted Oyama; Travis Gott; Kiyotaka Asakura; Satoru Takakusagi; Kotaro Miyazaki; Yuichiro Koike; Kyoko K. Bando
  JOURNAL OF CATALYSIS, 268, 2, 209, 222, Dec. 2009, [Peer-reviewed]
  English, Scientific journal
• Electrodeposition of Ag and Pd on a reconstructed Au(111) electrode surface studied by in situ scanning tunneling microscopy
  Satoru Takakusagi; Ken Kitamura; Kohei Uosaki
  ELECTROCHIMICA ACTA, 54, 22, 5137, 5141, Sep. 2009, [Peer-reviewed]
  English, Scientific journal
• Formation and Structure of Perfluorosulfonated Ionomer Thin Film on a Graphite Surface
  Takuya Masuda; Hideo Naohara; Satoru Takakusagi; Pankaj R. Singh; Kohei Uosaki
  CHEMISTRY LETTERS, 38, 9, 884, 885, Sep. 2009, [Peer-reviewed]
  English, Scientific journal
• Partial stripping of Ag atoms from silver bilayer on a Au(111) surface accompanied with the reductive desorption of hexanethiol SAM
  Toshihiro Kondo; Kazuhisa Tamura; Satoru Takakusagi; Ken Kitamura; Masamitu Takahasi; Jun'ichiro Mizuki; Kohei Uosaki
  JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 13, 7, 1141, 1145, Jul. 2009, [Peer-reviewed]
  English, Scientific journal
• Stability of underpotentially deposited Ag layers on a Au(111) surface studied by surface X-ray scattering
  Toshihiro Kondo; Satoru Takakusagi; Kohei Uosaki
  ELECTROCHEMISTRY COMMUNICATIONS, 11, 4, 804, 807, Apr. 2009, [Peer-reviewed]
  English, Scientific journal
• Adsorption structure of acetic anhydride on a TiO2(110) surface observed by scanning tunneling microscopy
  Kumiko Kinoshita; Shushi Suzuki; Wang-Jae Chun; Satoru Takakusagi; Kiyotaka Asakura
  SURFACE SCIENCE, 603, 3, 552, 557, Feb. 2009, [Peer-reviewed]
  English, Scientific journal
• Ambient Pressure(AP) XPSによる触媒表面のin situ評価
  高草木 達
  触媒, 51, 5, 367, 367, 2009
  Japanese, Research society
• Hydrophilicity transition of the clean rutile TiO(2) (110) surface
  Daniel C. Hennessy; Michael Pierce; Kee-Chul Chang; Satoru Takakusagi; Hoydoo You; Kohei Uosaki
  ELECTROCHIMICA ACTA, 53, 21, 6173, 6177, Sep. 2008, [Peer-reviewed]
  English, Scientific journal
• Spontaneous rapid growth of triruthenium cluster multilayers on gold surface. Cyclic voltammetric in situ monitoring and AFM characterization
  Takayuki Michi; Masaaki Abe; Satoru Takakusagi; Masako Kato; Kohei Uosaki; Yoichi Sasaki
  CHEMISTRY LETTERS, 37, 6, 576, 577, Jun. 2008, [Peer-reviewed]
  English, Scientific journal
• In situ real-time monitoring of electrochemical Ag deposition on a reconstructed Au(111) surface studied by scanning tunneling microscopy
  Satoru Takakusagi; Ken Kitamura; Kohei Uosaki
  JOURNAL OF PHYSICAL CHEMISTRY C, 112, 8, 3073, 3077, Feb. 2008, [Peer-reviewed]
  English, Scientific journal
• Effect of Electrode Potential on Ag Electrodeposition on a Reconstructed Au(111) Electrode Surface
  TAKAKUSAGI Satoru; KITAMURA Ken; UOSAKI Kohei
  Journal of the Surface Science Society of Japan, 29, 10, 621, 628, 日本表面科学会, 2008
  Japanese, Research society
• Self-assembled monolayers of compact phosphanes with alkanethiolate pendant groups: Remarkable reusability and substrate selectivity in Rh catalysis
  Kenji Hara; Ryuto Akiyama; Satoru Takakusagi; Kohei Uosaki; Toru Yoshino; Hiroyuki Kagi; Masaya Sawamura
  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 47, 30, 5627, 5630, 2008, [Peer-reviewed]
  English, Scientific journal
• Construction of self-assembled monolayer terminated with N-heterocyclic carbene-rhodium(I) complex moiety
  Kenji Hara; Keiji Iwahashi; Satoru Takakusagi; Kohei Uosaki; Masaya Sawamura
  SURFACE SCIENCE, 601, 22, 5127, 5132, Nov. 2007, [Peer-reviewed]
  English, Scientific journal
• Structure of Au(111) and Au(100) single-crystal electrode surfaces at various potentials in sulfuric acid solution determined by in situ surface X-ray scattering
  Toshihiro Kondo; Jun Morita; Kazuya Hanaoka; Satoru Takakusagi; Kazuhisa Tamura; Masamitu Takahasi; Jun'ichiro Mizuki; Kohei Uosaki
  JOURNAL OF PHYSICAL CHEMISTRY C, 111, 35, 13197, 13204, Sep. 2007, [Peer-reviewed]
  English, Scientific journal
• Photoanodic formation of an organic monolayer on a hydrogen-terminated Si(111) surface via Si-C covalent bond using a Grignard reagent and its application for one-step monolayer-patterning
  Takakusagi Satoru; Miyasaka Toyomitsu; Uosaki Kohei
  Journal of Electroanalytical Chemistry, 599, 2, 344, 348, 15 Jan. 2007, [Peer-reviewed]
  English, Scientific journal
• Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols
  Kenji Hara; Shinobu Tayama; Hidekazu Kano; Takuya Masuda; Satoru Takakusagi; Toshihiro Kondo; Kohei Uosaki; Masaya Sawamura
  CHEMICAL COMMUNICATIONS, 41, 4280, 4282, 2007, [Peer-reviewed]
  English, Scientific journal
• Photoanodic formation of an organic monolayer on a hydrogen-terminated Si(111) surface via Si-C covalent bond using a Grignard reagent and its application for one-step monolayer-patterning
  Satoru Takakusagi; Toyomitsu Miyasaka; Kohei Uosaki
  JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 599, 2, 344, 348, Jan. 2007, [Peer-reviewed]
  English, Scientific journal
• Photopatterning of an organic monolayer formed on a Si single crystal surface via Si-C covalent bond by UV irradiation in an inert atmosphere
  Satoru Takakusagi; Kohei Uosaki
  JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 45, 11, 8961, 8966, Nov. 2006, [Peer-reviewed]
  English, Scientific journal
• Cyclic diaminocarbene-rhodium(I) complex tethered to disulfide: Synthesis and application to gold surface modification
  Kenji Hara; Keiji Iwahashi; Yoshikazu Kanamori; Satoshi Naito; Satoru Takakusagi; Kohei Uosaki; Masaya Sawamura
  CHEMISTRY LETTERS, 35, 8, 870, 871, Aug. 2006, [Peer-reviewed]
  English, Scientific journal
• Unfolding, aggregation, and amyloid formation by the tetramerization domain from mutant p53 associated with lung cancer
  Y Higashimoto; Y Asanomi; S Takakusagi; MS Lewis; K Uosaki; Durell, SR; CW Anderson; E Appella; K Sakaguchi
  BIOCHEMISTRY, 45, 6, 1608, 1619, Feb. 2006, [Peer-reviewed]
  English, Scientific journal
• 自己組織化単分子層を用いた単一分子の電気伝導測定
  高草木達
  ぶんせき, 9, 451, 2006
  Japanese, Scientific journal
• Mechanism of Amyloid-Like Fibrillar Aggregation of Mutant Peptide of p53 Tetramerization Domain
  ASANOMI Yuya; TAKAKUSAGI Satoru; CHUMAN Yoshiro; KAYA Shunji; IMAGAWA Toshiaki; UOSAKI Kohei; SAKAGUCHI Kazuyasu
  Peptide Science, 2004, 0, 313, 316, Mar. 2005
  English, International conference proceedings
• Surface crystallographic orientation dependence of anodic oxide formation on gold single crystalline electrodes
  Yagi, I; T Awatani; T Kondo; K Hanaoka; J Morita; S Takakusagi; K Tamura; M Takahasi; J Mizuki; K Uosaki
  SURFACE OXIDE FILMS, 2003, 25, 143, 150, 2004, [Peer-reviewed]
  English, International conference proceedings
• Dynamic aspects and associated structures of TiO2(110) and CeO2(111) surfaces relevant to oxide catalyses
  K Fukui; S Takakusagi; R Tero; M Aizawa; Y Namai; Y Iwasawa
  PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 5, 24, 5349, 5359, Dec. 2003
  English, Scientific journal
• Self-limiting growth of pt nanoparticles from MeCpPtMe3 adsorbed on TiO2(110) studied by scanning tunneling microscopy
  S Takakusagi; K Fukui; R Tero; F Nariyuki; Y Iwasawa
  PHYSICAL REVIEW LETTERS, 91, 6, 066102, Aug. 2003, [Peer-reviewed]
  English, Scientific journal
• STM study on structures of two kinds of wide strands formed on TiO2(110)
  S Takakusagi; K Fukui; F Nariyuki; Y Iwasawa
  SURFACE SCIENCE, 523, 1-2, L41, L46, Jan. 2003
  English, Scientific journal
• Development of an X-ray photoemission electron microscopy system with multi-probes, and its application to surface imaging at static and dynamic states
  S Takakusagi; M Kato; Y Sakai; K Fukui; K Asakura; Y Iwasawa
  JOURNAL OF MICROSCOPY-OXFORD, 200, 3, 240, 250, Dec. 2000, [Peer-reviewed]
  English, Scientific journal
• X-ray photoemission electron microscopy (XPEEM) as a new promising tool for the real-time chemical imaging of active surfaces
  Y Yamaguchi; S Takakusagi; Y Sakai; M Kato; K Asakura; Y Iwasawa
  JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 141, 1-3, 129, 137, May 1999, [Peer-reviewed]
  English, Scientific journal
• Development of a Multi Surface Imaging System for LEEM, PEEM, SEEM, AEEM and XPEEM
  YAMAGUCHI Yoshitaka; TAKAKUSAGI Satoru; KATO Makoto; SAKAI Yuji; ASAKURA Kiyotaka; IWASAWA Yasuhiro
  Journal of the Surface Science Society of Japan, 19, 8, 498, 502, 日本表面科学会, 10 Aug. 1998
  Japanese
• 表面の反応を観る「光電子顕微鏡の新たな展開」
  山口良隆; 朝倉清高; 高草木達; 岩澤康裕
  表面, 35, 12, 621, 628, 広信社, 1997
  Japanese

• Dependence of phenol formation concentration using plasma-irradiated water and benzene on 2-propanol concentration
  林ロバート勇斗; 稲垣慶修; 白井直機; 高草木達; 佐々木浩一, 応用物理学会春季学術講演会講演予稿集(CD-ROM), 71st, 2024
• Dependence of synthesized phenol concentration on working gas species in benzene-phenol conversion using atmospheric-pressure plasma-liquid interaction
  林ロバート勇斗; 稲垣慶修; 高草木達; 佐々木浩一; 白井直機, 応用物理学会秋季学術講演会講演予稿集(CD-ROM), 85th, 2024
• アークプラズム法でHOPG上に作成したPtAuナノ粒子の異常なAu-Au結合短縮について
  朝倉清高; HU Bing; 轟直人; 和田山智正; 東晃太朗; 宇留賀朋哉; 宇留賀朋哉; 岩澤康裕; 三輪(有賀)寛子; 高草木達, 触媒討論会講演予稿集(CD-ROM), 129th, 2022
• Frontier Orbital Theory of Molecular Adsorption on TiO₂ Surface
  蒲池高志; 蒲池高志; 濱本信次; 巽俊暢; 高尾基史; 鳥屋尾隆; 鳥屋尾隆; 日沼洋陽; 前野禅; 高草木達; 古川森也; 古川森也; 瀧川一学; 清水研一; 清水研一, 日本化学会春季年会講演予稿集(Web), 102nd, 2022
• Thorough search analysis of extended x-ray absorption fine structure data for complex molecules and nanomaterials applications
  城戸大貴; 上村洋平; 脇坂祐輝; 三輪(有賀)寛子; 高草木達; 朝倉清高, 日本表面真空学会学術講演会要旨集(Web), 2021, 2021
• Frontier Orbital Theory of Molecular Adsorption on TiO₂ Surface
  濱本信次; 巽俊暢; 高尾基史; 鳥屋尾隆; 鳥屋尾隆; 日沼洋陽; 前野禅; 高草木達; 古川森也; 古川森也; 瀧川一学; 清水研一; 清水研一; 蒲池高志; 蒲池高志, 分子科学討論会講演プログラム&要旨(Web), 15th, 2021
• 外挿的探索を可能にする機械学習モデルを用いた新規触媒探索
  向山拓実; 峯真也; 鳥屋尾隆; 鳥屋尾隆; 前野禅; 高草木達; 瀧川一学; 瀧川一学; 清水研一; 清水研一, 触媒討論会討論会A予稿集(CD-ROM), 128th, 2021
• Layered Structure in Arc-Plasma Deposited PtAu/HOPG Electrocatalyst Evidenced by BCLA+BI-PEXAFS
  HU B.; BHARATE B.; JIMENEZ J. D.; DONG K.; LU B.; ARIGA-MIWA H.; TAKAKUSAGI S.; ASAKURA K.; TODOROKI N.; WADAYAMA T., 日本放射光学会年会・放射光科学合同シンポジウム(Web), 33rd, 2020
• Dynamic Behavior and Decomposition Property of Methanol Adsorbed on a Pt/TiO₂(110) Model Catalyst Surface
  LIU Can; TAKAKUSAGI Satoru; OGURA Shohei; ARIGA-MIWA Hiroko; FUKUTANI Katsuyuki; ASAKURA Kiyotaka, 日本化学会春季年会講演予稿集(CD-ROM), 100th, 2020
• In situ XAFS Study on In/SiO₂ Catalyst for Non-Oxidative Coupling of Methane Dynamic Structure Change during the Activation Process
  KASHABOINA Upendar; NISHIKAWA Yuta; WAKISAKA Yuki; SIRISIT Natee; BAO Deling; ARIGA-MIWA Hiroko; TAKAKUSAGI Satoru; INAMI Yuta; KURIYAMA Fumiya; DIPU Arnoldus Lambertus; OGIHARA Hitoshi; IGUCHI Shoji; YAMANAKA Ichiro; WADA Takahiro; ASAKURA Kiyotaka, KEK Progress Report (Web), 2020-6, 2020
• 高温反応条件下でのXAFSー反応解析の可能性
  KASHABOINA Upendar; 鮑徳玲; 城戸大貴; 三輪(有賀)寛子; 高草木達; 脇坂祐輝; 西川祐太; 井波雄太; 栗山史也; ARNOLDUSLAMBERTUS Dipu; 荻原仁志; 井口翔之; 山中一郎; 和田敬広; 朝倉清高, 触媒討論会討論会A予稿集(CD-ROM), 126th, 2020
• Pt/TiO₂(110)表面上メタノール分解反応における吸着種の動的挙動と反応特性の解明
  高草木達; 劉燦; 三輪寛子; 小倉正平; 福谷克之; 朝倉清高, 触媒討論会討論会A予稿集(CD-ROM), 126th, 2020
• 機械学習を用いたメタン酸化カップリング反応の文献データ解析と新規触媒予測
  鳥屋尾隆; 鳥屋尾隆; 高尾基史; 前野禅; 高草木達; 瀧川一学; 瀧川一学; 清水研一; 清水研一, 触媒討論会講演予稿集(CD-ROM), 125th, 2020
• In脱水素メタンカップリング触媒の高温オペランドXAFS観察
  KASHABOINA Upendar; 鮑徳玲; 城戸大貴; 三輪(有賀)寛子; 高草木達; 西川祐太; 井波雄太; 栗山史也; DIPU Arnoldus Lambertus; 荻原仁志; 井口翔之; 山中一郎; 和田敬広; 朝倉清高, 触媒 = Catalysts & Catalysis, 2020
• Statistical Analysis and Discovery of Heterogeneous Catalysts Based on Machine Learning from Diverse Published Data
  Keisuke Suzuki; Takashi Toyao; Zen Maeno; Satoru Takakusagi; Ken-ichi Shimizu; Ichigaku Takigawa, CHEMCATCHEM, Sep. 2019
  English, Technical report
• Adsorption, diffusion and desorption processes of methanol on a Pt/TiO₂(110) model catalyst surface studied by STM and TPD
  Can Liu; Takakusagi Satoru; Ogura Shohei; Ariga-Miwa Hiroko; Fukutani Katsuyuki; Asakura Kiyotaka, 日本表面真空学会学術講演会要旨集(Web), 2019, 2019
• In/SiO₂ Catalyst for Non-oxidative Coupling of Methane Improved by Activation in CH₄ flow: In situ XAFS Study
  KASHABOINA Upendar; NISHIKAWA Yuta; WAKISAKA Yuki; SIRISIT Natee; BAO Deling; ARIGA-MIWA Hiroko; TAKAKUSAGI Satoru; INAMI Yuta; KURIYAMA Fumiya; DIPU Arnoldus Lambertus; OGIHARA Hitoshi; IGUCHI Shoji; YAMANAKA Ichiro; WADA Takahiro; ASAKURA Kiyotaka, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019
• 表面制限還元置換法(SLRR)によるAu(111)表面のPtの化学種の構造
  朝倉清高; YUAN Qiuyi; 脇坂祐輝; 上村洋平; 和田敬広; 三輪(有賀)寛子; 高草木達, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019
• 酸化物表面の酸素脱着エネルギーと小分子吸着エネルギーの密度汎関数法計算
  日沼洋陽; 日沼洋陽; 鳥屋尾隆; 鳥屋尾隆; 蒲池高志; 蒲池高志; 前野禅; 高草木達; 古川森也; 古川森也; 瀧川一学; 瀧川一学; 清水研一; 清水研一, 日本金属学会講演概要(CD-ROM), 164th, 2019
• 酸化物表面における酸素脱着の密度汎関数法計算
  日沼洋陽; 日沼洋陽; 鳥屋尾隆; 鳥屋尾隆; 蒲池高志; 蒲池高志; 前野禅; 高草木達; 古川森也; 古川森也; 瀧川一学; 瀧川一学; 清水研一; 清水研一, 触媒討論会討論会A予稿集(CD-ROM), 124th, 2019
• 機械学習によるメタン酸化カップリング反応に有効な触媒探索
  高尾基史; 鳥屋尾隆; 鳥屋尾隆; 前野禅; 高草木達; 瀧川一学; 瀧川一学; 清水研一; 清水研一, ケモインフォマティクス討論会予稿集(Web), 42nd, 2019
• Machine learning predictions of factors affecting the activity of heterogeneous metal catalysts
  Ichigaku Takigawa; Ken-ichi Shimizu; Koji Tsuda; Satoru Takakusagi, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 255, Mar. 2018
  English, Summary international conference
• Ni₂P(1010)表面の水素発生反応特性
  金野弘; 三輪寛子; YUAN Qiuyi; 高草木達; 朝倉清高, 日本表面真空学会学術講演会講演要旨集, 2018, 2018
• Revisit of Pt Deposition via Surface Limited Redox Replacement of Copper UPD Layer on Au(111) by EXAFS
  YUAN Qiuyi; WAKISAKA Yuki; UEMURA Yohei; WADA Takahiro; ARIGA-MIWA Hiroko; TAKAKUSAGI Satoru; ASAKURA Kiyotaka; BRANKOVIC Stanko R, KEK Progress Report (Web), 2018-7, 2018
• Multiatom Resonance X-ray(MARX)Raman Spectroscopyと界面分子反応
  NATEE Sirisit; 城戸大貴; 脇坂祐輝; 三輪(有賀)寛子; 高草木達; 朝倉清高; 坂田智裕; 関澤央輝; 宇留賀朋哉; 岩澤康裕, 触媒討論会討論会A予稿集, 122nd, 2018
• メタンの有効利用を目的とした機械学習による吸着エネルギー予測
  鳥屋尾隆; 鳥屋尾隆; 高草木達; 瀧川一学; 清水研一; 清水研一, 触媒討論会討論会A予稿集, 122nd, 2018
• Prediction of factors that control chemical reactivity of metal surfaces by machine learning
  Takigawa Ichigaku; Shimizu Ken-ichi; Tsuda Koji; Takakusagi Satoru, Abstract of annual meeting of the Surface Science of Japan, 37th, 0, 24, 47, 17 Aug. 2017
  金属のdバンド中心は、様々な触媒反応の活性序列を示す良い指標である。dバンド中心は第一原理計算によって求めるが、種々の金属やバイメタル系に対して網羅的に計算を行うのは、計算・時間コストが高くなる。そこで本研究では，金属の密度，イオン化エネルギー等の入手容易な物理量を記述子とし、種々の金属・合金のdバンド中心の機械学習による高速予測を検討し，その結果、妥当な精度で予測できることを実証した。, 公益社団法人 日本表面科学会, Japanese
• Back-illuminated XAFS measurement with low concentration by means of BCLA
  脇坂祐輝; 上原広充; 城戸大貴; 大場惟史; YUAN Qiuyi; 向井慎吾; 岩崎裕也; 高草木達; 上村洋平; 横山利彦; 和田敬広; 宇尾基弘; 関澤央輝; 宇留賀朋哉; 宇留賀朋哉; 岩澤康裕; 朝倉清高, 量子ビームサイエンスフェスタ(Web), 2016, 2017
• 多核銅錯体埋込型カーボン電極触媒の酸素還元活性と活性中心構造の解明
  加藤優; 加藤優; 松原直啓; 武藤鞠佳; 上村洋平; 脇坂祐輝; 松村大樹; 高草木達; 朝倉清高; 八木一三; 八木一三, 電気化学会大会講演要旨集(CD-ROM), 84th, 2017
• SACLAによる光触媒の超高速時間分解XAFS研究
  上村洋平; 脇坂祐輝; 城戸大貴; 高草木達; 朝倉清高; 丹羽尉博, 日本結晶学会誌, 59, 1, 2017
• Polarization-dependent total reflection in-situ XAFS of polycrystalline Pt thin film surface
  Wakisaka Yuki; Takakusagi Satoru; Asakura Kiyotaka; Uehara Hiromitsu; Yuan Qiuyi; Wada Takahiro; Uemura Yohei; Kido Daiki; Kamei Yutaro; Kuroda Seiichi; Ohira Akihiro, Abstract of annual meeting of the Surface Science of Japan, 37, 0, 2017
  燃料電池電極触媒に用いられるPtナノ粒子表面の電子状態・局所構造を電気化学条件下で三次元的に理解することは触媒反応・劣化機構の解明において重要である。そこでモデル試料としてPt多結晶薄膜に対して、偏光依存全反射蛍光XAFS分光法を用いて、異なる電位間におけるPt表面の状態変化について面内・面直でとらえることを試み、XANES理論計算との比較を行った。, 公益社団法人 日本表面科学会, Japanese
• X線自由電子レーザーを用いたポンプ・プローブXAFSによるWO₃光触媒励起過程の研究
  城戸大貴; 上村洋平; 脇坂祐輝; 丹羽尉博; 野澤俊介; 足立伸一; 片山哲夫; 矢橋牧名; 有賀寛子; 高草木達; 横山利彦; 大谷文章; 朝倉清高, 日本化学会春季年会講演予稿集(CD-ROM), 96th, ROMBUNNO.2B1‐07, 10 Mar. 2016
  Japanese
• ピコ秒及びフェムト秒XAFSによる酸化タングステンの光励起状態のダイナミクス観測
  上村洋平; 城戸大貴; 脇坂祐輝; 上原広充; 大場惟史; 丹羽尉博; 野澤俊介; 佐藤篤志; 一柳光平; 深谷亮; 足立伸一; 片山哲夫; 矢橋牧名; 高草木達; 大谷文章; 横山利彦; 朝倉清高, 日本化学会講演予稿集, 95th, 2, 490, 11 Mar. 2015
  Japanese
• Au(111)電極表面上に形成されたPd UPD層の偏光全反射蛍光XAFS構造解析
  MASUDA TAKUYA; MASUDA TAKUYA; MASUDA TAKUYA; UEHARA HIROMITSU; TAKAKUSAGI SATORU; CHUN WANG-JAE; KONDO TOSHIHIRO; ASAKURA KIYOTAKA; UOSAKI KOHEI; UOSAKI KOHEI, 電気化学会大会講演要旨集(CD-ROM), 82nd, ROMBUNNO.1E02, 09 Mar. 2015
  Japanese
• PTRF-XAFS法によるTiO₂(110)上Pt_nクラスタの構造解析
  西村友作; 上原広充; 磯村典武; 鈴木涼; 紅谷篤史; 朝倉清高; 高草木達; 渡邊佳英, 物構研サイエンスフェスタ要旨集, 3rd, 2015
• ポンプ‐プローブXAFS法による光触媒WO3の光励起状態の観測
  上村洋平; 脇坂祐輝; 城戸大貴; 上原広充; 大場惟史; 丹羽尉博; 野澤俊介; 佐藤篤志; 深谷亮; 一柳光平; 足立伸一; 大谷文章; 高草木達; 横山利彦; 朝倉清高, 物構研サイエンスフェスタ要旨集, 3rd, 44, 2015
  Japanese
• メルカプト安息香酸修飾TiO₂(110)によるNi単原子種の安定化と偏光全反射蛍光XAFS法による構造解析
  國本明駿; 高草木達; 有賀寛子; 上原広充; 大場惟史; 朝倉清高, 表面科学学術講演会講演要旨集, 34th, 86, 171, 06 Nov. 2014
  金属と強く相互作用するメルカプト基を有するメルカプト安息香酸でTiO₂(110)表面を修飾し、その後AuまたはCuを蒸着することで、TiO₂(110)表面上でのAu、Cuの単原子分散が可能である。本研究では、金属として新たにNiの単原子分散を試みた。Ni蒸着後の構造を偏光全反射蛍光XAFS法により評価し、単原子分散していることを見出した。また、単原子分散したNiの構造モデルについても考察した。, 公益社団法人 日本表面科学会, Japanese
• Combined in situ XAFS and FTIR study of Ni phosphide catalysts
  Kyoko K. Bando; Takahiro Wada; Satoru Takakusagi; Shigeo Ted Oyama; Kiyotaka Asakura, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 248, Aug. 2014
  English, Summary international conference
• 酸素プラズマ照射による酸化物単結晶上に担持した有機保護金クラスターからのナノ粒子形成
  高草木達; 木工淳; IMRAN BIN ABDUL; R. M. Nabil; 上原広充; 有賀寛子; 朝倉清高, 日本化学会講演予稿集, 94th, 3, 760, 12 Mar. 2014
  Japanese
• 酸化物担持有機保護金クラスターへの酸素プラズマ照射によるナノ粒子形成と粒径制御
  高草木達; 木工淳; MOHAMAD NABIL Imran; bin A. R; 上原広充; 有賀寛子; 朝倉清高, 触媒討論会講演予稿集, 113th, 255, 10 Mar. 2014
  Japanese
• Structures and propeties of Ni2P single crystal surface: A surface science approach to a new class of hydrodesulfurization catalyst
  Kiyotaka Asakura; Hiroko Ariga; Satoru Takakusagi; S. Ted Oyama, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 247, Mar. 2014
  English, Summary international conference
• In‐situ電気化学XAFS法を用いた半導体光電極から酸素生成助触媒への励起ホール移動の観測
  蓬田匠; 吉田真明; 峯尾岳大; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, 日本放射光学会年会・放射光科学合同シンポジウム予稿集, 27th, 116, 11 Jan. 2014
  Japanese
• 担持貴金属ナノ粒子のXAFSによる局所構造
  大場惟史; 上原広充; 有賀寛子; 高草木達; 牧田勇一; 大嶋優輔; 久保仁志; 中村紀章; 朝倉清高, 物構研サイエンスフェスタ要旨集, 2013, 53, 2014
  Japanese
• ポンプ‐プローブXAFS法による酸化タングステンの光励起状態の観測
  上村洋平; 上原広充; 丹羽尉博; 野澤俊介; 佐藤篤志; 足立伸一; 大谷文章; 高草木達; 朝倉清高, 物構研サイエンスフェスタ要旨集, 2013, 54, 2014
  Japanese
• XAFS測定のための超高真空下試料搬送システム
  西村友作; 渡邊佳英; 二村智行; 千葉昭雄; 森貴広; 上原広充; 高草木達; 朝倉清高, 物構研サイエンスフェスタ要旨集, 2013, 85, 2014
  Japanese
• 水素化触媒Ni₂P(0001)表面上の水素吸着
  有賀寛子; 宮本剛史; ALVIN Hernandez; 高草木達; 大谷茂樹; 大山Ted; 朝倉清高, 表面科学学術講演会講演要旨集, 33rd, 125, 26 Nov. 2013
  Japanese
• 光電子顕微鏡を用いた大気圧条件下での金薄膜の観察
  北山冬馬; 朝倉清高; 高草木達; 有賀寛子; 上原広充; 宮崎晃太朗; 津野勝重; 工藤雅嗣; 平岩端, 表面科学学術講演会講演要旨集, 33rd, 180, 26 Nov. 2013
  Japanese
• Ni2P(1010)単結晶表面の酸化過程のSTM観察
  鴻野健太郎; 有賀寛子; 高草木達; 上原広充; 大谷茂樹; OYAMA S.Ted; 朝倉清高, 表面科学学術講演会講演要旨集, 33rd, 40, 26 Nov. 2013
  Japanese
• 酸素プラズマ照射による酸化物上金ナノ粒子のサイズ及び化学状態変化の観察
  木工淳; 高草木達; ラフマン モハマド・ナビル; イムラン・ビン・アブドル; 上原広充; 有賀寛子; 朝倉清高, 表面科学学術講演会講演要旨集, 33rd, 31, 26 Nov. 2013
  Japanese
• 電気化学的手法を用いたPt/TiO₂(110)モデル触媒表面の調製
  高草木達; 小川貴史; 上原広充; 有賀寛子; 朝倉清高, 触媒討論会討論会A予稿集, 112th, 413, 11 Sep. 2013
  Japanese
• In‐situ X線吸収分光法による水分解光電極上の酸化マンガン助触媒への電荷移動の観測
  吉田真明; 蓬田匠; 峯尾岳大; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, 電気化学会大会講演要旨集, 80th, 45, 29 Mar. 2013
  Japanese
• 半導体光電極から酸化マンガン助触媒への励起ホールの移動と光電極活性との相関
  蓬田匠; 吉田真明; 峯尾岳大; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, 電気化学会大会講演要旨集, 80th, 46, 29 Mar. 2013
  Japanese
• 金属結合能を有する機能性分子を共存させた酸化物表面上での単原子金属種の調製
  高草木達; 野島大孝; 宮崎晃太郎; 有賀寛子; 上原広充; 田旺帝; 岩澤康裕; 朝倉清高, 触媒討論会講演予稿集, 111th, 228, 11 Mar. 2013
  Japanese
• In‐situ X線吸収分光法による水分解用光電極上の酸素生成助触媒への励起キャリア移動の観測
  吉田真明; 蓬田匠; 峯尾岳大; 前田彩綾; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, 触媒討論会講演予稿集, 111th, 41, 43, 11 Mar. 2013
  Japanese
• STMによるNi₂P(1010)単結晶表面の表面構造と反応性に関する研究
  鴻野健太郎; 有賀寛子; 高草木達; 大谷茂樹; OYAMA S. Ted; 朝倉清高, 日本化学会講演予稿集, 93rd, 2, 460, 08 Mar. 2013
  Japanese
• メルカプト基を有する機能性分子で修飾した酸化物表面でのAu単原子種の調製
  高草木達; 野島大孝; 宮崎晃太郎; 有賀寛子; 上原広充; CHUN Wang‐Jae; 岩澤康裕; 朝倉清高, 日本化学会講演予稿集, 93rd, 3, 757, 08 Mar. 2013
  Japanese
• 水素化脱硫触媒Ni₂P(0001)表面上での水素挙動
  有賀寛子; 宮本剛史; HERNANDEZ Alvin; 木下久美子; 高草木達; 大谷茂樹; 大山Ted; 朝倉清高, 日本化学会講演予稿集, 93rd, 2, 504, 08 Mar. 2013
  Japanese
• Preparation and three-dimensional structure analysis of atomically dispersed metal species on an oxide surface premodified with functional organic molecules
  高草木 達; 朝倉 清高, 表面, 51, 3, 115, 127, Mar. 2013
  広信社, Japanese
• Study on cobalt phosphate cocatalyst (Co-Pi) on photoelectrode for overall water splitting by XAFS
  Mineo Takehiro; Uruga Tomoya; Asakura Kiyotaka; Uosaki Kohei; Kondoh Hiroshi; Yoshida Masaaki; Yomogida Takumi; Nitta Kiyofumi; Kato Kazuo; Masuda Takuya; Nitani Hiroaki; Abe Hitoshi; Takakusagi Satoru, Abstract of annual meeting of the Surface Science of Japan, 33, 0, 2013
  水分解用半導体光電極上のリン酸コバルト(Co-Pi)酸素生成助触媒について、Co-K端およびP-K端、K-K端XAFS測定を行い、光電極反応下でのCo-Pi助触媒の構造と化学状態の変化を調べた。これまでCo-Pi中のコバルト種は3価以上であることが知られていたが、本研究では反応初期過程においてコバルト2価種が観測され、光電極反応の進行とともにCo-Piの化学状態が変化することが分かった。, 公益社団法人 日本表面科学会
• Observation of photoexcited carrier transfer to MnOx/SrTiO3 photocatalyst by In-Situ XAFS
  Yoshida Masaaki; Takakusagi Satoru; Uruga Tomoya; Asakura Kiyotaka; Uosaki Kohei; Kondoh Hiroshi; Gon Narihiro; Yomogida Takumi; Mineo Takehiro; Nitta Kiyohumi; Kato Kazuo; Masuda Takuya; Nitani Hiroaki; Abe Hitoshi, Abstract of annual meeting of the Surface Science of Japan, 33, 0, 2013
  In-Situ X線吸収分光法により、光触媒反応中における酸化マンガン助触媒の価数変化を測定し、励起キャリアの移動を観測することを目的として実験を行った。酸化マンガンを担持したチタン酸ストロンチウム光触媒に硝酸銀水溶液中で紫外光を照射すると、酸化マンガン助触媒が3価から4価に酸化され、光触媒上から酸化マンガン助触媒へ励起ホールが移動する様子を観測できることを見出した。, 公益社団法人 日本表面科学会
• In‐situ X線吸収分光法を利用した水分解用光電極上の酸化マンガン助触媒への励起キャリア移動の観測
  吉田真明; 蓬田匠; 峯尾岳大; 前田彩綾; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, 表面科学学術講演会講演要旨集, 32nd, 32, 32, 20 Nov. 2012
  XAFS法により水分解光電極上の酸化マンガン助触媒の電子状態を測定し、光電極上から助触媒への励起キャリアの移動を観測した。光照射下で酸化マンガンのMn-K端XAFSを測定すると、3価から4価に酸化される様子が観測され、酸化マンガン上に励起ホールが移動することが示された。一方、酸化マンガンの電着量が少ないサンプルでは2価に還元される様子が観測され、一部の酸化マンガン粒子は酸素生成反応に寄与しないことが示唆された。, The Surface Science Society of Japan, Japanese
• 規整不均一α‐Sb₂O₄/VSbO₄触媒の調製とその反応活性
  朝倉清高; 原口惟; 和田敬広; 有賀寛子; 高草木達, 触媒討論会討論会A予稿集, 110th, 355, 14 Sep. 2012
  Japanese
• プラズマ処理による酸化物上金粒子の高分散化
  高草木達; NABIL Imran bin; Abdul R. M; 木工淳; 上原広充; 有賀寛子; 朝倉清高, 触媒討論会討論会A予稿集, 110th, 340, 14 Sep. 2012
  Japanese
• In‐Situ電気化学蛍光XAFSによる光電極表面上の助触媒への電荷移動の測定
  蓬田匠; 吉田真明; 畑廷尚; 豊島遼; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, Photon Fact News, 30, 2, 20, 23, Aug. 2012
  Japanese
• Surface Structure and Activity of Ni_2P Single Crystals as a Model Catalyst for Hydrodesulfurization
  ASAKURA Kiyotaka; ARIGA Hiroko; TAKAKUSAGI Satoru; MIYAMOTO Takeshi, 觸媒 = Catalyst, 54, 2, 138, 140, 10 Mar. 2012
  触媒学会, Japanese
• 電析によるPt/TiO₂(110)モデル触媒表面の調製
  高草木達; 小川貴史; 上原広充; 有賀寛子; 朝倉清高, 日本化学会講演予稿集, 92nd, 2, 216, 09 Mar. 2012
  Japanese
• In‐situ電気化学XAFS法による水分解用光電極上の酸素生成助触媒への電荷移動の観察
  吉田真明; 蓬田匠; 畑廷尚; 豊島遼; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, 日本化学会講演予稿集, 92nd, 2, 501, 09 Mar. 2012
  Japanese
• 高活性脱硫触媒Ni₂PのQEXAFS法による構造追跡—差分法によるQEXAFS補正について,
  和田敬広; 阪東恭子; 高草木達; 朝倉清高, 日本放射光学会年会・放射光科学合同シンポジウム予稿集, 25th, 136, 06 Jan. 2012
  Japanese
• In‐Situ電気化学蛍光XAFSによる光電極表面上の助触媒への電荷移動の測定
  蓮田匠; 吉田真明; 畑廷尚; 豊島遼; 新田清文; 加藤和男; 増田卓也; 仁谷浩明; 阿部仁; 高草木達; 宇留賀朋哉; 朝倉清高; 魚崎浩平; 近藤寛, PFシンポジウム要旨集, 29th, 61, 2012
  Japanese
• Photo-excited carrier transfer to Mn-oxide cocatalysts on the photoelectrode for water splitting studied by In-situ XAFS
  Yoshida Masaaki; Takakusagi Satoru; Uruga Tomoya; Asakura Kiyotaka; Uosaki Kohei; Kondoh Hiroshi; Yomogida Takumi; Mineo Takehiro; Maeda Saya; Nitta Kiyofumi; Kato Kazuo; Masuda Takuya; Nitani Hiroaki; Abe Hitoshi, Abstract of annual meeting of the Surface Science of Japan, 32, 0, 32, 32, 2012
  XAFS法により水分解光電極上の酸化マンガン助触媒の電子状態を測定し、光電極上から助触媒への励起キャリアの移動を観測した。光照射下で酸化マンガンのMn-K端XAFSを測定すると、3価から4価に酸化される様子が観測され、酸化マンガン上に励起ホールが移動することが示された。一方、酸化マンガンの電着量が少ないサンプルでは2価に還元される様子が観測され、一部の酸化マンガン粒子は酸素生成反応に寄与しないことが示唆された。, 公益社団法人 日本表面科学会
• Operando QEXAFSによるNi₂P脱硫触媒の構造追跡
  和田敬広; 阪東恭子; 高草木達; OYAMA S. T; 朝倉清高, PFシンポジウム要旨集, 29th, 21, 2012
  Japanese
• 遷移金属リン化物表面の構造と安定化要因
  朝倉清高; 有賀寛子; 高草木達; 鈴木秀志; 大谷茂樹; 大山茂; ALVIN Henandez; 木下久美子, 表面科学学術講演会講演要旨集, 31st, 174, 15 Dec. 2011
  Japanese
• 電気化学的手法によるPt/TiO₂(110)モデル触媒表面の精密調整
  小川貴史; 高草木達; 上原広充; 有賀寛子; 朝倉清高, 表面科学学術講演会講演要旨集, 31st, 110, 15 Dec. 2011
  Japanese
• 電子線リソグラフィを用いたα‐Sb₂O₄/VSbO₄薄膜の触媒反応活性とその機構解明
  原口惟; 和田敬広; 有賀寛子; 高草木達; 朝倉清高, 表面科学学術講演会講演要旨集, 31st, 175, 15 Dec. 2011
  Japanese
• 水素化脱硫触媒Ni₂Pの表面構造と反応性
  有賀寛子; フェルナンデス アルビン; 木下久美子; 高草木達; 大谷茂樹; 大山S.Ted; 朝倉清高, 触媒討論会討論会A予稿集, 108th, 312, 13 Sep. 2011
  Japanese
• 機能性分子修飾による酸化物表面上Cu種の構造制御
  高草木達; 野島大孝; 宮崎晃太朗; 和田敬広; 有賀寛子; 田旺帝; 野村昌治; 朝倉清高, 日本放射光学会年会・放射光科学合同シンポジウム予稿集, 24th, 143, 07 Jan. 2011
  Japanese
• 水素化脱硫反応中のNi₂P触媒のXANES変化
  和田敬広; 阪東恭子; 宮本剛志; 有賀寛子; 高草木達; OYAMA S. Ted; 朝倉清高, PFシンポジウム要旨集, 28th, 28, 2011
  Japanese
• 機能性分子修飾による酸化物表面上Cu種の構造制御
  高草木達; 野島大孝; 宮崎晃太朗; 和田敬広; 有賀寛子; 田旺帝; 野村昌治; 朝倉清高, 表面科学学術講演会講演要旨集, 30th, 67, 04 Nov. 2010
  Japanese
• 電子線リソグラフィを用いたα‐Sb₂O₄/VSbO₄薄膜触媒の部分酸化反応の制御
  原口惟; 和田敬広; 有賀寛子; 高草木達; 朝倉清高, 表面科学学術講演会講演要旨集, 30th, 412, 04 Nov. 2010
  Japanese
• 金属担体相互作用―偏光全反射蛍光XAFS法による研究例―
  朝倉清高; 高草木達; 有賀寛子; CHUN Wang Jae, 触媒討論会討論会A予稿集, 106th, 344, 15 Sep. 2010
  Japanese
• メルカプト安息香酸構造異性体によるTiO₂(111)表面Cu化学種の構造制御
  野島大孝; 高草木達; 宮崎晃太朗; 和田敬広; 有賀寛子; CHUN Wang Jae; 野村昌治; 朝倉清高, 触媒討論会討論会A予稿集, 106th, 341, 15 Sep. 2010
  Japanese
• Operando Analysis of an Active Site and a H_2 S Treatment in Ni_2 P Desulfarization Catalysts
  WADA Takahiro; BANDO Kyoko; MIYAMOTO Takeshi; ARIGA Hiroko; TAKAKUSAGI Satoru; OYAMA S. Ted; ASAKURA Kiyotaka, 觸媒 = Catalyst, 52, 6, 462, 464, 04 Sep. 2010
  触媒学会, Japanese
• Control of the nonmaterial structure on the modified TiO2 (110) surface (特集 機能元素のナノ材料科学)
  朝倉 清高; Takakusagi Satoru, マテリアルインテグレ-ション, 22, 9, 2, 5, Sep. 2009
  ティー・アイ・シィー, English
• Dynamic aspects and associated structures of TiO2(110) and CeO2(111) surfaces relevant to oxide catalyses
  K Fukui; S Takakusagi; R Tero; M Aizawa; Y Namai; Y Iwasawa, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 5, 24, 5349, 5359, Dec. 2003
  English
• Structure and reactivity of metal clusters at oxide surfaces characterized by time-resolved DXAFS and STM.
  Y Iwasawa; K Fukui; S Takakusagi; A Suzuki; M Nomura, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 226, U281, U281, Sep. 2003
  English, Summary international conference
• Self-limiting growth of pt nanoparticles from MeCpPtMe3 adsorbed on TiO2(110) studied by scanning tunneling microscopy
  S Takakusagi; K Fukui; R Tero; F Nariyuki; Y Iwasawa, PHYSICAL REVIEW LETTERS, 91, 6, Aug. 2003
  English
• STM study on structures of two kinds of wide strands formed on TiO2(1 1 0)
  Satoru Takakusagi; Ken-Ichi Fukui; Fumito Nariyuki; Yasuhiro Iwasawa, Surface Science, 523, 1-2, L41, L46, 10 Jan. 2003
  English
• Observation of the surface chemical process on micro-structured surface by emission electron microscopy and related techniques
  K. Asakura; Y. Ohminami; K. Ijima; S. Suzuki; Y. Yamaguchi; S. Takakusagi; Y. Iwasawa; M. Kato; Y. Sasaki, Proceedings of 6th International Symposium on Advanced Physical Fields, Growth of well-defined Nanostructures 2001, 60, 2001
  English, Report scientific journal
• Development of an X-ray photoemission electron microscopy system with multi-probes, and its application to surface imaging at static and dynamic states
  S Takakusagi; M Kato; Y Sakai; K Fukui; K Asakura; Y Iwasawa, JOURNAL OF MICROSCOPY-OXFORD, 200, 240, 250, Dec. 2000
  English
• X-ray photoemission electron microscopy (XPEEM) as a new promising tool for the real-time chemical imaging of active surfaces
  Y Yamaguchi; S Takakusagi; Y Sakai; M Kato; K Asakura; Y Iwasawa, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 141, 1-3, 129, 137, May 1999
  English
• Development of Multifunctional Surface Imaging System
  ASAKURA Kiyotaka; YAMAGUCHI Yoshitake; TAKAKUSAGI Satoru; KATO Makoto; SAKAI Yuji; IWASAWA Yasuhiro, 真空, 42, 3, 467, 467, Mar. 1999
  Japanese

• Foundations and applications of XAFS 2nd Edition
  高草木達, 5.7.1 偏光全反射蛍光XAFS(PTRF-XAFS)法
  講談社, Aug. 2025, 9784065404867, x, 357p, Japanese, [Contributor]
• 触媒総合事典
  高草木達, 4-26 走査型トンネル顕微鏡（STM）・原子間力顕微鏡（AFM）
  朝倉書店, Feb. 2023, 9784254252743, xiv, 530p, 図版 [4] p, Japanese, [Contributor]
• Nanoinformatics
  Ichigaku Takigawa; Ken-ichi Shimizu; Koji Tsuda; Satoru Takakusagi, Machine Learning Predictions of Factors Affecting the Activity of Heterogeneous Metal Catalysts
  Springer Singapore, 2018, [Contributor]
• XAFSの基礎と応用
  高草木 達; 朝倉 清高, 4.7.1 全反射XAFS
  講談社サイエンテフィク, Jul. 2017, [Contributor]
• X-ray and Neutron Techniques for Nanomaterials Characterization
  Wang-Jae Chun; Satoru Takakusagi; Yohei Uemura; Kyoko Bando; Kiyotaka Asakura, X-Ray Absorption Fine Structure Analysis of Catalytic Nanomaterials,pp 609-664
  Springer Berlin Heidelberg, Dec. 2015, [Joint work]
• 現代界面コロイド科学の事典
  高草木 達, 界面の一分子計測
  丸善, May 2010, [Contributor]
• 翻訳 応用界面・コロイド化学ハンドブック
  高草木 達; 魚崎 浩平, 第6章 自己組織化単分子層－金上のアルカンチオール
  （株）エヌ・ティー・エス, 2006, [Contributor]

• 偏光全反射蛍光 XAFS法による表面反応プロセスのその場/オペランド計測
  高草木達; 魯邦
  日本分析化学会第74年会, 24 Sep. 2025, Japanese, Invited oral presentation
  [Invited]
• その場計測に基づくプラズマ触媒反応の基礎学理解明
  高草木達; 魯邦
  第86回応用物理学会秋季学術講演会, 08 Sep. 2025, Invited oral presentation
  [Invited]
• パーシステントホモロジーと自己相関解析を用いたSTM像からの吸着種間相互作用の抽出
  高草木達
  2025年度NIFS一般共同利用研究課題(研究会)「数理科学・プラズマ科学・原子分子科学・物質科学の共通研究拠点形成」, 16 Jun. 2025, Nominated symposium
  [Invited]
• 触媒反応の原子レベル可視化と圧力ギャップフリー触媒表面科学の確立
  高草木達
  岩澤コンファレンス2025「持続可能な社会をささえる最先端サイエンス」, 07 Jun. 2025, Nominated symposium
  [Invited]
• Development of in situ/operando surface science techniques to bridge the pressure gap in UHV surface chemistry and catalysis
  Satoru Takakusagi
  Joint FHI-ICAT Symposium, 08 Nov. 2024, English, Nominated symposium
  [Invited]
• Atomic-level visualization of surface catalytic reactions by in situ/operando surface science techniques
  Satoru Takakusagi
  The 12th Vacuum and Surface Sciences Conference of Asia and Australia (VASSCAA-12), 14 Oct. 2024, English, Invited oral presentation
  [Invited]
• その場/オペランド表面科学計測による触媒反応プロセスの原子レベル可視化
  高草木達
  日本物理学会第79回年次大会, 16 Sep. 2024, Japanese, Invited oral presentation
  [Invited]
• 単結晶モデル表面を用いた触媒反応プロセスの原子レベル可視化
  高草木達
  ナノ学会第22回大会, 23 May 2024, Japanese, Invited oral presentation
  22 May 2024 - 24 May 2024, [Invited]
• 触媒材料開発における先端計測とマテリアルズ・インフォマティクス：現状と課題
  高草木達
  NIFS研究会「数理科学・プラズマ科学・物質科学の共通研究拠点形成 」, 20 May 2024, Japanese, Nominated symposium
  20 May 2024 - 21 May 2024, [Invited]
• 不均一な構造を有する触媒材料における構造・活性相関の評価：単結晶モデル触媒を用いたアプローチ
  高草木達
  2023年度量子ビームサイエンスフェスタ, 06 Mar. 2024, Japanese, Invited oral presentation
  [Invited]
• 放射光と表面科学を用いた触媒活性点の原子レベル構造解析
  高草木達
  北海道大学触媒科学研究所・立命館大学SRセンター共催シンポジウム「触媒科学と放射光－Soft～Tender X線の新たな展開」, 26 Jan. 2024, Japanese, Nominated symposium
  [Invited]
• Development of synchrotron X-ray and surface science techniques for characterizing plasma catalysis
  Satoru Takakusagi
  2023 Australia-Japan Symposium on Plasma Catalysis, 23 Nov. 2023, English, Nominated symposium
  23 Nov. 2023 - 24 Nov. 2023, [Invited]
• Dynamic Behavior of Intermediate Adsorbates to Control Activity and Product Selectivity in Heterogeneous Catalysis: Methanol Decomposition on Pt/TiO2(110)
  Satoru Takakusagi
  MIRAI 2.0（日本・スウェーデンMIRAIプロジェクト） Research and Innovation Week 2023 Materials Science TEG, 14 Nov. 2023, English, Invited oral presentation
  13 Nov. 2023 - 17 Nov. 2023, [Invited]
• 不均一な構造を有する固体触媒の放射光を用いた構造解析：不均一性への挑戦
  高草木達
  第132回触媒討論会, 13 Sep. 2023, Japanese, Invited oral presentation
  [Invited]
• Atomic-level visualization of surface catalytic reactions by in situ/operando surface science techniques
  Satoru Takakusagi
  ICAT-FHI Symposium: Approaching to the Catalysis Reality, 11 Sep. 2023, English, Invited oral presentation
  [Invited]
• その場/オペランド表面科学計測による触媒反応の原子レベル可視化
  高草木達
  第452回触媒科学研究所コロキウム, 05 Jun. 2023, Japanese, Invited oral presentation
  [Invited]
• 圧力ギャップフリー触媒表面科学を目指して：現状と課題
  高草木達
  触媒科学計測共同研究拠点ミニシンポジウム「超高速データ駆動科学と先端計測技術の融合による触媒科学イノベーション」, 30 Mar. 2023, Japanese, Nominated symposium
  [Invited]

  
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• オペランド偏光全反射蛍光XAFS法による触媒動作中の活性点三次元構造解析
  高草木達
  第12 回 岩澤コンファレンス「 サステナブル社会のための触媒化学・表面科学の最前線 」, 29 Mar. 2023, Japanese, Nominated symposium
  [Invited]
• 偏光XAFSと単結晶モデル表面を用いた触媒活性点のオペランド三次元構造解析
  高草木達
  触媒学会界面分子変換研究会ワークショップ『固体触媒の活性構造を知る』, 28 Nov. 2022, Japanese, Invited oral presentation
  28 Nov. 2022 - 28 Nov. 2022, [Invited]
• Unraveling 3D structure of active metal sites on catalyst surfaces under working conditions by operando PTRF-XAFS technique
  Satoru Takakusagi
  MIRAI 2.0（日本・スウェーデンMIRAIプロジェクト） Research and Innovation Week 2022 Materials Science TEG, 16 Nov. 2022, English, Keynote oral presentation
  [Invited]
• Elucidation of Precise 3D Structure-Activity Relationship in Heterogeneous Catalysis by Operando PTRF-XAFS Technique
  Satoru Takakusagi
  IMS-ICAT Joint Symposium: Surface Science for Catalysis, 11 Oct. 2022, English, Invited oral presentation
  [Invited]
• Operando PTRF-XAFS technique for precise 3D structure determination of active metal sites in heterogeneous catalysis
  Satoru Takakusagi
  ICAT-FHI Symposium: New Dimension of Catalytic Surface Study, 16 Sep. 2022, English, Invited oral presentation
  [Invited]
• Development of operando PTRF-XAFS technique for precise 3D structure determination of active metal sites in heterogeneous catalysis
  Satoru Takakusagi
  International Symposium on Next Generation Synchrotron Radiation Facility Utilization for Catalysts Characterization as Post Symposium of TOCAT9, 31 Jul. 2022, English, Keynote oral presentation
  31 Jul. 2022 - 01 Aug. 2022, [Invited]
• Operando PTRF-XAFS technique for elucidating relationship between 3D structure of active metal sites and catalytic properties under working conditions
  Satoru Takakusagi; Lu Bang; Daiki Kido; Yuta Sato; Kiyotaka Asakura
  The 2021 International Chemical Congress of Pacific Basin Societies (Pacifichem2021), 20 Dec. 2021, Invited oral presentation
  [Invited]
• オペランド偏光全反射蛍光XAFS法の開発による動作中触媒表面の三次元構造解析
  高草木達
  令和２年度日本表面真空学会東北・北海道支部学術講演会, 05 Mar. 2021
  [Invited]
• 単結晶モデル表面を用いた触媒反応プロセスの原子レベル可視化
  高草木達
  2020年度 触媒学会北海道支部 札幌講演会, 02 Dec. 2020, Japanese, Invited oral presentation
  02 Dec. 2020 - 02 Dec. 2020, [Invited]
• Atomic-level visualization of surface catalytic reactions by in-situ/operando XAFS and STM
  Satoru Takakusagi
  International Joint Symposium On-Line: Cutting Edge of Surface Science For Atomic Scale Approach to Catalyst, 05 Nov. 2020, English, Nominated symposium
  05 Nov. 2020, [Invited]
• Operando PTRF-XAFS technique for elucidating 3D structure-activity relationship in heterogeneous catalysis
  Satoru Takakusagi; Lu Bang; Daiki Kido; Yuta Sato; Kiyotaka Asakura
  The 2nd Workshop of Reaction Infography / The 3rd IRCCS International Symposium, 31 Jan. 2020, English, Invited oral presentation
  31 Jan. 2020 - 01 Feb. 2020, [Invited]
• 高草木達，魯邦，城戸大貴，佐藤優太，朝倉清高,
  触媒動作中の活性点三次元構造決定のためのオペランド偏光全反射蛍光XAFS法の開発
  PF研究会「XAFS・X線顕微鏡分光分析分野でのIMSS，PF戦略的利用に関する研究会」, 18 Dec. 2019, Japanese, Invited oral presentation
  17 Dec. 2019 - 18 Dec. 2019, [Invited]
• Development of operando PTRF-XAFS technique for determining 3D structure of active sites in heterogeneous catalysis
  Satoru Takakusagi
  Okazaki Conference “Forefront of Measurement Technologies for Surface Chemistry and Physics in Real-Space, k-Space, and Real-Time”, 03 Dec. 2019, English, Invited oral presentation
  02 Dec. 2019 - 04 Dec. 2019, [Invited]
• 触媒動作中の活性点立体構造決定のためのオペランド偏光全反射蛍光XAFS法の開発と触媒インフォマティクス
  高草木 達
  第17回SPring-8ユーザー協同体顕微ナノ材料科学研究会・第14回日本表面科学会放射光表面科学研究部会・第3回プローブ顕微鏡研究部会合同シンポジウム, 04 Mar. 2019, Japanese, Invited oral presentation
  [Invited], [Domestic Conference]
• 偏光全反射蛍光XAFS法を用いた固気及び固液界面における表面金属ナノ構造の三次元構造解析
  高草木 達
  日本表面真空学会学術講演会, 20 Nov. 2018, Japanese, Invited oral presentation
  [Invited], [Domestic Conference]
• 担持金属モデル触媒表面の原子レベル構造解析と反応計測
  高草木 達
  第122回触媒討論会, 26 Sep. 2018, Japanese, Invited oral presentation
  [Invited], [Domestic Conference]
• Atomic-level structure and reactivity on well-defined model catalysts surfaces studied by STM and XAFS
  Satoru Takausagi; Kiyotaka Asakura
  International Symposium on Advancement and Prospect of Catalysis Science & Technology, 27 Jul. 2018, English
  [Invited], [International presentation]
• Structure and reactivity on well-defined model catalyst surfaces studied by STM and XAFS
  Satoru Takakusagi; Kiyotaka Asakura
  Symposium on Nanomaterials for Environmental Purification and Energy Conversion, 21 Feb. 2018, English, Invited oral presentation
  [Invited], [International presentation]
• 酸化物単結晶表面におけるAuナノ構造の原子レベル評価と制御
  高草木 達; 朝倉 清高
  2017年日本金属学会秋期講演大会, 07 Sep. 2017, Japanese
  [Invited], [Domestic Conference]
• Oxygen plasma treatment of ligand-protected Au clusters on TiO2(110) :unusual loading-dependence of Au nanoparticle size
  S. Takakusagi; K. Asakura
  International Symposium on Pure and Applied Chemistry (ISPAC) 2017, 09 Jun. 2017, English
  [Invited], [International presentation]
• Single metal dispersion on an oxide single crystal surface: effect of premodification with a mercapto compound on metal dispersion
  S. Takakusagi; K.Asakura
  3a000687, 17 Aug. 2016, English, Invited oral presentation
  [Invited], [International presentation]
• 3D structure analysis of atomically dispersed metal species on an oxide single crystal surface by polarization-dependent total-reflection fluorescence XAFS
  Satoru Takakusagi
  The 74th Okazaki Conference “Frontier of X-ray Absorption Spectroscopy and Molecular Science”, 04 Feb. 2015, English, Invited oral presentation
  [Invited], [International presentation]
• 3D structural determination of atomically dispersed metals on a TiO2(110) surface premodified with functional organic molecules
  S. Takakusagi; H. Nojima; H. Ariga; H. Uehara; K. Miyazaki; W.-J. Chun; Y. Iwasawa; K. Asakura
  Vietnam Malaysia International Chemical Congress (VMICC) 2014, 08 Nov. 2014, English, Invited oral presentation
  [Invited], [International presentation]
• 酸化物単結晶上金属ナノ構造の反応特性と構造制御
  高草木 達
  2014年日本金属学会秋期講演大会, 25 Sep. 2014, Japanese, Invited oral presentation
  [Invited], [Domestic Conference]
• Preparation and 3D structure analysis of atomically dispersed metal species on a TiO2(110) single crystal surface premodified with functional organic molecules
  Satoru Takakusagi
  The 6th IEEE International Nanoelectronics Conference (IEEE INEC 2014), 28 Jun. 2014, English, Invited oral presentation
  [Invited], [International presentation]
• 酸化物単結晶表面上に高分散した金属種の構造と反応特性
  高草木 達
  日本表面科学会触媒表面科学研究部会ワークショップ「表面化学の新展開」, 01 Mar. 2014, Japanese, Invited oral presentation
  [Invited], [Domestic Conference]
• Dynamic Behavior of Intermediate Adsorbates to Control Activity and Product Selectivity in Heterogeneous Catalysis: Methanol Decomposition on Pt/TiO2(110)
  Satoru Takakusagi
  MIRAI 2.0（日本・スウェーデンMIRAIプロジェクト） Research and Innovation Week 2023 Materials Science TEG 2023, 14 Nov. 2013, English, Invited oral presentation
  [Invited]
• Preparation of monomeric metal species on a TiO2 single crystal surface premodified with with functional organic molecules
  Satoru Takakusagi; Hirotaka Nojima; Kotaro Miyazaki; Takahiro Wada; Hiroko Ariga; Wang-Jae Chun; Masaharu Nomura; Yasuhiro Iwasawa; Kiyotaka Asakua
  17th Malaysian Chemical Congress (17 MCC), 16 Oct. 2012, English, Invited oral presentation
  [Invited], [International presentation]
• Atomically Dispersed Metal Species Formed on TiO2(110) Surfaces Premodified with Functional Organic Molecules
  TAKAKUSAGI Satoru
  CRC-FHI Joint Meeting“Complex Surfaces in Material Science”, 19 Sep. 2012, English, Nominated symposium
  [Invited], [International presentation]
• Formation of Atomically Dispersed Cu on a TiO2(110) Surface Precovered with Functional Organic
  S. Takakusagi; H. Nojima; K. Miyazaki; T. Wada; H. Ariga; W.-J. Chun; M. Nomura; Y. Iwasawa; K. Asakura
  International Symposium and the Third Iwasawa Conference on Catalysis and Surface Science for Utilization of Carbon Resources and Related Topoics, 03 Dec. 2011, English, Nominated symposium
  [Invited], [International presentation]
• Direct STM Visualization of Spillover Adsorbates on a Pt/TiO2(110) surface
  Satoru Takakusagi; Ken-ichi Fukui; Kiyotaka Asakua; Yasuhiro Iwasawa
  14th Asian Chemical Congress 2011 (14 ACC), 08 Sep. 2011, English, Invited oral presentation
  [Invited], [International presentation]
• In-situ STM Observation of Spillover Process on a Pt/TiO2(110) Model Catalyst Surface
  TAKAKUSAGI Satoru
  The Third Joint Symposium of CRC-Hokkaido Univ. and Xiarmen Univ., 11 Apr. 2011, English, Nominated symposium
  [Invited], [International presentation]
• 酸化物表面上金属ナノ構造の機能性有機分子による構造制御
  高草木 達
  第6回放射光表面科学部会顕微ナノ材料科学研究会合同シンポジウム, 10 Dec. 2010, Japanese, Nominated symposium
  [Invited], [Domestic Conference]
• 偏光全反射蛍光XAFS 法による固体表面上に形成した金属ナノ構造の精密解析
  高草木 達; 朝倉 清高
  筑波大学-KEK第三回連携ミニ研究会-XAFSと機能性物質, 21 Dec. 2009, Japanese, Nominated symposium
  [Invited], [Domestic Conference]

• 環境触媒化学特論Ⅱ, 2024年, 修士課程, 環境科学院

• 触媒学会
• 電気化学会
• 日本表面真空学会
• 日本化学会
• 日本XAFS研究会
• アメリカ化学会

• オペランド表面科学計測システムの開発による圧力ギャップフリー触媒表面科学の確立
  科学研究費助成事業
  Apr. 2024 - Mar. 2027
  高草木 達
  日本学術振興会, 基盤研究(A), 北海道大学, 24H00445
• 非平衡プラズマを基盤とした電子駆動触媒反応の創成
  戦略的創造研究推進事業（CREST）
  Oct. 2019 - Mar. 2025
  野崎 智洋
  科学技術振興機構（JST）, Coinvestigator, Competitive research funding
• 活性点立体構造と表面吸着種のオペランド複合計測による触媒反応機構の原子レベル解明
  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)
  Apr. 2021 - Mar. 2024
  高草木 達
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), Hokkaido University, 21H01802
• Development of operando PTRF-XAFS technique and its application to 3D structure analysis of catalyst active sites under working conditions
  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)
  Apr. 2018 - Mar. 2021
  高草木 達
  本年度は、まず、昨年度設計・製作を行ったオペランド偏光全反射蛍光XAFS装置の性能向上及び最適化に向けた試みを行った。真空度改善のため、真空排気ラインのコンダクタンスを大きくするとともに、排気に使用しているターボ分子ポンプを、より排気速度の大きいポンプへと変更した。こうした試みにより、真空度は2桁程度改善した。また、装置に取付けられている蛍光取り出し用のBe窓（ICF70規格のフランジ中央部にBe薄膜をろう付け）の有効径を可能な限り大きくし、試料と半導体検出器（19素子solid state detector）との距離及び立体角の最適化を行うことで、スペクトルのS/N比向上を実現した。
  続いて、アルミナ単結晶表面上に白金ナノ粒子を担持したモデル触媒表面（Pt/α-Al2O3(0001)）でのCO酸化反応中のPt活性点電子状態及び3次元構造について、昨年度得られた結果の再現性もかねて、再度オペランド偏光全反射蛍光XAFS測定（Pt L3吸収端）を行った。反応ガス（CO、O2及び濃度補正用Arを含む混合ガス）雰囲気下で試料を加熱し、各温度で反応進行状況を確認しながらXANES測定を行ったところ、温度の上昇に伴ってスペクトルのwhite line強度は減少した。このことは温度上昇により、Ptが徐々に還元されたことを示している。活性は>473 Kで顕著になることがわかった。さらに、493 KでCO酸化反応が進行中のEXAFS測定にも成功し、スペクトルは三次元構造解析に十分なS/N比であった。予備的な解析から1 nm程度のナノ粒子が活性点であることを見出し、FEFFコードを用いた三次元構造決定を開始した。
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (B), Hokkaido University, 18H01864
• Exploration of nanostructure-property relationships for materials innovation
  Grants-in-Aid for Scientific Research
  06 Nov. 2015 - 31 Mar. 2018
  TANAKA Isao; MATSUNAGA Katsuyuki; MUTO Shunsuke; TANIGUCHI Takashi; KITAOKA Satoshi; KANNO Ryoji; TAKAKUSAKI Satoru; TSUDA Koji
  This group encouraged many international activities of project members. This group supported publishing an open-access international book of our research summary, publishing a special issue in an international journal and providing a series of lectures on our studies. This group also supported young researches to collaborate with foreign researchers.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area), Kyoto University, 15K21748
• Exploration of nanostructure-property relationships for materials innovation
  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
  28 Jun. 2013 - 31 Mar. 2018
  TANAKA Isao; MATSUNAGA Katsuyuki; SHIBATA Naoya; MUTO Shunsuke; TANIGUCHI Takashi; OHTA Hiromichi; KITAOKA Satoshi; KANNO Ryoji; TAKAKUSAKI Satoru; TSUDA Koji; ADACHI Hirohiko; SAKUMA Taketo; TAKANO Mikio; MORI Hirotaro; HIGUCHI Tomoyuki
  This group mainly encouraged the collaboration between project members. This group organized international symposiums for publishing our studies, organized many small workshops for accelerating the communication between researchers with different backgrounds, published an international book of our research summary, and encouraged may activities of young researchers. In addition, this group supported the building of a web site and publication of a booklet.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area), Kyoto University, 2505
• Exploration of nanostructure - property relationships for materials innovation
  Grants-in-Aid for Scientific Research
  28 Jun. 2013 - 31 Mar. 2018
  TANAKA Isao; MATSUNAGA Katsuyuki; SHIBATA Naoya; MUTO Shunsuke; TANIGUCHI Takashi; OHTA Hiromichi; KITAOKA Satoshi; KANNO Ryoji; TAKAKUSAKI Satoru; TSUDA Koji; ADACHI Hirohiko; SAKUMA Taketo; TAKANO Mikio; MORI Hirotaro; HIGUCHI Tomoyuki
  This group mainly encouraged the collaboration between project members. This group organized international symposiums for publishing our studies, organized many small workshops for accelerating the communication between researchers with different backgrounds, published an international book of our research summary, and encouraged may activities of young researchers. In addition, this group supported the building of a web site and publication of a booklet.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area), Kyoto University, 25106001
• Synthesis and atomic-level characterization of well-defined surface nanostructures for development of novel catalytic materials
  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
  Jun. 2013 - Mar. 2018
  TAKAKUSAGI Satoru; MATSUMOTO Yuji; TAKIGAWA Ichigaku
  We have developed oxide-supported metal catalysts and immobilized metal complex catalysts which are highly efficient for purification of environment and green organic synthesis by combining atomic-level surface characterization using single-crystal model catalyst surfaces. We particularly focused on molecular activation at characteristic nanostructures formed at the metal-oxide interfaces in the oxide-supported metal catalysts, while in the immobilized metal complex catalyst we examined the effects of catalytic activity on spatial arrangement and orientation of the surface-attached metal complexes. A novel approach to find efficient catalytic materials with high-speed and high-precision based on the informatics-based techniques was also explored.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area), Hokkaido University, 25106010
• Development of oxide-supported metal catalysts with well-defined structure and composition for determination of the number of metal atoms in the most active oxide-suppoeted metal catalyst
  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)
  2011 - 2013
  TAKAKUSAGI Satoru; TSUNOYAMA Hironori; ASAKURA Kiyotaka; ARIGA Hiroko
  Catalytic properties such as activity and selectivity of oxide-supported metal catalysts strongly depend on metal cluster size and metal-support interaction. In this research project, we tried to develop a method to prepare gold clusters with a small size distribution in the range of single atom-10 nm on a titanium dioxide single crystal surface by using ligand-protected gold clusters, and the structures of the deposited gold clusters were examined at the atomic level by surface science techniques such as STM/AFM and polarization dependent total-reflection fluorescence XAFS. We also developed a ultra-high vacuum equipment for measuring catalytic activity of the deposited gold clusters formed on an oxide single crystal surface.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (C), Hokkaido University, 23550001
• 酸化物表面欠陥によるナノクラスターの制御と触媒作用
  科学研究費助成事業
  2008 - 2009
  朝倉 清高; 鈴木 秀士; 高草木 達
  酸化物上の金属ナノクラスターは、触媒,ガスセンサー,光材料,様々な分野で応用されている。ナノクラスターの粒子サイズを自由に制御することができれば、高活性・高選択的触媒開発も可能である。TiO_2(110)表面は中でも広く研究が進んでいる表面である。この表面におけるナノ粒子の核形成には、表面に存在する格子欠陥や線状欠陥であるステップが重要といわれながら、ナノ粒子の形や大きさを制御するために必要な基板酸化物と金属との相互作用の本質は十分にわかっていない。酸化物表面特にTiO_2(110)表面に形成した欠陥とその表面に構築する金属ナノクラスターとの相互作用を明らかにし、欠陥等を利用した酸化物表面のナノクラスター構造制御法を開発することを目的とする。
  本年はAuを少量蒸着し、その挙動を改質したTiO_2(110)表面で検討したところ、欠陥を多く含む表面で、大きな構造変化を観測し、Auの13程度のナノクラスターからなることを見出した。
  日本学術振興会, 特定領域研究, 北海道大学, 20047001
• Morphological, Electronic, and Molecular Structures and Electron Transfer Characteristics at Metal/Molecule and Semiconductor/Molecule Interfaces
  Grants-in-Aid for Scientific Research
  2006 - 2009
  UOSAKI Kohei; IKEDA Katsuyoshi; NOGUCHI Hidenori; TAKAKUSAGI Satoru
  To obtain information of geometric, electronic and molecular structures and electron transfer properties at solid/liquid interfaces, which is essential information for future electronic devices and sensors, development of methods to construct molecular layers and characterization of structures and electron transfer property have been carried out. As a result, 1. novel method for constructing molecular layers on silicon with photo- electrochemical functions was developed, 2. interfacial electronic structure change induced by adsorption of molecules was clarified by sum frequency generation (SFG) and gap-mode Raman spectroscopy, and 3. reactions at solid/liquid interfaces were monitored in situ in real time by SXS and XAFS using synchrotron radiation and SFG.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (A), Hokkaido University, 18205016
• Conductivity measurement of single molecule using self-assembled monolayer formed onvarious electrode surfaces
  Grants-in-Aid for Scientific Research
  2007 - 2008
  TAKAKUSAGI Satoru
  再現性の高い単一分子の電気伝導測定を可能とすることを目的とし、金上のチオール、シリコン上Si-C 結合を介した単分子層等の自己組織化単分子層(SAM)上に、合成化学的手法を用いて金属層を析出させ、構造のよく規制された金属層-SAM-金属(または半導体)基板からなる接合構造の作成法を確立した。また実際に電気伝導測定を行って電荷移動機構を明らかにした。さらにフェルミ準位付近に分子軌道を有し、多電子酸化還元能を示すルテニウム二核錯体を骨格に含むSAM を金表面上に形成し、電気化学走査型トンネル顕微鏡を用いて、分子一個ずつを識別しながら電気伝導性の評価を行った。分子の像輝度(トンネル電流の流れやすさ)は、探針、基板、分子軌道のエネルギーレベルの相対位置により変化し、軌道を介した共鳴トンネリングによる電子伝導パスが存在すると解釈した。
  Japan Society for the Promotion of Science, Grant-in-Aid for Young Scientists (B), Hokkaido University, 19750102
• フォーカスマイクロ波を用いた超高密度自己組織化単分子膜(SAM)の新形成法
  科学研究費助成事業
  2005 - 2006
  魚崎 浩平; 高草木 達
  固体表面に高い配向性を持つ機能性分子層を形成することは分子デバイス等、ナノテクノロジーにおける最重要課題の一つである。溶液プロセスで簡便に、配向性の高い単分子層を構築できる自己組織化法では、貴金属上(特に金)チオール系分子層やシリコン上のシリコンー炭素直接結合を介した分子層がよく研究されている。しかし、これら単分子層を次世代の超高機能分子デバイスとして利用するには、表面に存在する欠陥をなくし、また従来を上回る高い被覆率・配向性を実現することが不可欠である。さらに実用的には、分子層形成反応が短時間で完了することが望ましい。昨年度の研究成果を踏まえつつ、有機合成など反応が効率的に進行することが明らかになりつつあるマイクロ波合成を機能性分子層の形成に適用し、欠陥の極めて少ない超高密度な分子膜の作成を短時間で効率的に作成することを目的に、研究を行った。本年度は以下の成果を得た。
  1.シリコンによるマイクロ波吸収と温度上昇機構の解明を目的に、ドーパントの種類(窒素ドープ(n型)あるいはホウ素ドープ(p型))や密度依存性について検討した。その結果、ドーパントの種類にはあまり依存しないが、密度には大きく依存することを明らかにした。
  2.シリコン(111)単結晶表面上でのオクタデシル単分子層形成について全反射赤外分光法により詳紬に検討し、最適化を図った。具体的にはマイクロ波強度を上げる、オクタデゼンを加熱効果の高い高誘電率溶媒に希釈ずる等の条件を変え、分子層形成反応の反応時間短縮や欠陥の少ない超高密度膜を形成した。
  日本学術振興会, 萌芽研究, 北海道大学, 17655053
• Real Time Monitoring of Electron Transfer Dynamics at Solid/liquid Interfaces by Non-linear Spectroscopy
  Grants-in-Aid for Scientific Research
  2004 - 2006
  UOSAKI Kohei; IKEDA Katsuyoshi; TAKAKUSAGI Satoru; NOGUCHI Hidenori
  To understand the mechanism of electron transfer dynamics at solid/liquid interfaces, information of structures of molecules at electrode/electrolyte interface including short-lived intermediates and solvent at the interface is essential. The determination of the interfacial structures of the intermediate and solvent is, however, difficult by conventional surface vibrational techniques because of small number of molecules compared to bulk molecules. Temporal vibration of vibrational modes induced by electronic excitation is monitored by IR adsorption and surface-specific sum frequecy generation (SFG) techniques. We investigated the relations between interfacial structures and reaction dynamics by using these spectroscopic methods.
  1. Observation and dynamics of adsorbates at solid/liquid interfaces by SFG spectroscopy
  Dynamics of adsorbed CO on Pt electrode was followed by visible pump SFG probe measurements. An SFG peak due to adsorbed CO at on-top site of Pt was observed at 2064cm-l. The intensity of this peak decreased quickly upon excitation and recovered within few ten of os. A new broad peak was observed at 1980cm-l corresponding to adsorbed CO at multi-fold site, suggesting the site exchange upon excitation. The recovery rate was found to be dependent on potential.
  2. Carrier and charge transfer dynamics by visible pump-visible and IR technique
  Time-resolved visible-pump visible and infrared-probe techniques, in which very short UV or visible pulse excitation is combined with delayed ultrafast visible and mid-IR absorption, respectively, are powerful tools to monitor the changes in electronic and molecular structure, respectively, as after the photoexcitation. In the present study, (1) a system, which allows these two measurements, was constructed, (2) visible-pump infrared-probe technique was applied to study the effect of size and surface treatment on the carrier dynamics of CdS, and (3) visible-pump visible and infrared-probe techniques were applied to study the photo-induced intra-molecular charge transfer with a triruthenium complex [Ru_3(O)(CH_3CO2)_6(CO)L_2], where L=ligands, containing a strongly IR active ligand, CO, which act as a direct IR probe of the electron density at the metal center.
  3. Characterization of water structure at biomaterial surfaces
  Many biological systems such as proteins and enzymes are inactive without water. For a complete understanding of the function of such systems, information of the structure and dynamics of the water is essential. We incestigated the structure of water at several biomaterial surfaces. For example, we monitored the structure of interfacial water at hydro-polymer gel/solid interface by SFG spectroscopy under various pressures. The contribution of weakly hydorogen bonded water in SFG spectra increased with pressure, suggesting the inportant role of weakly hydorogen bonded water to the low friction properties at the hydro-polymer gel/solid interfaces.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research on Priority Areas, Hokkaido University, 16072202
• シリコン表面での自己組織化分子層の構築とハイブリッド光電変換デバイスの創製
  科学研究費助成事業
  2004 - 2005
  高草木 達
  本年度は以下の2点について研究を行った。
  1.シリコン表面上での(光)電気化学的有機単分子層形成過程の解明
  電極として水素終端化p型シリコン単結晶、溶液としてグリニャール試薬(C_<18>H_<37>MgCl)のTHF溶液を用い、電極を正電位側に掃引するとオクタデシル単分子層が形成されることが全反射赤外分光法により確認された。またn型シリコンを電極とし、キセノンランプ照射による光電気化学法によっても単分子層は形成されるが、被覆率は上記の約6割であった。原子間力顕微鏡により、分子層形成反応中の表面観察を行ったところ、後者では表面が著しくエッチングされていた。X線光電子分光法の結果より、表面は一部塩素終端がされていることがわかり、光照射により生成した高酸化力のホールが、塩素と結合したシリコン原子のバックボンドを切断することでエッチングが起こったと考えられる。被覆率が低いのは、本来分子層形成反応に用いられるホールがこのエッチングに用いられたためと考えられる。
  2.有機単分子層修飾シリコンを用いた光電変換デバイスの分子積層による高効率化
  n型水素終端化シリコン単結晶表面に4-ビニルベンジルクロライドを単分子層として導入し、N-メチル-4-(4'-ピリジル)を作用させることで、ビオロゲン修飾シリコン電極を作成した。本ビオロゲン修飾シリコンは、塩化白金酸カリウム溶液に浸漬し、ビオロゲン(おそらくN部位)に吸着したPtCl^<4->を還元して白金微粒子とすることで、電気化学的水素発生に高い活性を示すことが、昨年度の結果からわかっている。本年度は1層目のビオロゲンを修飾後、ジブロモブタン,ビオロゲンを交互に反応、連結させることでビオロゲンの積層化を試みた。結果、5層まではビオロゲン吸着量及び白金析出後の水素発生電流は層数に比例して増加することを確認した。またp型シリコンを用いた光照射下でも同様な結果が得られた。
  日本学術振興会, 若手研究(B), 北海道大学, 16750105
• Dynamic Monitoring of Molecular Structure at Solid/Liquid Interfaces
  Grants-in-Aid for Scientific Research
  2001 - 2003
  UOSAKI Kohei; TAKAKUSAGI Satoru; YAGI Ichizo
  ・Construction of Sun frequency generation (SFG) system for dynamic structure change.
  (a)A pump line using 355nm excitation beam was added to a ps-based SFG system so that time dependent structure change can be followed with 〜2Ops time resolution.
  (b)A broad band SFG system was constructed based on a visible pump IR probe system using 100 fs laser.
  ・Applications of the SFG systems to solid/liquid interface.
  (a)Monitoring of TiO_2 surface for the conversion to hydrophilic surface and adsorption of alcohol.
  TiO_2 is the most studied photocatalyst and conversion of hydrophobic surface to hydrophilic surface by UV illumination is an interesting process. Here, SFG was used to monitor the conversion process from hydrophobic to hydrophilic surface and the adsorption of alcohol.
  (b)Carrier dynamics in semiconductor nanoclusters
  Semiconductor nanoclusters attract much attention due to their unique optical properties. Photoexcited carrier (electron and holes) dynamics in CdSSe nanoclusters dispersed in glass and CdS nanoclusters in reversed micelles were followed by visible pump-IR absorption probe technique.
  (c)Determination of water structure at electrode/electrolyte interface.
  Although structure of water at electrode surface attracts much interests from both fundamental and application view points, it is not well understood due to the limitation of techniques. Here, we were successful to measure the water structure at gold film electrode as a function of electrode potential using SFG.
  Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (A), Hokkaido University, 13304047
• 新規複合電子放出顕微鏡の確立とそれを用いた表面メゾスコピック領域の化学現象観察
  科学研究費助成事業
  2001 - 2002
  高草木 達
  東京大学大学院理学系研究科所属の複合電子放出顕微鏡を基本として、これまでに整備して高輝度化した電子放出顕微鏡システムを用いて以下の研究を行った。また原子・分子スケールでの観察を行うために走査トンネル顕微鏡も併用した。
  1.Au-Ag/Si(100)上でのAg酸化に伴う非線形動的化学現象
  メゾスコピツク表面動的化学現象に関して、シリコン基板上にパターニングして蒸着したAg薄膜表面の酸化過程(酸素圧〜10^<-2>Pa)を473-573Kでその場追跡したところ、原子状吸着酸素種の他に、メタノール部分酸化反応に活性とされる酸素種が構造欠陥で生成後、ドメインを形成しながら成長していく様子が観察された。こうした構造欠陥等の不均一領域での特異な反応性を原子レベルで理解するために、走査トンネル顕微鏡を用いた局所表面構造および動的現象の観察を行った。その結果、多原子欠陥的な非常に配布飽和度が高い表面サイトが、反応開始点となっていることが示唆された。
  2.Pt/TiO_2(110)表面上でのナノ金属粒子間の非線形動的現象
  上記のような非線形化学現象が触媒活性、選択性等に与える影響を原子レベルで理解するために、TiO_2(110)表面上にPt粒子を導入した不均一モデル表面を構築し、その表面上での吸着分子の動的挙動を走査トンネル顕微鏡を用いて調べた。この表面をメタノールに露出するとTiO_2(110)表面のみに露出し場合には観察されなかった、メタノールの解離により生成したメトキシが観察された。室温および昇温時のメトキシの挙動について、吸着種間相互作用(衝突による反応、反発)や吸着種が金属微粒子に到達した場合の動き(反応による脱離、拡散の方向の変化)等に着目して研究を行い、粒子サイズによる反応性の違いや粒子分布が、メトキシの動きや反応の活性・選択性にどういった影響を与えるかを詳細に検討した。
  日本学術振興会, 特別研究員奨励費, 01J05885

• 有機単分子層の形成方法および機能素子の製造方法
  Patent right
  2004-319487
• 分子デバイスとその製造方法
  Patent right
  2003-309431